Reversible and Irreversible Binding of Nanoparticles to Polymeric Surfaces

Table 1

Physical properties of statistical and block copolymers.

Polymer 1		n	m	Yield [%]	𝑀𝑛,th	𝑀𝑛	𝑀𝑤	𝑀𝑤/𝑀𝑛	Polymer 3	𝑀𝑛	𝑀𝑤/𝑀𝑛
Statistical	s5	1	99	99	42 532	37 900	41 380	1.1	s5	38 630	1.1
Block	b1	30	70	97	39 740	28 450	31 920	1.1	b1	49 210	1.2
Block	b2	10	90	97	41 659	25 840	26 980	1.1	b2	33 030	1.1
Block	b5	1	99	78	42 532	27 240	28 600	1.1	b5	27 960	1.1
Polymer 5/statistical		50	50	99	37 813	34 170	37 020	1.1	—	—	—
Polymer 4/homo		0	100	99	42 553	32 520	34 710	1.1	—	—	—
Polymer	s6	0.5	99.5	Prepared by mixing of polymer 3/s5 with polymer 4 (1∶1)
Polymer	s7	0.1	99.9	Prepared by mixing of polymer 3/s5 with polymer 4 (1∶9)
Polymer	s8	0.01	99.99	Prepared by mixing of polymer 3/s5 with polymer 4 (1∶99)