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Journal of Nanomaterials
Volume 2011, Article ID 267415, 6 pages
Research Article

One-Step Nonaqueous Synthesis of Pure Phase TiO2 Nanocrystals from TiCl4 in Butanol and Their Photocatalytic Properties

1Centre for Advanced Optoelectronic Functional Materials Research, Key Laboratory for UV Light-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, Changchun 130024, China
2Faculty of Chemistry, Baicheng Normal University, Baicheng 137000, China

Received 10 July 2010; Revised 17 February 2011; Accepted 17 March 2011

Academic Editor: P. Panine

Copyright © 2011 Tieping Cao et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Pure phase TiO2 nanomaterials were synthesized by an autoclaving treatment of TiCl4 with butanol as a single alcohol source. It was found that the control of molar ratio of TiCl4 to butanol played an important role in determining the TiO2 crystal phase and morphology. A high molar ratio of TiCl4 to butanol favored the formation of anatase nanoparticles, whereas rutile nanorods were selectively obtained at a low molar ratio of TiCl4 to butanol. Evaluation of the photocatalytic activity of the synthesized TiO2 was performed in terms of decomposition of organic dye rhodamine B under ultraviolet irradiation. It turned out that the as-synthesized TiO2 crystallites possessed higher photocatalytic activities toward bleaching rhodamine B than Degussa P25, benefiting from theirhigh surface area, small crystal size as well as high crystallinity.