Research Article

Solid-Liquid Phase Equilibria of the Quaternary System NaCl + NH4Cl + NaHCO3 + NH4HCO3 + H2O at 283.15 and 313.15 K

Table 2

The comparison of solubility data of ternary systems at 283.15 K, 313.15 K, and 0.1 MPaa.

NoComposition of liquid phase, 100 bSolid phasecReference
Na+NH4+ClHCO3

283.15 K
110.510.0015.800.59S + SBThis work
24.257.2919.360.00A + S[13]
4.966.2319.920.00A + SThis work
30.009.0315.693.62AB + AThis work
41.392.450.0012.00AB + SBThis work

313.15 K
111.210.0015.620.94S + SB[12]
10.480.0015.620.99S + SBThis work
26.0176.6322.050.00A + S[14]
5.916.7322.410.00A + SThis work
30.0012.2519.098.73AB + AThis work
1.465.110.0021.20AB + SB[12]
41.706.140.0025.30AB + SBThis work

aStandard uncertainties u are u (T) = 0.1 K, u (p) = 0.005 MPa, ur (Na+) = 0.003, ur (NH4+) = 0.003, ur (Cl) = 0.003, and ur (HCO3) = 0.003. b, Mass fraction, cA: NH4Cl, S: NaCl, AB: NH4HCO3, SB: NaHCO3.