Research Article

Cryptogamic Packed Biofilter as Potential Adsorbent for CO2, NH3, and H2S Impurities from Biogas

Table 5

Absorption properties of the cryptogamic filter compared to other biofilters.

Bed type/adsorbentGasImpurity gasLoading rateRE (%)Elimination capacityDisadvantageReference

Peat biofilterNH320 ppmv1.8 g m-3 hr-18041 g m−3 d−1Overloads at a loading rate of 7.9 gm-3 hr-1. Prone to channeling and maldistribution. Limited ability to neutralize acidic degradation products[49]
Perlite biofilterNH320-50 ppmv8.6 g m−3 d−1 and 21.5 g m−3 d−199.5NAProduction of NO and NO2 at the outlet[38]
Cow manure compostH2S~ 1500 ppm58 m3 h−18016–118 g m-3 h-1High operating costs, clogging to deposition of elemental sulfur[50]
Red mudH2S200 ppm0.0048NA2.1 g H2S/100 gDue to the small mass of adsorbent, H2S removal was low[42]
Biomass ashCO2 and H2S100–600 ppm H2S, 33–35% CO20.56-1.25 kg H2S t-1 ash, 35 kg CO2 t-1 ash, and 135 kg CO2 t-1 ash50 for H2S, not feasible for CO2NANot feasible for CO2 removal, ashes could not be reused for as fertilizer[51]
T3, T4 soil substratesH2S771-819 ppm0.0048 m3 h-193, 9720.8, 20.1 g S/100 gA constant flow  m3/hr to prevent large pressure dropThis study
Moss substrateCO2, NH3, H2SCO2 31.6%, H2S 307 ppm, NH3 13 ppm0.006 m3 h-159 CO2, 38 NH3, 68 H2S6.0 g S/100 g of sorbentThe flow  m3/hr to prevent intoxication of microbes by NH3 and H2S presentThis study
Cryptogamic filterCO2, NH3, H2SCO2 38%, NH3 8.7 ppm, H2S 819 ppm0.006 m3 h-199.7 CO2, 77.2 NH3, 98.6 H2S11 g S/100 gIt does not work on high pressure, high flow rate operation, and requires water scrubber for removal of excess oxygenThis study

NA: not applicable/addressed.