Research Article
A Comparative Study of Solvothermal and Sol-Gel-Derived Nanocrystalline Alumina Catalysts for Ethanol Dehydration
Table 3
Summary of catalysts for ethylene synthesis and their catalytic ability.
| Catalyst | Surface area (m2/g) | Amount of catalyst | Space velocity (h−1) | Reaction temperature (°C) | Ethylene yield (%) | References |
| Al-SV | 215 | 0.05 g | WHSV 8.4 | 250–350 | 53–100 | This work | H-ZSM-5 (Si/Al = 28) | 425 | 0.2 g | WHSV 0.422 | 200 | 9–13 | [1] | TiO2/γ-Al2O3 | 187 | 1.15 mL | LHSV 26–104 | 360–550 | 91–99 | [5] | Mn-SAPO-34 | 473 | 2.0 g | WHSV 2.0 | 340 | 97.8 | [26] | H3PO4·12WO3·H2O | 104 | 10 g | WHSV 1.0 | 250 | 68 | [27] | Tungstophosphoric acid/MCM-41 | 183 | 0.2 g | WHSV 2.9 | 300 | 97.9 | [28] | P/H-ZSM-5 (Si/Al = 12.18) | 160 | 1.5 g | WHSV 3.0 | 280–440 | 31–100 | [29] | Ag3PW12O40·3H2O | n.a. | 0.5 mL | GHSV 6000 | 220 | 99.2 | [30] | Fe2O3 | 40 | 10 mL | LHSV 2.85 | 500 | 63.4 | [31] | Commercial Al2O3 | 190 | 3.0 mL | LHSV 3.0 | 450 | 78.1 | [32] | H-ZSM-5 (Si/Al = 25) | 295 | 3.0 mL | LHSV 3.0 | 450 | 93.6 | [32] |
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n.a. = not applicable.
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