Degradation Kinetics of Photoelectrocatalysis on Landfill Leachate Using Codoped TiO2/Ti Photoelectrodes
Table 2
Effect of various operating conditions on initial rate by photoelectrocatalysis process.
Number
Initial pH
Potential bias
COD0/mgL−1
/K
Polynomial regression constant
Initial /mg·(Lm)−1
equation(1)
-1
2
20
4378
303
1.009
−0.018
0.978
0.018
() (2) = 0.978
-2
4
20
4378
303
0.987
−0.014
0.931
0.014
-3
6
20
4378
303
0.997
−0.009
0.986
0.009
-4
8
20
4378
303
0.995
−0.006
0.948
0.006
-5
10
20
4378
303
0.994
−0.005
0.972
0.005
-1
7
5
4378
303
1.004
−0.004
0.986
0.004
()
= 0.998
-2
7
10
4378
303
1.006
−0.003
0.976
0.003
-3
7
15
4378
303
0.993
−0.003
0.976
0.003
-4
7
18
4378
303
1.005
−0.004
0.972
0.004
-5
7
20
4378
303
0.986
−0.019
0.96
0.019
-6
7
23
4378
303
0.982
−0.021
0.92
0.021
-1
7
20
4378
303
2189.8
−17.6
0.997
17.6
()
= 0.972
-2
7
20
2189
303
1470.7
−16.7
0.963
16.7
-3
7
20
1459
303
1112.8
−4.8
0.947
4.8
-4
7
20
1059
303
874.8
−2.5
0.991
2.5
-5
7
20
876
303
725.8
−5.0
0.990
5.0
-1
7
20
4378
283
1.004
0.994
() (3) = 0.967
-2
7
20
4378
293
0.994
−0.001
0.99
0.001
-3
7
20
4378
303
0.984
−0.018
0.949
0.018
-4
7
20
4378
313
0.994
−0.008
0.994
0.008
-5
7
20
4378
323
0.999
−0.010
0.98
0.010
() represents pH, potential bias, and initial COD concentration, respectively; () this equation only represents polynomial fitting under pH range from 2 to 10; () this equation represents / equation.