Journal of Chemistry / 2023 / Article / Tab 2 / Research Article
Solid-Liquid Phase Equilibria of the Quaternary System NaCl + NH4 Cl + NaHCO3 + NH4 HCO3 + H2 O at 283.15 and 313.15 K Table 2 The comparison of solubility data of ternary systems at 283.15 K, 313.15 K, and 0.1 MPaa .
No Composition of liquid phase, 100 b Solid phasec Reference Na+ NH4 + Cl− HCO3 − 283.15 K 1 10.51 0.00 15.80 0.59 S + SB This work 2 4.25 7.29 19.36 0.00 A + S [13 ] 4.96 6.23 19.92 0.00 A + S This work 3 0.00 9.03 15.69 3.62 AB + A This work 4 1.39 2.45 0.00 12.00 AB + SB This work 313.15 K 1 11.21 0.00 15.62 0.94 S + SB [12 ] 10.48 0.00 15.62 0.99 S + SB This work 2 6.017 6.63 22.05 0.00 A + S [14 ] 5.91 6.73 22.41 0.00 A + S This work 3 0.00 12.25 19.09 8.73 AB + A This work 1.46 5.11 0.00 21.20 AB + SB [12 ] 4 1.70 6.14 0.00 25.30 AB + SB This work
a Standard uncertainties
u are
u (
T ) = 0.1 K,
u (
p ) = 0.005 MPa,
u r (Na
+ ) = 0.003,
u r (NH
4 + ) = 0.003,
u r (Cl
− ) = 0.003, and
u r (HCO
3 − ) = 0.003.
b , Mass fraction,
c A: NH
4 Cl, S: NaCl, AB: NH
4 HCO
3 , SB: NaHCO
3 .