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Journal of Nanomaterials
Volume 2014, Article ID 369034, 12 pages
Research Article

The Morphostructural, Compositional, and Electrochemical Characterization of Electrodeposited Nanolayers on a New Ti-15Ta-5Zr Alloy

Romanian Academy, Institute of Physical Chemistry “Ilie Murgulescu”, Splaiul Independentei 202, 060021 Bucharest, Romania

Received 7 February 2014; Accepted 21 March 2014; Published 30 April 2014

Academic Editor: Fathallah Karimzadeh

Copyright © 2014 Cora Vasilescu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A porous, homogeneous, phosphorous-enriched oxide nanolayer was realized on the new Ti-15Ta-5Zr alloy surface by the anodic galvanostatic electrodeposition in phosphoric acid solution. This nanolayer contains TiO2, ZrO2 oxides, tantalum suboxides, and ions incorporated in the time of the electrodeposition process and has a thickness of 15.5 nm (X-ray photoelectron spectroscopy data). Atomic force microscopy determined a homogeneous roughness. Scanning electron microscopy evinced a porous microstructure that can stimulate the growth of the bone tissue into pores. The presence of the anions promotes the electrostatic bonds between the nanolayer and different species from the biofluid, namely, osteoinduction. The anodic oxidation nanolayer improved all electrochemical and corrosion parameters conferring superior protection to the substrate by its higher resistance to the ion migration. Impedance spectra showed that the electrodeposited nanolayer is formed by an inner, dense, barrier layer and an outer porous layer. The nanolayer thickened in time, namely, is bioactive. The oxidized nanolayer is able to protect the alloy from ion release, to assure long-term corrosion resistance, to minimize adverse reactions, to increase alloy bioactivity, to stimulate cell growth, and to favor osseointegration.