Research Article

Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst

Table 3

Effect of reaction temperature.

Temperature (°C)Conversion (%)Yield (%)
Epoxide 2Verbenol 3Verbenone 4Myrtenol 5Myrtenal 6

R.T000000
60804202934
8010021250720
10095473368
120964124425

Reaction conditions: 0.5 mL α-pinene, 1.3 mL H2O2; catalyst 0.1 g; 24 h; acetonitrile (5 ml). Yields are determined by GC using dodecane as internal standard.