Journal of Nanomaterials

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Photoluminescence Properties of Nanocrystals

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Volume 2012 |Article ID 963485 |

Hui Che, Jesse Huso, John L. Morrison, Dinesh Thapa, Michelle Huso, Wei Jiang Yeh, M. C. Tarun, M. D. McCluskey, Leah Bergman, "Optical Properties of ZnO-Alloyed Nanocrystalline Films", Journal of Nanomaterials, vol. 2012, Article ID 963485, 7 pages, 2012.

Optical Properties of ZnO-Alloyed Nanocrystalline Films

Academic Editor: J. C. Sczancoski
Received27 Nov 2011
Revised28 Feb 2012
Accepted08 Mar 2012
Published14 May 2012


ZnO is emerging as one of the materials of choice for UV applications. It has a deep excitonic energy level and a direct bandgap of ~3.4 eV. Alloying ZnO with certain atomic constituents adds new optical and electronic functionalities to ZnO. This paper presents research on Mg𝑥Zn𝟏𝑥O and ZnS𝟏𝑥O𝑥 nanocrystalline flexible films, which enable tunable optical properties in the deep-UV and in the visible range. The ZnO and Mg0.3Zn0.7O films were found to have bandgaps at 3.35 and 4.02 eV, respectively. The photoluminescence of the Mg0.3Zn0.7O exhibited a bandedge emission at 3.95 eV, and at lower energy 3.38 eV due to the limited solubility inherent to these alloys. ZnS0.76O0.24 and ZnS0.16O0.84 were found to have bandgaps at 3.21 and 2.65 eV, respectively. The effect of nitrogen doping on ZnS0.16O0.84 is discussed in terms of the highly lattice mismatched nature of these alloys and the resulting valence-band modification.

1. Introduction: The Mg𝑥Zn1𝑥O and ZnS1𝑥O𝑥 Alloy Systems

Zinc oxide (ZnO) is a direct bandgap semiconductor with a bandgap of ~3.37 eV at room temperature and relatively deep excitonic binding energy of 60 meV, both attributes of which make ZnO an efficient UV optical material at and above room temperature [16]. Due to their environmentally friendly chemical nature, resistivity to harsh environments, and deep excitonic level, ZnO as well as Mg𝑥Zn1𝑥O (where 𝑥 is the composition) are emerging materials capable of high-efficiency luminescence in a wide range of the ultraviolet (UV) spectrum [68].

ZnO has the hexagonal wurtzite structure, while MgO has the NaCl cubic structure with a direct bandgap ~7.5 eV and excitonic binding energy ~140 meV [9, 10]. Alloying these two provides a family of materials with tunable optical and electronic properties. Although the atomic sizes of Mg and Zn are comparable, that is, Mg𝑥Zn1𝑥O is considered to be a lattice-matched system, due to the two different crystal structures the two oxides do not show complete solid solubility. Despite this inherent property, Mg𝑥Zn1𝑥O alloys with tunable optical properties over a large composition range have been realized [7, 8, 11, 12]. The exact properties were found to be somewhat growth dependant; the general trend of the bandgap behavior indicates that at Mg composition up to ~35% the alloy is soluble and has mainly the wurtzite structure with bandgap spanning the range of ~3.4–4 eV. At the composition range of ~35%–60% (referred to as the transition range), the alloy is phase separated into the wurtzite and the cubic structures, and at Mg composition above ~60% it has the cubic structure and bandgaps tuned in the range ~5–7 eV. Figure 1 presents a general schematic of the bandgap behavior of the Mg𝑥Zn1𝑥O alloy system.

Another alloy system that may be proven to be very useful is ZnS1𝑥O𝑥 that potentially should allow tuneability into the visible range. To date, very little is known about its material, electronic and optical properties [13]. ZnS with the zinceblende structure has a direct bandgap ~3.84 eV [14]. The substituting anions in the ZnS1𝑥O𝑥 alloy have large differences in size and chemical properties: the covalent radii of sulfur and oxygen are 1.02 Å and 0.73 Å, respectively, and their electronegative values are 2.58 and 3.44. This alloy is considered to be a highly lattice mismatched system. As a consequence, the ZnS1𝑥O𝑥 alloy system has been predicted to have unusual material properties that should add new functionality to ZnO [14, 15]. First-principle plane-wave calculations by Moon et al. on highly mismatched II–VI alloys have predicted that these alloys possess huge bowing coefficients, that is, a significant deviation from linearity upon going from one end member of the alloy to the second [14]. Figure 2 presents the calculated bandgap of ZnS1𝑥O𝑥 as a function of composition 𝑥 [14]. In general terms, the cause of the large bowing parameter of these highly mismatched alloys has been attributed to hybridization and creation of resonance defect-like states at the gap edges. For example, at the low regime of sulfur concentration, the bowing into the visible is due to the raising of the valence band, while the conduction band is only slightly affected by the alloying [15]. Several groups reported similar unusual alloy properties of other highly mismatched systems such as GaAs𝑥N1𝑥 and GaN1𝑥Bi𝑥 [1618]. In Figure 2, the square dots represent our experimental result that will be discussed in detail in the following sections. The advantages of having a highly lattice mismatched alloy is that for a relative small concentration of sulfur a significant modification of the bandgap can be attained that enables optical properties in the visible.

2. Experiment

The substrate used for the experiments is commercially available fluorinated ethylene propylene (FEP), also known as Teflon FEP, which is flexible and UV-transparent. The ZnO and the Mg0.3Zn0.7O samples were grown at room temperature on prepared FEP substrates utilizing magnetron sputtering of Zn and Mg–Zn targets, respectively, under argon plasma. The samples were then oxidized for 2 hours under an atmosphere of 99.99% pure oxygen at a temperature of 275°C. The ZnS𝑥O1𝑥 films were grown by a reactive RF magnetron sputtering system, at 300°C, using a ceramic ZnS target and argon as the sputtering gas. In addition to the argon, controlled amounts of oxygen and nitrogen were introduced during the growth process so to achieve nitrogen-doped ZnS𝑥O1𝑥 films. The nitrogen pressure in the chamber was approximately 2.1×105 Torr. The films were sputtered at 50 W for 1.5 hours. The nitrogen incorporation was verified by X-ray photoelectron spectroscopy (XPS). The compositions of the alloys were determined via energy dispersive spectroscopy (EDS).

The photoluminescence (PL) experiments utilized a JY-Horiba micro-Raman/PL system consisting of a high-resolution T-64000 triple monochromator and a UV confocal microscope capable of focusing to a spot size of ~1 μm diameter. A CW-Kimmon laser with a wavelength of 325 nm (3.8 eV) and a Lexel Laser at 244 nm (5.1 eV) were used as the excitation source for the PL, and the cold temperature PL measurements were conducted in an INSTEC UV-compatible microcell. The subgap PL spectra were obtained, at room temperature, using a JY-Horiba FluoroLog-3 spectrofluorometer with a 450-W xenon lamp as the excitation source at 490 nm. The transmission spectra were acquired at room temperature using an Agilent Cary-300 system. The transmission data were acquired with a double-beam technique, and the data were normalized relative to the transparent region. Both procedures allow us to neglect equipment response as well as Fresnel reflections and scattering losses at the long wave length limit up to near the bandgap value.

3. Results and Discussion

Figures 3 and 4 present scanning electron microscope (SEM) images and photographs of the ZnO and Mg0.3Zn0.7O flexible films [6], and Figure 5 presents those of the ZnS0.16O0.84. As is depicted in the figures, the morphology of the films is structured: in the nanoscale regime for ZnO and Mg0.3Zn0.7O and at submicron regime for ZnS0.16O0.84. An extended discussion on the material properties of our flexible films can be found in [6]. In order to estimate the bandgaps of the alloys, transmission spectra were acquired at room temperature and are presented in Figures 6(a) and 6(b). As can be seen in the figure, the alloys exhibit a rather broad absorption edge that is attributed to localized states due to the inherent alloy disorder and phase segregations. When the absorbance bandgap is not sharply defined, the usual method of extrapolation [20] may not render good results. To estimate the bandgap in such cases, transmission derivative procedures can be utilized, which were successfully used previously for the analysis of the bandgaps of Mg𝑥Zn1𝑥O and In𝑥Ga1𝑥N [6, 2123]. In the following, we present the derivation of the method applicable to direct bandgap transitions.

The transmission through a film may be approximated as [20, 24][]𝑇(𝐸)1𝑅(𝐸)2𝑒𝛼(𝐸)𝑡,(1) where 𝐸 is the energy of the incident light, 𝑅 is the reflectance, and 𝑡 is the thickness of the film. In (1), the absorption coefficient 𝛼 may be written as [25]𝐶𝛼(𝐸)=𝐸𝜂𝑟(𝐸)𝐸𝐸𝑔,(2) where 𝜂𝑟(𝐸) is the energy-dependent index of refraction and 𝐶 is a constant. In obtaining the transmission derivative one needs to consider the behavior of the reflectance near the bandgap energy. It can be shown that as 𝐸𝐸𝑔, the quantities 1𝑅(𝐸) and 𝑑𝑅(𝐸)/𝑑𝐸 remain finite at energies in the vicinity of 𝐸𝑔 due to the existence of a band tail which prevents a singularity-type behavior. Experimental results concerning ZnO thin film properties indeed found that the reflectance and its derivative are well-behaved quantities near the bandgap energy [26]. Consequently, for the purposes of our analysis we may write the transmission through a direct gap semiconductor as𝑇(𝐸)=𝑒𝐶(1/𝐸𝜂𝑟(𝐸))𝐸𝐸𝑔,(3) where 𝐶=𝐶𝑡. The first derivative of 𝑇(𝐸) with respect to energy is then𝑑𝑇𝑑𝐸=𝐶1𝐸2𝜂𝑟(𝐸)𝐸𝐸𝑔𝑑𝜂𝑟(𝐸)𝑑𝐸𝐸𝐸𝑔𝐸𝜂𝑟(𝐸)2+12𝐸𝜂𝑟(𝐸)𝐸𝐸𝑔exp𝐶1𝐸𝜂𝑟(𝐸)𝐸𝐸𝑔,(4) and at the limit 𝐸𝐸𝑔, one getslim𝐸𝐸𝑔𝑑𝑇𝑑𝐸=1𝐶100+0,(5) which yields a spike towards negative infinity at 𝐸=𝐸𝑔. It was assumed that 𝑑𝜂𝑟(𝐸)/𝑑𝐸is continuous around 𝐸𝑔 due to band tail states as was discussed in [27, 28]. Thus, a plot of 𝑑𝑇/𝑑𝐸 versus 𝐸 will exhibit a strong singularity at the bandgap energy. In realistic cases, absorption tails exist, which soften the divergence and result in well-defined peaks around the gap energy, as also can be seen in Figure 7.

From Figure 7, the ZnO film has a bandgap of ~3.35 eV at room temperature, which is consistent with previous reports [29], while that of Mg0.3Zn0.7O is at ~4.02 eV, a value similar to that previously observed for thin films grown via the pulsed laser deposition [7]. The bandgap of the ZnS0.16O0.84 and ZnS0.76O0.24 alloys are 2.65 and 3.21 eV, respectively, values which agree with those predicated from the first-principle plane-wave calculations presented in Figure 2 [14]. As such the transmission derivative method estimates well the bandgap of our materials.

The PL properties of the films presented in Figures 8 and 9 show that the Mg0.3Zn0.7O film has two optical emissions: one at 3.38 and the other at a 3.95 eV. At Mg composition of ~30%, the sample is expected to be phase segregate due to the limited solubility of the MgO–ZnO solid solution (see Figure 1). Accordingly, the peak emissions at 3.38 and at 3.95 eV are attributed to ZnO-rich and to MgO-rich domains, respectively. The ZnS0.16O0.84 film was found to luminesce at the visible range of 2.48 eV; however, the PL intensity was only visible at 77 K, and the PL of the ZnS0.76O0.24 was found to be extremely weak. The low efficiency of the PL may be a result of a significant concentration of structural defects due to the highly mismatched nature of this alloy system. As can be seen in Figure 5(b), the morphology of the sample is very coarse, unlike that of the MgZnO film presented in Figure 3. These structural defects may act as nonradiative centers impeding the PL efficiency.

Mapping of the bandgap via luminescence is a very informative technique for the study of deep impurities and defect centers in ZnO. ZnO has been found to have a characteristic broad In-gap PL with components in the green, yellow, and red part of the spectrum [3032]. Although the origins of these PL are as yet under investigation, the consensus is that they are related to oxygen and zinc vacancies as well as to interstitial oxygen. In addition to those intrinsic centers, it was established that nitrogen doped ZnO also exhibits a broad in-gap PL at ~1.7 eV [19, 33]. Recent findings concerning the characteristics of nitrogen in ZnO found that nitrogen is a deep acceptor with acceptor level 1.3 eV above the valence band maximum [19, 34].

Unlike the deep level of nitrogen in ZnO, in ZnS1𝑥O𝑥 the acceptor level was predicated to be relatively shallow for the low regime of sulfur concentration [15]. As was discussed in the introduction, this comes about due to the rising of the valence band toward the acceptor level upon alloying. The implication of the phenomenon is that p-type doping might be realized in lightly alloyed ZnO. Figure 10 presents the in-gap PL spectrum of nitrogen-doped ZnO taken from [19] and that of the ZnS0.16O0.84 film that exhibits a broad PL band at ~ 1.88 eV. The close proximity of the two peak positions and their similar linewidths suggest that that PL of the ZnS0.16O0.84 is due to nitrogen centers. Based on the in-gap PL emission, and the bandgap found for the ZnS0.16O0.84, a tentative bandgap diagram is presented in Figure 11 for which the nitrogen impurity has a level of ~0.37 eV above the valence band. In this diagram, it was assumed that the lattice coupling of the nitrogen center in ZnS0.16O0.84 is similar to that calculated for the same center in ZnO, that is, ~0.4 eV; for a smaller coupling, the nitrogen level should be a little higher and is at ~0.77 eV above the valence band in the limiting case of no coupling. For intermediate coupling energy ~0.22 eV, the nitrogen level will be at 0.55 eV, which is aligned with that of ZnO. Several factors may impact the observed in-gap PL energies, such as residual stress and structural defect-states, that might cause some discrepancy between the theory and experiments. Study of nitrogen-doped ZnS films demonstrated that effective p-type conductivity can be readily attained, and a shallow nitrogen acceptor level about 0.19 eV above the valance band was suggested [35]. Thus, ZnS1𝑥O𝑥 may have potential as a material component in ZnO-based devices when p-type doping is required.

4. Conclusions

ZnS0.16O0.84, ZnS0.76O0.24, ZnO, and Mg0.3Zn0.7O nanocrystalline films were grown via a sputtering technique on a flexible substrate with the objective of achieving ZnO-based alloys with bandgaps spanning the visible to the UV. The bandgaps of the films were found to be 2.65, 3.21, 3.35, and 4.02 eV, respectively. The PL spectra of the Mg0.3Zn0.7O exhibit a band-edge peak at 3.95 eV, and one at 3.38 eV that is attributed to a Zn-rich MgZnO segregates that arise from the inherent low solubility limit of this alloy system. The PL intensity of the ZnS0.16O0.84 and ZnS0.76O0.24 films was found to be extremely week. Structural defects, arising from the highly mismatched alloy constituents, were discussed to be the nonradiative optical centers. Future study will investigate whether the ZnS1-xOx alloy system possesses an efficient PL. The ZnS0.16O0.84 was found to have an in-gap PL attributed to nitrogen centers, and a nitrogen energy level at the range ~0.37–0.77 eV relative to the valence-band was proposed.


This research was supported by the US Department of Energy, Office of Basic Energy Science, Division of Materials Science and Engineering under Award DE-FG02-07ER46386.


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