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Journal of Nanomaterials
Volume 2013 (2013), Article ID 139768, 6 pages
Research Article

Fabrication and Corrosion Resistance of Superhydrophobic Hydroxide Zinc Carbonate Film on Aluminum Substrates

1Institute of Powder Metallurgy, Central South University, Hunan, Changsha 410083, China
2Department of Materials Science and Engineering, Central South University of Forestry and Technology, Hunan, Changsha 410004, China

Received 29 December 2012; Accepted 24 January 2013

Academic Editor: Li Li

Copyright © 2013 Jin Liang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Superhydrophobic hydroxide zinc carbonate (HZC) films were fabricated on aluminum substrate through a convenient in situ deposition process. Firstly, HZC films with different morphologies were deposited on aluminum substrates through immersing the aluminum substrates perpendicularly into aqueous solution containing zinc nitrate hexahydrate and urea. Secondly, the films were then modified with fluoroalkylsilane (FAS: CH3(CF2)6(CH2)3Si(OCH3)3) molecules by immersing in absolute ethanol solution containing FAS. The morphologies, hydrophobicity, chemical compositions, and bonding states of the films were analyzed by scanning electron microscopy (SEM), water contact angle measurement (CA), Fourier transform infrared spectrometer (FTIR), and X-ray photoelectron spectroscopy (XPS), respectively. It was shown by surface morphological observation that HZC films displayed different microstructures such as microporous structure, rose petal-like structure, block-shaped structure, and pinecone-like structure by altering the deposition condition. A highest water contact angle of 156.2° was obtained after FAS modification. Moreover, the corrosion resistance of the superhydrophobic surface on aluminum substrate was investigated using electrochemical impedance spectroscopy (EIS) measurements. The EIS measurements’ results revealed that the superhydrophobic surface considerably improved the corrosion resistance of aluminum.