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Journal of Nanomaterials
Volume 2014, Article ID 561920, 9 pages
Research Article

Bromate Removal from Water Using Doped Iron Nanoparticles on Multiwalled Carbon Nanotubes (CNTS)

1Chemistry Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
2Chemical Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

Received 15 September 2013; Revised 28 November 2013; Accepted 17 December 2013; Published 6 February 2014

Academic Editor: Godwin Ayoko

Copyright © 2014 Aasem Zeino et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The raw carbon nanotubes (CNTs) were prepared by the floating catalyst chemical vapor deposition method. The raw carbon nanotubes were functionalized, impregnated with iron nanoparticles, and characterized using high resolution transmission electron microscopy (HRTEM), scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), Differential Scanning Calorimetry (DSC), and thermogravimetric analysis (TGA). The three types of these multiwalled carbon nanotubes were applied as adsorbents for the removal of bromate from drinking water. The effects of the pH, the concentration of anion, the adsorbent dose, the contact time, and the coanions on the adsorption process have been investigated. The results concluded that the highest adsorption capacities were 0.3460 and 0.3220 mg/g through using CNTs-Fe and raw CNTs, respectively, at the same conditions. The results showed that the CNTs-Fe gives higher adsorption capacity compared with the raw CNTs and the functionalized CNTs. The presence of nitrate ( ) in the solution decreases the adsorption capacity of all CNTs compared with chloride ( ) associated with pH adjustment caused by nitric acid or hydrochloric acid, respectively. However, the adsorption of all MWNCTs types increases as the pH of solution decreases.