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Journal of Nanomaterials
Volume 2006 (2006), Article ID 83583, 5 pages

Surface Functionalization of Multiwalled Carbon Nanotube with Trifluorophenyl

1Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials and Key Laboratory of the Ministry of Education on Nanomaterials, Beijing University of Chemical Technology, Beijing 100029, China
2Department of Physics, University of Potsdam, Potsdam 14469, Germany
3School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

Received 21 March 2006; Revised 15 May 2006; Accepted 5 June 2006

Academic Editor: Jun Liu

Copyright © 2006 Zhi-Min Dang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A new approach to dispersion of multiwalled carbon nanotube (MWNT) in common polar solvents was reported. Here, a detailed study of nanotube chemistry by using trifluorophenyl (TFP) to modify the surface of MWNT was discussed, which was not reported before. A characterization of the reaction products using a variety of techniques was provided. The results confirmed that the surface of MWNT was successfully functionalized. Furthermore, trifluorophenyl multiwalled carbon nanotube (TFP-MWNT) was well dispersed in polar solvents, such as tetrahydrofuran (THF), acetic acid (Ac), N,N-dimethyl formamide (DMF), dimethyl sulfoxide (DMSO), due to the adsorption of trifluorophenyl groups on the surface of raw MWNT. Following chemical modification, dispersed individual nanotube suggests the potentials for wide applications.