Photodegradation of Methylene Blue Using Carbon-Doped ZnSn(OH)<sub>6</sub> Composite Coated on Membrane

Fenelon, Ernso; Ni’am, Achmad Chusnun; Thi Nguyen, Truc-Mai; Lin, Ying-Fu; Wang, Ya-Fen; You, Sheng-Jie

doi:https://doi.org/10.1155/2023/8471214

Journal of Chemistry

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Abstract Introduction Discussion Conclusions Data Availability Conflicts of Interest Acknowledgments References Copyright Related Articles

Research Article | Open Access

Volume 2023 | Article ID 8471214 | https://doi.org/10.1155/2023/8471214

Photodegradation of Methylene Blue Using Carbon-Doped ZnSn(OH)₆ Composite Coated on Membrane

Ernso Fenelon,¹Achmad Chusnun Ni’am,²Truc-Mai Thi Nguyen,³Ying-Fu Lin,⁴Ya-Fen Wang,^4,5and Sheng-Jie You^4,5

Academic Editor: Ahmad M. Mohammad

Received12 Nov 2022

Revised26 Dec 2022

Accepted05 Jan 2023

Published20 Jan 2023

Abstract

The dye contamination of water is a global concern in the environment. In this study, the photocatalytic technology and membrane module were combined to improve the surface distribution of the active species of the catalyst for better degradation of the methylene blue (MB) dye under visible light. ZnSn(OH)₆ was chosen due to carbon’s complex metal oxide doped to facilitate the application under visible light. The numerous characterizations were analyzed in the composites to verify the consistency of the optimum degradation of MB over the catalyst coated on the membrane. During the preparation of the ZnSn(OH)₆ composite, the results confirmed that different reaction times and amounts of sodium hydroxide significantly affected the pollutant’s degradation. The carbon-doped composite denoted the largest surface area and increased the catalyst’s reactive sites on the membrane. The photocatalytic activity test showed that 1% carbon doped on ZnSn(OH)₆ prepared at 160°C by hydrothermal method coated on the membrane had the optimal degradation of 89.74% of MB. This study contributes to the ongoing study and development of photocatalytic membranes for the photodegradation of wastewater treatment.

1. Introduction

Wastewater contamination is becoming an environmental and industrial challenge [1]. In case, dye elimination is one of the most difficult challenges for textile manufacturing operations [2]. In addition, synthetic dyes in the environment present a challenge for wastewater treatment [3]. The degradation of dyes from wastewater is essential owing to their effects on water quality in the environment, even in low quantities [4]. Due to the potential risk of dye wastewater in the environment, effective treatment should be applied before discharging [5].

Various technologies and procedures for environmental remediation have been established in recent decades for dye removal, including adsorption and photocatalysis [6]. The photocatalytic method proved the efficient result in reducing the synthetic dyes in wastewater due to its simple application in the degradation of dyes processes [7] because photocatalyst applies light energy with the potential level to provide energy for the chemical reaction [8–10]. The catalyst, Zinc-tin bimetal hydroxide, and oxide (ZnSn(OH)₆, ZnSnO₄, Zn₂SnO₃), as a class of complex metal oxide was widely studied as a fire retardant [11, 12], lithium-ion battery material [13], catalysts owing to their environmentally-friendly, nontoxic, safe and high-effective flame and smoke-retardant properties, and lithium-ion storage properties [14]. However, the wide bandgap of ZnSn(OH)₆ is a big challenge to the absorption of visible light when applying this material [6, 15, 16]. As a result, carbon quantum dots were coated on ZnSn(OH)₆ to improve the photon absorption, thus, enhancing the photocatalytic ability of the material. Besides, the photocatalytic membrane application has been considered a better strategy to achieve a better degradation result. To facilitate a better distribution of an active species of the catalyst into the degradation of dye pollutants, applying the photocatalytic membrane has been considered a better strategy to achieve a better result. The photocatalytic membrane has a high potential to degrade the organic pollutants by producing oxygen-reactive radicals under light irradiation. As a result, combining photocatalysts and membranes hold the potential to increase the material’s photocatalytic applicability as well as its applicability in all fields. [17, 18].

This study used carbon quantum dots to improve the photocatalytic performances of ZnSn(OH)₆ for removing methylene blue (MB) from water. Firstly, the shapes of ZnSn(OH)₆ were controlled by adding different amounts of sodium hydroxide (NaOH). Then, the hydrothermal method was used for carrying out the carbon-doped on ZnSn(OH)₆ using other reaction times, temperatures, and different percentages of carbon-doped on the catalyst to control the photodegradation under visible light and coated on the membrane for improving the degradation of MB.

2. Experimental Section

2.1. Material and Chemical

All the chemicals were used without being treated. Tin (IV) Chloride Pentahydrate SnCl₄∙5H₂O manufactured by Alfa aesar, Zinc Acetate Dehydrate Zn(CH₃COO)₂∙2H₂O and glucose manufactured by Sigma, sodium hydroxide made in Japan, ethanol C₂H₅OH manufactured by Alfa aesar, double distilled water, MB manufactured by Alfa aesar, and Nitrogen and Oxygen manufactured by Mingyang special gas Co., purity 99.99%, respectively.

2.2. Preparation of Zinc Stannate

The preparation of the different shapes of zinc stannate followed the previous studies reported by Pham, Li, and coauthors [19, 20]. 0.7 g of pentahydrate tin tetrachloride and 0.44 g of zinc acetate dehydrate were added in two backers separately, dissolved in 5 mL of double distilled water, and stirred for 10 min. Different amounts of sodium hydroxide solution (4, 6, and 8 mL of 3 M) were added dropwise. After that, the solution was stirred for 10 min, then 10 mL of 40% aqueous ethanol solution was added and stirred again for 10 min. The solution was put into an autoclave at different temperatures (120, 140, and 160°C). Those temperatures have been chosen to avoid the deformation of the material because at around 120–150°C, a hydrated form of zinc stannates termed zinc hydroxy stannate (ZnSn(OH)₆) or ZHS occurs during hydrothermal development [21].

2.3. Preparation of Carbon-Doped Zinc Stannate

The preparation of the different shapes of carbon-doped zinc stannate followed the previous study reported by Li and coauthors [22]. The carbon-doped zinc stannate was prepared by the different percentages of glucose (1, 5, and 10%) used for the carbon’s source and mixed with a small amount of double-distilled water, then stirred for 10 min and doped into the solution of zinc stannate, and then mixed for 30 min. Afterward, follow the same process above of the hydrothermal method by using different temperatures.

2.4. Catalyst Coating Membrane

The catalyst coating membrane was applied by modifying the polyvinylidene fluoride (PVDF) membrane as shown in Figure 1(a), the low-temperature plasma system was operated as shown in Figure 1(b), and the operation parameter in Table 1. To prepare the membrane coating 0.20 g of catalyst was added in 5 mL of 20% ethanol solution, the mixture was stirred and mixed by ultrasonic vibration, and the membrane was manually immersed in the uniform mixed solution for 30 min until the catalyst was completely coated on both sides of the membrane. Afterward, the coated membrane was removed from the dish and exposed to air drying for one day at room temperature. Then, the membrane coated with the catalyst was adhered to the membrane surface of a 10 × 10 cm flat frame (Figure 1(c)) using the type of AB glue to join the membrane with the frame, and the inner dimensions of the reaction tank are detailed in Table 2.

(a)

(b)

(c)

2.5. Photocatalytic Characteristics

The surface morphology was determined by scanning electron microscopy (SEM, Model: ZEISS EVO MA 10, ZEISS EVO LS 10). The X-ray diffraction (XRD) pattern uses a Bruker D8-Advance 5005 with Cu Kα radiation (λ = 0.1540 nm) to determine the samples' phase composition and crystal structure. The function group and bonding in the catalyst were analyzed by Fourier transform infrared spectroscopy on an FT/IR-4700 FTIR Spectrometer from JASCO. The material’s diffuse reflectance spectroscopy (DRS) was measured in a wavelength range of 200–800 nm using a UV-Vis spectrometer (JASCO-V550). The surface area analysis by BrunauerEmmett–Teller (BET) and the pore structure by Barrett–Joyner–Halenda (BJH) were measured by the US ASAP 2020 nitrogen adsorption instrument.

2.6. Modified Photocatalytic Membrane Experiment

In this study, the photocatalytic membrane test as shown in Figure 2 was used with MB as the target pollutant by batch experiment. The investigation was carried out with the photocatalytic membrane degradation experiment with 100 mL of 20 ppm of MB for 12 h at room temperature, and the sample was analyzed every hour. The visible light source was a lamp of 110 V, and 12 W, and the photocatalytic activities were measured with the optimum wavelength (λ = 665 nm) by spectrophotometer GENESYS 10 UV.

3. Result and Discussion

3.1. Effect of Different NaOH Concentrations on the Shape of Zinc Stannate

The evolution of microscopic image has been shown differently by adding different amounts of NaOH (4, 6, and 8 mL of 3 mol·L⁻¹) in the preparation of the zinc stannate from cubic, truncated tetradecahedron, and octahedron, respectively (Figure 3). The direct relationship between the NaOH concentration and the shape of the sample can be seen and better understood below in the scanning electron microscopy (SEM) analysis. As shown in Figure 3, the morphology of ZnSn(OH)₆ changes with different NaOH dosages. The results indicated that NaOH dosage is a primary factor affecting the hydrothermal synthesis process of ZnSn(OH)₆.

3.2. SEM Analysis of Different Reaction Times on the Shape of Zinc Stannate

The direct relation between reaction time and the shape of the sample can be seen clearly in SEM results, as shown in Figure 4. The shape and structure of the octahedron (Figure 4(b) (A–C)) were not completely achieved when the preparation time was 2 h (Figure 4(b) (A)), and the zinc oxyhydroxide polyhedral structure began to collapse when the reaction time was 6 h (Figure 4(b) (C)), so the result showed that the optimum preparation time was 4 h (Figure 4(b) (B)). The shape of the truncated tetradecahedron (Figure 4(a) (A–C)) and the octahedron were formed simultaneously. In addition, the cubic (Figure 4(c) (A–C)) was presented when the preparation times were 2, 4, and 6 h. Therefore, 4 h was the optimal reaction time to simultaneously obtain the three shapes (cube, octahedron, and tetradecahedron).

(A)

(B)

(C)

3.3. Analysis of XRD of Different Morphology of Zinc Stannate

The analysis of XRD results of zinc stannate hydroxide is shown in (Figure 5(a)). The 16 diffraction peaks of these three samples were 19.7, 22.8, 32.4, 36.4, 38.2, 40.0, 43.4, 46.5, 51.0, 52.4, 57.9, 61.7, 68.0, 71.5, 72.7, and 77.3°, respectively, with (111), (200) of ZnSn(OH)₆, (220), (013), (311), (222), (321), (400), (331), (420), (422), (511), (440), (135), and (531) compared with the database (JCPDS card No. 73–2384) and previous studies [23–25]. The crystal plane result indicates that ZnSn(OH)₆ composites have been successfully prepared, with no impurities.

(a)

(b)

(c)

(d)

For further comparison, it can be seen that the peak of the three different shapes of zinc stannate was expected to be different at the 22.8° (200) and 32.4° (220) crystal plane positions. The peaks (220) and (200) increased by increasing the amount of NaOH. It was due to sodium hydroxide’s influence on the materials’ preparation.

After confirming the effect of sodium hydroxide on the crystallites of zinc stannate, the relationship between the reaction time and the formation of the zinc stannate cube was established in Figure 5(b). The experiment was designed for 2, 4, 6, and 8 h as the operating parameters of the hydrothermal reaction time. XRD confirmed the modification of the crystal lattice, the crystal face of zinc stannate appeared in 6 h showing the most vigorous peak intensity of the tetrahedron. On the other hand, in samples 2 and 8 h, the crystallinity of the remaining samples is almost similar. The result showed that 6 and 4 h are the best preparation times, and further explanation also appeared in the SEM section.

The XRD analysis of zinc hydroxide with different amounts of carbon content is shown in Figure 5(c). The result shows the zinc hydroxide content of 1% of carbon and pure zinc hydroxide denoted a similar diffraction pattern and classified as the diffraction peaks of zinc stannate (JCPDS card No. 73-2384). Thus, 1% carbon-doped on the samples did not change the physical structure. However, the XRD analysis could not detect any diffraction peak spectrum by adding more than 10% of carbon to the samples; it could be explained that the excessive amount of carbon destroys the crystal structure of the zinc stannate and no longer exhibited the physical form of the material and might be limited for potential photodegradation of the pollutant.

The effect of temperature on the crystallinity of zinc stannate (Figure 5(d)) can be known from the primary peak intensity of the (200) crystal plane [6], the XRD peak intensity of the crystal face was 18,499, 19,283, and 25,979 nm at 120, 140, and 160°C, respectively, which means that the crystallinity of zinc stannate increased with increasing the temperature.

3.4. FTIR Analysis of Different Shapes of Zinc Stannate

The FTIR absorption peak positions of the three different shapes of zinc stannate (Figure 6(a)), indicating that the functional groups of zinc stannate were not changed by adding NaOH solution. The broad peak of 3000–3500 cm⁻¹ and the characteristic peaks around 1620 cm⁻¹ are attributed to the surface water molecules of zinc stannate or the vibration of ⁻OH bonds in crystal water [26]. The characteristic peak around 2341 cm⁻¹ is attributed to CO₂ adsorbed on the catalyst surface [27, 28]. The peak around 1176 cm⁻¹ is related to the vibration of the zinc stannate zinc Sn-OH bond, and the characteristic peaks of 540 cm⁻¹ and 779 cm⁻¹ are attributed to the internal structure of zinc stannate and O-vibration, respectively, [26, 29]. Those characterization peaks explain that the Sn-OH bond’s vibration is responsible for producing OH radicals. In addition, superoxide was created by the reaction of O-vibration on the catalyst’s surface with an electron. Thus, zinc stannate’s surface-rich hydroxyl group structure and oxygen vibration were beneficial in producing hydroxyl radicals and superoxide with strong oxidizing ability during the photocatalytic reaction, which can effectively degrade the environmental organic pollutants under visible light. On the other hand, as reported by Jose and coauthors [30], the functional groups of the ZnSn(OH)₆ do not change at differences in synthesized temperature.

(a)

(b)

Figure 6(b) illustrates how changing temperatures affect the functional group makeup of cube zinc stannate. The bottom of the zinc stannate was used as a control, and the position of absorption peaks was the same, which means that the temperature did not change the surface of the functional group of the composition of zinc stannate using 1% of carbon-doped in the sample by the regulation of hydrothermal method. In addition, the group still has a large amount of hydroxide on the surface that promotes the progress of the photocatalytic reaction.

3.5. Brunauer–Emmett–Teller (BET) and the Pore Structure Barrett–Joyner–Halenda (BJH) Analysis

The surface structure of three shapes of zinc stannate was analyzed by the N₂adsorption-desorption curve (Figures 7(a)–7(c)). The isotherms belong to the isotherm adsorption curve of class IV. Besides, according to the international union of pure and applied chemistry classification, three shapes of zinc stannate can be found, and the hysteresis belongs to the H3 type. The specific surface areas of cubes, octahedrons, and truncated tetradecahedrons were 8.7, 2.8, and 2.3 m²·g⁻¹, respectively. Due to the large crystal size of the sample, the specific surface areas were relatively small.

(a)

(b)

(c)

(d)

The corresponding BJH pore size distribution is shown in Figure 7(d), and it is shown that the cubic zinc stannate was beneficial to form a structure with a larger pore size; the average pore size of cubic zinc stannate, octahedron zinc stannate, and truncated tetrahedron zinc stannate was 88, 61, and 26 nm, respectively. A larger surface area and porous structure increase the number of reactive sites on the catalyst’s surface, which is beneficial for the adsorption of pollutants during the reaction process and enhances photocatalytic activities. So the cubic zinc stannate might be the best material in this study [15, 31, 32].

3.6. The UV-DRS Absorption Spectrum Analysis

The UV-DRS absorption spectrum analysis was shown in Figure 8. The DRS absorption spectrum analysis was observed from Figure 8(a), the absorption peaks of octahedron zinc stannate, tetradecahedron zinc stannate, and cubic zinc stannate 275, 280, and 320 nm, respectively. The results clearly showed the light absorption range change by the shapes of zinc stannate. This analysis proved that the absorption peaks edge of cubic zinc stannate was closer to the visible light area, so the position of the light adsorption on the cube zinc stannate compared to other materials can be easily applied for the production of OH radicals and superoxide and can achieve the best photocatalytic activities under visible light. Besides, the indirect bandgap of the materials was shown in Figure 8(b), the bandgap of octahedron zinc stannate, tetradecahedron zinc stannate, and cubic zinc stannate are 2.93, 3.06, and 3.01 eV, respectively. These results indicated that the band structure of each shape is different, which directly affects the photocatalytic performance and mechanism of the materials. So the indirect bandgaps of different morphologies of ZnSn(OH)₆ are approximately 3.0 eV. Based on the previous study [33, 34], the conduction band (CB) and the valance band (VB) of the ZnSn(OH)₆ are approximately −0.52 and 3.16 eV vs. NHE, respectively.

(a)

(b)

3.7. Analysis of Photocatalytic Degradation Efficiency of Zinc Stannate with Different Carbon Doping Amounts

The photocatalytic efficiency of zinc stannate with different amounts of carbon on the samples was determined by the degradation of MB dye under visible light (Figure 9(a)). The MB degradation efficiency of various amounts of carbon dopes on cubic zinc stannate was ranked as follows. 0, 1, 5, and 10% carbon with degradation efficiency of 19.13, 89.74, 69.1, and 30.93%, respectively. It can be seen that the photocatalytic efficiency decreases by increasing the amount of carbon by more than 1%. It might explain that an excess amount of carbon reduced the photoreaction in the reactor by decreasing the light penetration and the photoactivity of zinc stannate. The results and the previous XRD analysis demonstrate that excessive carbon destroys stannic acid.

(a)

(b)

As mentioned in the previous section, because the pure zinc stannate cannot work in visible light, so 1% carbon-doped was used as a reference here. As can be seen in Figure 9(b) with different shapes of the samples, the degradation efficiency of zinc stannate for MB degradation was ranked as follows 89.74, 82.06, and 71.88% with the cube, truncated tetradecahedral, and octahedron, respectively. This result is consistent with the DRS analysis in that the light absorption wavelength range of the cubic zinc stannate is much closer to visible light compared to other shapes, and the results of BET and BJH showed a larger specific surface area and having a more significant number of mesopores, all enhancing the photocatalytic efficiency [35, 36].

3.8. Photocatalytic Efficiency Analysis of 1% Carbon-Doped Zinc Stannate at Different Reaction Temperatures

The degradation of MB dye under visible light determined the photocatalytic membrane efficiency of 1% carbon-doped on zinc stannate at different temperatures. In addition, cubic, octahedral, and tetradecahedral carbon blends were evaluated in the impurity content was 1%. The photocatalytic efficiency was optimum at 160°C (Figure 10(a)). The photodegradation results were matched with the XRD analysis because the higher photocatalytic efficiency is denoted at the higher crystallinity simultaneously. So, the material’s crystallinity positively correlates with the photocatalytic efficiency. The results may be explained that a complete decomposition of glucose into carbon doping on the zinc stannate crystal was better by increasing the temperature; the cube’s shape and 1% of carbon-doped on zinc stannate showed the best performance for photocatalytic efficiency evaluations, with 89.74% of degradation of MB under visible light irradiation. Figures 10(b) and 10(c) show the degradation efficiency of various synthetic temperatures of octahedron and tetradecahedron. Both of them at 1% of carbon-doped on zinc stannate and tetrahedral shape denoted that the photocatalytic efficiency was increased with increasing the temperature. Furthermore, the cube-shaped 1% carbon-doped on tin hydroxide zinc acid exhibited the best performance in all photocatalytic efficiency evaluated. The removal efficiency of MB under visible light irradiation was reached at 89.74% and was effectively consistent with the characterizations above.

(a)

(b)

(c)

The result was also compared in Table 3 to some previous studies on the degradation of dyes based on ZnSn(OH)₆ photocatalyst and realized that most of that experiments used high energy (UV-light) and low dyes concentration to induce the degradation of dye using ZnSn(OH)₆. Our research showed a better performance due to the highly efficient degradation of high-concentration dyes under visible light. Although the efficiency of the catalyst interval is high, applying the photocatalytic membrane can be considered a better strategy of innovation to achieve a better degradation result.

3.9. Photocatalytic Mechanism of Degradation of MB

The photocatalytic mechanism of the proposed carbon-doped zinc stannate for MB degradation under visible light is shown in Figure 11. The electrons were excited and moved to the CB of ZnSn(OH)₆ to generate excess e⁻ and h⁺ under visible light. Under the support of carbon quantum dots, the excess e⁻ in the CB of ZnSn(OH)₆ could transfer to the carbon dots for the reaction reactions. According to the discussed band structure, the CB of the ZnSn(OH)₆ (−0.52 eV vs NHE) is higher than the O₂/ (−0.33 eV vs NHE), so the excess e⁻ can reduce O₂ to form radicals. The radicals prompted the oxidization of MB. On the other hand, the excess h⁺ produced •OH⁻ radicals from water. Then, the •OH⁻ radicals degraded MB [22, 25]. The recombination of e⁻ and h⁺ was reduced under supporting carbon quantum dots, which helped enhance the photocatalytic performances of the material. After coating the carbon-doped zinc stannate on the membrane, by turning on the light, the electrons (e⁻) were moved to the conduction band (CB), and the holes (h⁺) were active in the valance band (VB) as shown in equation (1). Equation (2) shows the production of the superoxide , when the electrons were reacted with the oxygen on the surface of the catalyst coated on the membrane. Then, equation (3) explains the production of the OH radicals . Finally, the degradation products are shown in equations (4) and (5).

4. Conclusions

The result of the experiment confirmed that the preparation of carbon-doped zinc stannate was effectively prepared by the hydrothermal method. The morphology of zinc stannate changed by adding different NaOH dosages. The effect of NaOH dosage and synthesis time on the morphology, specific surface area, and light absorption of ZnSn(OH) SEM, BET confirmed ₆, and DRS. The BJH analysis showed that the cubic stannate composite had the best pore size. As a result, the BET showed the surface area of cubic zinc stannate (8.7 m²·g⁻¹) to be better than tetradecahedron (2.8 m²·g⁻¹) and octahedron (2.3 m²·g⁻¹). In addition, the XRD and FTIR confirm no change in the crystal structure and chemical bonding between each shape of ZnSn(OH)₆. The results show that 1% of carbon-doped on ZnSn(OH)₆ cubic by hydrothermal method at 160°C for 6 h reached the highest photocatalytic efficiency of MB (89.74%) under visible light. The photocatalytic results confirmed that the cubic shape of ZnSn(OH)₆ is a potential catalyst for the photodegradation of MB, and carbon-ZnSn(OH)₆ coupled with a photocatalytic membrane is promising for future applications.

Data Availability

The data used to support the study are available from the corresponding author upon request.

Conflicts of Interest

The authors declare there are no conflicts of interest.

Acknowledgments

The authors want to present their gratitude to Chung Yuan Christian University (Taiwan) for supporting this work. The work was supported by Chung Yuan Christian University under Project no. 109609432.

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Copyright © 2023 Ernso Fenelon et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Journal of Chemistry

Photodegradation of Methylene Blue Using Carbon-Doped ZnSn(OH)6 Composite Coated on Membrane

Abstract

1. Introduction

2. Experimental Section

2.1. Material and Chemical

2.2. Preparation of Zinc Stannate

2.3. Preparation of Carbon-Doped Zinc Stannate

2.4. Catalyst Coating Membrane

2.5. Photocatalytic Characteristics

2.6. Modified Photocatalytic Membrane Experiment

3. Result and Discussion

3.1. Effect of Different NaOH Concentrations on the Shape of Zinc Stannate

3.2. SEM Analysis of Different Reaction Times on the Shape of Zinc Stannate

3.3. Analysis of XRD of Different Morphology of Zinc Stannate

3.4. FTIR Analysis of Different Shapes of Zinc Stannate

3.5. Brunauer–Emmett–Teller (BET) and the Pore Structure Barrett–Joyner–Halenda (BJH) Analysis

3.6. The UV-DRS Absorption Spectrum Analysis

3.7. Analysis of Photocatalytic Degradation Efficiency of Zinc Stannate with Different Carbon Doping Amounts

3.8. Photocatalytic Efficiency Analysis of 1% Carbon-Doped Zinc Stannate at Different Reaction Temperatures

3.9. Photocatalytic Mechanism of Degradation of MB

4. Conclusions

Data Availability

Conflicts of Interest

Acknowledgments

References

Copyright

Photodegradation of Methylene Blue Using Carbon-Doped ZnSn(OH)₆ Composite Coated on Membrane