Research Article

Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst

Table 2

Effect of reaction time.

Time (h)Conversion (%)Yield (%)
Epoxide 2Verbenol 3Verbenone 4Myrtenol 5Myrtenal 6

6427112400
124812112500
207814114242
2410021250720

Reaction conditions: 0.5 mL α-pinene 1, 1.3 mL H2O2; 0.1 g catalyst; 80°C; acetonitrile (5 ml); 24 h. Yields are determined by GC using dodecane as internal standard.