Table of Contents Author Guidelines Submit a Manuscript
Journal of Nanomaterials
Volume 2011 (2011), Article ID 326472, 5 pages
http://dx.doi.org/10.1155/2011/326472
Research Article

Pore Structure Control of Ordered Mesoporous Silica Film Using Mixed Surfactants

1Department of Materials Science and Engineering, Yonsei University, 134 Sinchon-dong, Seodaemun-gu, Seoul 120-749, Republic of Korea
2Electronic Materials Research Center, Korea Institute of Science and Technology, Seoul 130-650, Republic of Korea

Received 23 December 2010; Revised 17 March 2011; Accepted 19 April 2011

Academic Editor: Shaogang Hao

Copyright © 2011 Tae-Jung Ha et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. Rouquerol, D. Avnir, C. W. Fairbridge et al., “Recommendations for the characterization of porous solids (Technical Report),” Pure and Applied Chemistry, vol. 66, p. 1739, 1994. View at Google Scholar
  2. V. Chiola, J. E. Ritsko, and C.D. Vanderpool, Process for producing low-bulk density silica, U.S. Patent 3556725, 1971.
  3. S. Inagaki, S. Ogata, Y. Goto, and Y. Fukushima, “Mesoporous materials derived from layered silicates and the adsorption properties,” Studies in Surface Science and Catalysis, vol. 117, pp. 65–76, 1998. View at Google Scholar · View at Scopus
  4. R. Ryoo, J. M. Kim, C. H. Ko, and C. H. Shin, “Disordered molecular sieve with branched mesoporous channel network,” Journal of Physical Chemistry, vol. 100, no. 45, pp. 17718–17721, 1996. View at Google Scholar · View at Scopus
  5. S. E. Park, “Application of Mesoporous Molecular Sieves,” Chemistry World, vol. 38, no. 11, pp. 30–39, 1998. View at Google Scholar
  6. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, and J. S. Beck, “Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism,” Nature, vol. 359, no. 6397, pp. 710–712, 1992. View at Google Scholar · View at Scopus
  7. Y. Lu, R. Ganguli, C. A. Drewien et al., “Continuous formation of supported cubic and hexagonal mesoporous films by sol-gel dip-coating,” Nature, vol. 389, no. 6649, pp. 364–368, 1997. View at Publisher · View at Google Scholar · View at Scopus
  8. R. Nagarajan, Structure-Performance Relationships in Surfactants, part 1.1, Marcel Dekker, New York, NY, USA, 2003.
  9. S. P. Moulik, “Micelles: self-organized surfactant assemblies,” Current Science, vol. 71, no. 5, pp. 368–376, 1996. View at Google Scholar
  10. N. Igarashi, K. A. Koyano, Y. Tanaka, S. Nakata, K. Hashimoto, and T. Tatsumi, “Investigation of the factors influencing the structural stability of mesoporous silica molecular sieves,” Microporous and Mesoporous Materials, vol. 59, no. 1, pp. 43–52, 2003. View at Publisher · View at Google Scholar · View at Scopus
  11. J. S. Choi, D. J. Kim, S. H. Chang, and W. S. Ahn, “Catalytic applications of MCM-41 with different pore sizes in selected liquid phase reactions,” Applied Catalysis A, vol. 254, no. 2, pp. 225–237, 2003. View at Publisher · View at Google Scholar · View at Scopus
  12. R. L. Putnam, N. Nakagawa, K. M. McGrath et al., “Titanium dioxide—surfactant mesophases and Ti-TMS1,” Chemistry of Materials, vol. 9, no. 12, pp. 2690–2693, 1997. View at Google Scholar · View at Scopus
  13. D. Zhao, J. Feng, Q. Huo et al., “Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores,” Science, vol. 279, no. 5350, pp. 548–552, 1998. View at Publisher · View at Google Scholar · View at Scopus
  14. J. R. Matos, M. Kruk, L. P. Mercuri et al., “Ordered mesoporous silica with large cage-like pores: structural identification and pore connectivity design by controlling the synthesis temperature and time,” Journal of the American Chemical Society, vol. 125, no. 3, pp. 821–829, 2003. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  15. A. Doyle and B. K. Hodnett, “Stability of MCM-48 in aqueous solution as a function of pH,” Microporous and Mesoporous Materials, vol. 63, pp. 53–57, 2003. View at Google Scholar
  16. L. Z. Wang, J. L. Shi, J. Yu, W. H. Zhang, and D. S. Yan, “Temperature control in the synthesis of cubic mesoporous silica materials,” Materials Letters, vol. 45, no. 5, pp. 273–278, 2000. View at Google Scholar · View at Scopus
  17. L. Chen, J. Xu, W. H. Zhang, J. D. Holmes, and M. A. Morris, “Syntheses of complex mesoporous silicas using mixtures of nonionic block copolymer surfactants: understanding formation of different structures using solubility parameters,” Journal of Colloid and Interface Science, vol. 353, no. 1, pp. 169–180, 2011. View at Google Scholar
  18. S.-B. Jung, T.-J. Ha, J.-B. Seon, and H.-H. Park, Microporous and Mesoporous Materials, vol. 111, no. 1-3, pp. 188–193, 2008.
  19. M. Yan, S. Dourdain, and A. Gibaud, “Analysis of water condensation in P123 templated 2D hexagonal mesoporous silica films by X-ray reflectivity,” Thin Solid Films, vol. 516, no. 22, pp. 7955–7961, 2008. View at Publisher · View at Google Scholar · View at Scopus
  20. P. K. Kipkemboi, P. C. Kiprono, and P. Kndalut, “Preparation of mesoporous silica with amphiphilic poly(oxyethylene)/ poly (oxybutylene) diblock and poly(oxyethylene)/poly(oxypropylene) triblock copolymers as templates,” Indian Journal of Chemistry—Section A, vol. 48, no. 4, pp. 498–503, 2009. View at Google Scholar · View at Scopus
  21. T.-J. Ha, H.-H. Park, S.-Y. Jung, S.-J. Yoon, J.-S. Kim, and H.W. Jang, “Effect of porosity on the Seebeck coefficient of mesoporous TiO2 thin films,” Thin Solid Films, vol. 518, no. 24, pp. 7196–7198, 2010. View at Google Scholar
  22. S. K. Hait and S. P. Moulik, “Determination of critical micelle concentration (CMC) of nonionic surfactants by donor-acceptor interaction with iodine and correlation of CMC with hydrophile-lipophile balance and other parameters of the surfactants,” Journal of Surfactants and Detergents, vol. 4, no. 3, pp. 303–309, 2001. View at Google Scholar · View at Scopus
  23. Y. L. Su and H. Z. Liu, “Temperature-dependent solubilization of PEO-PPO-PEO block copolymers and their application for extraction trace organics from aqueous solutions,” Korean Journal of Chemical Engineering, vol. 20, no. 2, pp. 343–346, 2003. View at Google Scholar · View at Scopus
  24. F. Y. Wei, Z. W. Liu, J. Lu, and Z. T. Liu, “Synthesis of mesoporous MCM-48 using fumed silica and mixed surfactants,” Microporous and Mesoporous Materials, vol. 131, no. 1–3, pp. 224–229, 2010. View at Publisher · View at Google Scholar · View at Scopus
  25. C. Liu, S. Wang, Z. Rong, X. Wang, G. Gu, and W. Sun, “Synthesis of structurally stable MCM-48 using mixed surfactants as co-template and adsorption of vitamin B12 on the mesoporous MCM-48,” Journal of Non-Crystalline Solids, vol. 356, no. 25–27, pp. 1246–1251, 2010. View at Publisher · View at Google Scholar