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Journal of Nanomaterials
Volume 2011 (2011), Article ID 869618, 8 pages
Research Article

Preparation and Characterization of Pure Rutile TiO2 Nanoparticles for Photocatalytic Study and Thin Films for Dye-Sensitized Solar Cells

1Institute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan
2Department of Chemistry, National Central University, Chung-Li 320, Taiwan

Received 31 May 2010; Accepted 8 September 2010

Academic Editor: William W. Yu

Copyright © 2011 Huei-Siou Chen et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Pure rutile-phase TiO2 (r-TiO2) was synthesized by a simple one pot experiment under hydrothermal condition using titanium (IV) n-butoxide as a Ti-precursor and HCl as a peptizer. The TiO2 products were characterized by XRD, TEM, ESCA, and BET surface area measurement. The r-TiO2 were rodlike in shape with average size of ~61×32 nm at hydrothermal temperature of 220°C for 10 h. Hydrothermal treatment at longer reaction time increased the tendency of crystal growth and also decreased the BET surface area. The degradation of methylene blue was selected as a test reaction to confer the photocatalytic activity of as-obtained r-TiO2. The results showed a strong correlation between the structure evolution, particle size, and photocatalytic performance of r-TiO2. Furthermore, the r-TiO2-based solar cell was prepared for the photovoltaic characteristics study, and the best efficiency of ~3.16% was obtained.