Review Article

From Plastic to Silicone: The Novelties in Porous Polymer Fabrications

Table 2

Advantages and disadvantages of main types of fabrication techniques [33].

Fabrication methodAdvantagesDisadvantages

Solvent casting/particulate leachingControl over porosity, pore size, and crystallinityLimited mechanical property, residual solvents, and porogen material
Porogen leachingControlled over porosity and pore geometryInadequate pore size and pore interconnectivity
Gas foamingFree of harsh organic solvents, control over porosity and pore sizeLimited mechanical property, inadequate pore interconnectivity
Phase separationNo decrease in the activity of the moleculeDifficult to control precisely morphology
Freeze-dryingHigh temperature and separate leaching step not requiredSmall pore size and long processing time