Structure and Electrochemical Behavior of Minor Mn-Doped Olivine LiMn<sub><i>x</i></sub>Fe<sub>1−<i>x</i></sub>PO<sub>4</sub>

<table class="table-group" id="tab3"><tr><td><table class="table"><tr><td class="thead-hr" colspan="4"><hr/></td></tr><tr class="thead"><td class="align_center"> </td><td class="align_center"><svg height="11.8174pt" id="M17" style="vertical-align:-3.1815pt" version="1.1" viewbox="-0.0498162 -8.6359 18.3375 11.8174" width="18.3375pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M645 631C614 643 545 666 457 666C215 666 23 519 23 283C23 90 158 -16 337 -16C412 -16 489 2 522 10C543 39 590 127 606 167L580 181C519 89 459 18 348 18C201 18 122 136 122 287C122 464 244 632 435 632C544 632 602 595 608 472L639 475C643 526 645 581 645 631Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,8.619,3.132)"><path d="M1006 650H829L492 147L357 650H174L166 618C270 609 275 601 247 502L194 315C158 189 136 127 122 96C104 56 80 37 18 32L12 0H256L263 32C181 40 176 51 183 98C188 132 197 179 226 281L299 541H301L433 6H458L809 551H811L753 141C739 41 734 39 650 32L642 0H917L923 32C836 39 827 41 839 142L887 535C896 610 901 612 997 618L1006 650Z"></path></g></svg> (cm<sup>3</sup>/mol)</td><td class="align_center">Slope</td><td class="align_center"><svg height="11.8174pt" id="M18" style="vertical-align:-3.1815pt" version="1.1" viewbox="-0.0498162 -8.6359 17.9447 11.8174" width="17.9447pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M743 375C743 570 607 650 407 650H136L130 622C214 612 220 606 204 526L125 122C110 43 105 36 24 27L17 0H250C382 0 482 23 571 76C680 141 743 248 743 375ZM644 379C644 188 520 36 305 36C277 36 249 38 229 46C205 55 202 71 212 126L293 553C300 588 306 600 317 606C330 613 356 617 390 617C547 617 644 537 644 379Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,9.893,3.132)"><path d="M495 163C480 117 462 85 444 65C421 39 387 34 332 34C290 34 256 36 236 47C218 57 213 77 213 131V526C213 612 222 616 301 622V650H40V622C122 616 128 611 128 526V126C128 41 120 34 36 28V0H489C498 31 519 126 525 157L495 163Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,14.844,3.132)"><path d="M135 536C164 536 186 560 186 587C186 617 164 639 136 639C109 639 85 617 85 587C85 560 109 536 135 536ZM252 0V26C188 32 181 38 181 106V451C138 433 90 420 39 412V388C99 379 102 374 102 312V106C102 38 95 32 32 26V0H252Z"></path></g></svg> (cm<sup>2</sup>/s)</td></tr><tr><td class="thead-hr" colspan="4"><hr/></td></tr><tr><td class="align_left">LiMn<sub>0.1</sub>Fe<sub>0.9</sub>PO<sub>4</sub></td><td class="align_center">0.0227</td><td class="align_center">0.0085</td><td class="align_center"><span style="width: 62.838ptpx;"><svg height="11.9413pt" id="M19" style="vertical-align:-0.3499002pt" version="1.1" viewbox="-0.0498162 -11.5914 62.838 11.9413" width="62.838pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M412 140C382 77 369 73 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497V118C207 46 201 38 110 32V0H389Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,57.645,-5.741)"><path d="M414 144C384 79 371 75 317 75H135L276 221C367 316 408 376 408 465C408 570 327 635 237 635C179 635 131 609 100 575L42 494L67 471C94 510 138 565 205 565C277 565 321 517 321 435C321 348 258 270 195 195C146 137 88 81 33 26V0H411C423 44 433 88 446 135L414 144Z"></path></g></svg></span></td></tr><tr><td class="align_left">LiMn<sub>0.2</sub>Fe<sub>0.8</sub>PO<sub>4</sub></td><td class="align_center">0.0224</td><td class="align_center">0.0121</td><td class="align_center"><span style="width: 62.8379ptpx;"><svg height="11.9413pt" id="M20" style="vertical-align:-0.3499002pt" version="1.1" viewbox="-0.0498162 -11.5914 62.8379 11.9413" width="62.8379pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M244 635C114 635 38 519 38 422C38 317 111 240 217 240C236 240 255 244 277 256L345 292C311 140 203 39 59 15L64 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<div>Lithium diffusion coefficients of LiMn<sub>0.1</sub>Fe<sub>0.9</sub>PO<sub>4</sub> and LiMn<sub>0.2</sub>Fe<sub>0.8</sub>PO<sub>4</sub>.</div>

Journal of Chemistry

tab3

Table 3

Table 3: Structure and Electrochemical Behavior of Minor Mn-Doped Olivine LiMn<sub><i>x</i></sub>Fe<sub>1−<i>x</i></sub>PO<sub>4</sub> 

Journal of Chemistry

Structure and Electrochemical Behavior of Minor Mn-Doped Olivine LiMnxFe1−xPO4

Table 3

Structure and Electrochemical Behavior of Minor Mn-Doped Olivine LiMn_xFe_1−xPO₄