Research Article

Microstructures of Reduced Graphene Oxide/Sulfur Nanocomposites and Their Impacts on Lithium Storage Performances

Table 1

Comparison of a set of reported studies on graphene/sulfur and graphene oxide/sulfur composites with their corresponding electrochemical performances.

CompositeS content in G/S powder (wt)Electrolyte1st discharge capacity (mAh g−1)Capacity at the th cycle (mAh g−1)Source

TG – a-S
ball milling
73 wt%
82 wt%
1 M LiTFSI/DOL/DME [email protected] C 
835@1 C
615@100th
530@100th
[14]

rGO + a-S
melting infiltration
22 wt%1 M LiPF6/EC/DMC[email protected] A g−1 670@80th[15]

TG + c-S
melting infiltrating
20 wt%
40 wt%
60 wt%
80 wt%
1 M LiTFSI/DOL/DME [email protected] A g−1
[email protected] A g−1
[email protected] A g−1
[email protected] A g−1
602@70th
728@70th
880@70th
449@70th
[16]

TG + a-S
melting infiltration
67 wt%N/A[email protected] A g−1421@100th [17]

rGO + S
melting infiltration
66.7 wt%1 M LiTFSI/DOL/DME [email protected] C435@60th[18]

TG + a-S
rGO coated
63 wt%N/A[email protected] A g−1928@100th [17]

mGO + S + PEG
GO/CB wrapped
70 wt% 
(34–46%)
1 M LiTFSI/DOL/DME [email protected] C520@100th[19]

pGNS + a-S
melting infiltration
22 wt%1 M LiTFSI/PEGDME[email protected] A g−1539@40th[20]

pGNS + S
melting infiltration
66.7 wt%1 M LiTFSI/DOL/DME [email protected] C1007@60th[18]

rGO + c-S 
oxidation
87 wt%1 M LiTFSI/DOL/
TEGDME
[email protected] A g−1492@50th[21]

rGO + c-S
Na2S + NaSO3
75.2 wt%1 M LiCF3SO3 + 0.2 wt% LiNO3/
DME/DOL
[email protected] A g−1930@50th[22]

rGO + S
Na2SO3 + Na2S + rGO
63.6 wt%
50.9%
1 M LiTFSI/DOL/DME[email protected] A g−1804@80th[23]

p graphene + c-S
Na2S2O3 + H2SO4
83.3 wt%
66.6%
1 M LiTFSI + 0.1 M LiNO3/
EGDME/DOXL
[email protected] C810@50th[24]

TG + c-S
S dissolve in CS2
71.8 wt%1 M LiTFSI/DOL/DME [email protected] C490@50th[25]

rGO + S
chemical microemulsion
66 wt%1 M LiTFSI/PYR14TFSI/
PEGDME
[email protected] A g−1735@50th[26]

Nafion coated TG + c-S
S dissolve in CS2
71.8 wt%1 M LiTFSI/DOL/DME [email protected] C750@50th[25]

rGO + S
wrapped, S in CS2
65 wt%
(52%)
1 M LiTFSI/DOL/DME 725@1 C622@60th[27]

rGO: reduced graphene oxide; TG: thermally exfoliated graphene; pGNS: porous (activated) graphene nanosheets.
a-S: amorphous sulfur; c-S: crystalline sulfur.
In most literatures, the electrode for electrochemical characterizations contains 80 wt% GO/S, 10 wt% carbon additive, and 10 wt% binder.