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Journal of Nanomaterials
Volume 2014 (2014), Article ID 682985, 10 pages
http://dx.doi.org/10.1155/2014/682985
Research Article

Experimental Investigation of the Coprecipitation Method: An Approach to Obtain Magnetite and Maghemite Nanoparticles with Improved Properties

1Department of Chemistry, Foundation Federal University of Rondonia, 76801-974 Porto Velho, RO, Brazil
2Institute of Biological Sciences, University of Brasilia, 70910-900 Brasilia, DF, Brazil

Received 14 August 2013; Revised 14 January 2014; Accepted 14 January 2014; Published 19 May 2014

Academic Editor: William W. Yu

Copyright © 2014 Wilson Sacchi Peternele et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. E. J. W. Verwey and E. L. Heilmann, “Physical properties and cation arrangement of oxides with spinel structures I. Cation arrangement in spinels,” The Journal of Chemical Physics, vol. 15, no. 4, pp. 174–180, 1947. View at Google Scholar · View at Scopus
  2. R. D. Waldron, “Infrared spectra of ferrites,” Physical Review, vol. 99, no. 6, pp. 1727–1735, 1955. View at Publisher · View at Google Scholar · View at Scopus
  3. G. A. Ferguson and M. Hass, “Magnetic structure and vacancy distribution in γFe2O3 by neutron diffraction,” Physical Review, vol. 112, pp. 1130–1113, 1958. View at Google Scholar
  4. J. M. Perez, F. J. Simeone, Y. Saeki, L. Josephson, and R. Weissleder, “Viral-induced self-assembly of magnetic nanoparticles allows the detection of viral particles in biological media,” Journal of the American Chemical Society, vol. 125, no. 34, pp. 10192–10193, 2003. View at Publisher · View at Google Scholar · View at Scopus
  5. A. I. Anton, “Measurements of turbulence suppression due to a transverse magnetic field applied on a ferrofluid motion,” Journal of Magnetism and Magnetic Materials, vol. 85, no. 1–3, pp. 137–140, 1990. View at Google Scholar · View at Scopus
  6. P. Taylor, “Ostwald ripening in emulsions,” Advances in Colloid and Interface Science, vol. 75, no. 2, pp. 107–163, 1998. View at Google Scholar · View at Scopus
  7. E. H. Kim, S. H. Lee, K. B. Kwak, and K. B. Kim, “Synthesis of ferroluid with magnetic nanoparticles by sonochemical method for MRI contrast agent,” Journal of Magnetism and Magnetic Materials, vol. 289, pp. 328–330, 2005. View at Google Scholar
  8. A. Jordan, R. Scholz, P. Wust et al., “Endocytosis of dextran and silan-coated magnetite nanoparticles and the effect of intracellular hyperthermia on human mammary carcinoma cells in vitro,” Journal of Magnetism and Magnetic Materials, vol. 194, no. 1, pp. 185–196, 1999. View at Publisher · View at Google Scholar · View at Scopus
  9. D. C. F. Chan, D. B. Kirpotin, and P. A. Bunn Jr., “Synthesis and evaluation of colloidal magnetic iron oxides for the site-specific radiofrequency-induced hyperthermia of cancer,” Journal of Magnetism and Magnetic Materials, vol. 122, no. 1–3, pp. 374–378, 1993. View at Google Scholar · View at Scopus
  10. D. L. Leslie-Pelecky and R. D. Rieke, “Magnetic properties of nanostructured materials,” Chemistry of Materials, vol. 8, no. 8, pp. 1770–1783, 1996. View at Google Scholar · View at Scopus
  11. E. M. Moreno, M. Zayat, M. P. Morales, C. J. Serna, A. Roig, and D. Levy, “Preparation of narrow size distribution superparamagnetic γ-Fe2O3 nanoparticles in a sol-gel transparent SiO2 matrix,” Langmuir, vol. 18, no. 12, pp. 4972–4978, 2002. View at Publisher · View at Google Scholar · View at Scopus
  12. J. Lee, T. Isobe, and M. Senna, “Preparation of ultrafine Fe3O4 particles by precipitation in the presence of PVA at high pH,” Journal of Colloid and Interface Science, vol. 177, no. 2, pp. 490–494, 1996. View at Publisher · View at Google Scholar · View at Scopus
  13. Y. S. Kang, S. Risbud, J. P. Tabolt, and P. Stroeve, “Synthesis and characterization of nanometer size Fe3O4 and γFe2O3 particles,” Chemistry of Materials, vol. 8, pp. 2209–2211, 1996. View at Google Scholar
  14. C. Hammond, The Basics of Cristallography and Diffraction, Oxford University Press, New York, NY, USA, 1997.
  15. B. D. Cullity, Introduction to Magnetic Materials, Addison-Wesley, New York, NY, USA, 1972.
  16. A. Bee, R. Massart, and S. Neveu, “Synthesis of very fine maghemite particles,” Journal of Magnetism and Magnetic Materials, vol. 149, no. 1-2, pp. 6–9, 1995. View at Google Scholar · View at Scopus
  17. G. A. Van Ewijk, G. J. Vroege, and A. P. Philipse, “Convenient preparation methods for magnetic colloids,” Journal of Magnetism and Magnetic Materials, vol. 201, no. 1–3, pp. 31–33, 1999. View at Google Scholar · View at Scopus
  18. N. Anton, P. Gayet, J.-P. Benoit, and P. Saulnier, “Nano-emulsions and nanocapsules by the PIT method: an investigation on the role of the temperature cycling on the emulsion phase inversion,” International Journal of Pharmaceutics, vol. 344, no. 1-2, pp. 44–52, 2007. View at Publisher · View at Google Scholar · View at Scopus
  19. P. Lindner and T. Zemb, Neutrons, X-Rays and Light: Scattering Methods Applied to Soft Condensed Matter, Elsevier, Amsterdam, The Netherlands, 2002.
  20. P. N. Pusey and W. van Megen, “Dynamic light scattering by non-ergodic media,” Physica A, vol. 157, no. 2, pp. 705–741, 1989. View at Google Scholar · View at Scopus
  21. P. Sandkühler, J. Sefcik, and M. Morbidelli, “Kinetics of aggregation and gel formation in concentrated polystyrene colloids,” The Journal of Physical Chemistry B, vol. 108, pp. 20105–20121, 2004. View at Google Scholar
  22. L. Vayssieres, “On the thermodynamic stability of metal oxide nanoparticles in aqueous solutions,” International Journal of Nanotechnology, vol. 2, no. 4, pp. 411–439, 2005. View at Google Scholar · View at Scopus
  23. G. Gnanaprakas, J. Philip, T. Jayakumar, and B. Raj, “Effect of digestion time and alkali addition rate on physical properties of magnetite nanoparticles,” Journal of Physical Chemistry B, vol. 111, no. 28, pp. 7978–7986, 2007. View at Publisher · View at Google Scholar · View at Scopus
  24. G. Gnanaprakas, S. Mahadevan, T. Jayakumar, P. Kalyanasundaram, J. Philip, and B. Raj, “Effect of initial pH and temperature of iron salt solutions on formation of magnetite nanoparticles,” Materials Chemistry and Physics, vol. 103, no. 1, pp. 168–175, 2007. View at Publisher · View at Google Scholar · View at Scopus
  25. R. M. Cornell and U. Schertmann, Oxides in the Laboratory: Preparation and Characterization, Wiley-VCH, Weinheim, Germany, 1991.
  26. A. L. Patterson, “The Scherrer formula for X-ray particle size determination,” Physical Review, vol. 56, no. 10, pp. 978–982, 1939. View at Publisher · View at Google Scholar · View at Scopus
  27. G. H. Woehrle, J. E. Hutchison, S. Özkar, and R. G. Finke, “Analysis of nanoparticle transmission electron microscopy data using a public- domain image-processing program, Image,” Turkish Journal of Chemistry, vol. 30, no. 1, pp. 1–13, 2006. View at Google Scholar · View at Scopus
  28. T. Sugimoto, “Preparation of monodispersed colloidal particles,” Advances in Colloid and Interface Science, vol. 28, pp. 65–108, 1987. View at Google Scholar · View at Scopus
  29. Y.-K. Sun, M. Ma, Y. Zhang, and N. Gu, “Synthesis of nanometer-size maghemite particles from magnetite,” Colloids and Surfaces A, vol. 245, no. 1–3, pp. 15–19, 2004. View at Publisher · View at Google Scholar · View at Scopus
  30. B. D. Cullity and C. D. Graham, Introduction to Magnetic Materials, Addison-Wesley, Reading, Mass, USA, 1972.
  31. B. D. Cullity, Elements of X-ray Diffraction, Prentice Hall, Upper Saddle River, NJ, USA, 1967.
  32. T. Neuberger, B. Schöpf, H. Hofmann, M. Hofmann, and B. von Rechenberg, “Superparamagnetic nanoparticles for biomedical applications: possibilities and limitations of a new drug delivery system,” Journal of Magnetism and Magnetic Materials, vol. 293, no. 1, pp. 483–496, 2005. View at Publisher · View at Google Scholar · View at Scopus
  33. R. N. Panda, N. S. Gajbhiye, and G. Balaji, “Magnetic properties of interacting single domain Fe3O4 particles,” Journal of Alloys and Compounds, vol. 326, no. 1-2, pp. 50–53, 2001. View at Publisher · View at Google Scholar · View at Scopus
  34. G. F. Goya, T. S. Berquó, F. C. Fonseca, and M. P. Morales, “Static and dynamic magnetic properties of spherical magnetite nanoparticles,” Journal of Applied Physics, vol. 94, no. 5, pp. 3520–3528, 2003. View at Publisher · View at Google Scholar · View at Scopus
  35. J. Lee, T. Isobe, and M. Senna, “Magnetic properties of ultrafine magnetite particles and their slurries prepared via in-situ precipitation,” Colloids and Surfaces A, vol. 109, pp. 121–127, 1996. View at Publisher · View at Google Scholar · View at Scopus
  36. D. H. Han, J. P. Wang, and H. L. Luo, “Crystallite size effect on saturation magnetization of fine ferrimagnetic particles,” Journal of Magnetism and Magnetic Materials, vol. 136, no. 1-2, pp. 176–182, 1994. View at Google Scholar · View at Scopus
  37. D. H. Lindsley, “Experimental studies of oxides minerals,” in Oxide Minerals: Petrologic and Magnetic Significance, D. H. Lindsley, Ed., vol. 25 of Reviews in Mineralogy, pp. 69–100, Mineralogical Society of America, 1991. View at Google Scholar