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Journal of Nanomaterials
Volume 2015 (2015), Article ID 745217, 10 pages
Research Article

Development of Castor Oil Based Poly(urethane-esteramide)/TiO2 Nanocomposites as Anticorrosive and Antimicrobial Coatings

1Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
2Research Center, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia

Received 2 September 2014; Accepted 15 December 2014

Academic Editor: Antonios Kelarakis

Copyright © 2015 Mohammed Rafi Shaik et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Castor oil based polyesteramide (CPEA) resin has been successfully synthesized by the condensation polymerization of N-N-bis (2-hydroxyethyl) castor oil fatty amide (HECA) with terephthalic acid and further modified with different percentages of 7, 9, 11, and 13 wt.% of toluene-2,4-diisocyanate (TDI) to obtain poly(urethane-esteramide) (UCPEA), via addition polymerization. TiO2 (0.1, 0.2, 0.3, 0.4, and 0.5 wt%) nanoparticles were dispersed in UCPEA resin. The structural elucidation of HECA, CPEA, and UCPEA has been carried out using FT-IR, 1H-NMR, and 13C-NMR spectroscopic techniques while physicochemical and physicomechanical properties were investigated by standard methods. Thermal stability and molecular weight of UCPEA have been assessed by thermogravimetric analysis (TGA) and gel permeation chromatography (GPC), respectively. Furthermore, the corrosion behavior of UCPEA coatings on mild steel has been investigated by potentiodynamic polarization measurements in different corrosive environments (3.5 wt% HCl, 5 wt% NaCl, 3.5 wt% NaOH, and tap water) at room temperature and surface analysis by scanning electron microscope (SEM) and energy dispersive X-ray (EDX). The antibacterial activities of the UCPEA were tested against bacteria and fungi by agar disc diffusion method. The results of this study have revealed that UCPEA nanocomposite coatings exhibit good physicomechanical, anticorrosion and antimicrobial properties, which can be safely used up to 200°C.