Functionalization of Silica Nanoparticles for Polypropylene Nanocomposite Applications

<table>Solid state <sup>29</sup>Si CP MAS NMR spectra for the unmodified (A) and modified 20 nm particles with TMCS (B) and DMOCS (C). The notation “R” at <i>δ</i>, <i>ε</i> and <svg height="17.9125" id="M8" style="vertical-align:-0.1638pt" version="1.1" viewbox="0 0 11.25 17.9125" width="11.25" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,0,0,-.017,.062,17.65)"><path d="M387 375q0 -16 -17 -31t-29 -15q-9 0 -12 13q-13 74 -80 74q-36 0 -61 -24.5t-25 -56.5t24 -51.5t68 -19.5q33 0 47 2l2 -7l-32 -42q-20 2 -54 2q-45 0 -74 -21.5t-29 -60.5q0 -41 28 -65.5t73 -24.5q78 0 145 67l17 -23q-33 -47 -84.5 -75t-111.5 -28q-70 0 -114.5 35.5
t-44.5 92.5q0 46 38 78t95 45v2q-35 10 -54.5 33t-19.5 52q0 55 53 88.5t122 33.5q67 0 98.5 -23.5t31.5 -49.5z" id="x1D700"></path></g>
<g transform="matrix(.012,0,0,-.012,7.037,9.488)"><path d="M227 744l-123 -338l-31 15l73 368q12 3 41.5 -8t36.5 -20z" id="x2032"></path></g>
</svg> corresponds to methyl (TMCS) or octyl (DMOCS) groups.</table>

Journal of Nanomaterials

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Figure 3

Figure 3: Functionalization of Silica Nanoparticles for Polypropylene Nanocomposite Applications 