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Journal of Nanomaterials
Volume 2015 (2015), Article ID 963173, 8 pages
http://dx.doi.org/10.1155/2015/963173
Research Article

Highly Durable Direct Methanol Fuel Cell with Double-Layered Catalyst Cathode

1School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
2Key Laboratory of Chemical Engineering Process and Technology for High efficiency Conversion, College of Heilongjiang Province, Harbin 150080, China
3School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China

Received 14 June 2015; Revised 23 June 2015; Accepted 29 June 2015

Academic Editor: Jun Chen

Copyright © 2015 Jing Liu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. S. Sharma and B. G. Pollet, “Support materials for PEMFC and DMFC electrocatalysts—a review,” Journal of Power Sources, vol. 208, pp. 96–119, 2012. View at Publisher · View at Google Scholar · View at Scopus
  2. S. Basri, S. K. Kamarudin, W. R. W. Daud, and Z. Yaakub, “Nanocatalyst for direct methanol fuel cell (DMFC),” International Journal of Hydrogen Energy, vol. 35, no. 15, pp. 7957–7970, 2010. View at Publisher · View at Google Scholar · View at Scopus
  3. E. Antolini, T. Lopes, and E. R. Gonzalez, “An overview of platinum-based catalysts as methanol-resistant oxygen reduction materials for direct methanol fuel cells,” Journal of Alloys and Compounds, vol. 461, no. 1-2, pp. 253–262, 2008. View at Publisher · View at Google Scholar · View at Scopus
  4. X. Zhao, M. Yin, L. Ma et al., “Recent advances in catalysts for direct methanol fuel cells,” Energy and Environmental Science, vol. 4, no. 8, pp. 2736–2753, 2011. View at Publisher · View at Google Scholar · View at Scopus
  5. V. Neburchilov, J. Martin, H. Wang, and J. Zhang, “A review of polymer electrolyte membranes for direct methanol fuel cells,” Journal of Power Sources, vol. 169, no. 2, pp. 221–238, 2007. View at Publisher · View at Google Scholar · View at Scopus
  6. A. Mehmood, M. G. An, and H. Y. Ha, “Physical degradation of cathode catalyst layer: a major contributor to accelerated water flooding in long-term operation of DMFCs,” Applied Energy, vol. 129, pp. 346–353, 2014. View at Publisher · View at Google Scholar
  7. J.-H. Kim, M.-J. Yang, and J.-Y. Park, “Improvement on performance and efficiency of direct methanol fuel cells using hydrocarbon-based membrane electrode assembly,” Applied Energy, vol. 115, pp. 95–102, 2014. View at Publisher · View at Google Scholar
  8. C. C. Ke, X. J. Li, S. G. Qu, Z. G. Shao, and B. L. Yi, “Preparation and properties of Nafion/SiO2 composite membrane derived via in situ sol-gel reaction: size controlling and size effects of SiO2 nano-particles,” Polymers for Advanced Technologies, vol. 23, no. 1, pp. 92–98, 2012. View at Publisher · View at Google Scholar
  9. Y.-C. Park, D.-H. Kim, S. Lim, S.-K. Kim, D.-H. Peck, and D.-H. Jung, “Design of a MEA with multi-layer electrodes for high concentration methanol DMFCs,” International Journal of Hydrogen Energy, vol. 37, no. 5, pp. 4717–4727, 2012. View at Publisher · View at Google Scholar · View at Scopus
  10. S. Rousseau, C. Coutanceau, C. Lamy, and J.-M. Léger, “Direct ethanol fuel cell (DEFC): electrical performances and reaction products distribution under operating conditions with different platinum-based anodes,” Journal of Power Sources, vol. 158, no. 1, pp. 18–24, 2006. View at Publisher · View at Google Scholar · View at Scopus
  11. A. Kianimanesh, Q. Yang, S. S. Park, D. Xue, and T. Freiheit, “Model for the degradation performance of a single-cell direct methanol fuel cell under varying operational conditions,” Fuel Cells, vol. 13, no. 6, pp. 1005–1017, 2013. View at Publisher · View at Google Scholar · View at Scopus
  12. M. K. Debe, “Electrocatalyst approaches and challenges for automotive fuel cells,” Nature, vol. 486, no. 7401, pp. 43–51, 2012. View at Publisher · View at Google Scholar · View at Scopus
  13. L. Wang, S. G. Advani, and A. K. Prasad, “Degradation reduction of polymer electrolyte membranes using CeO2 as a free-radical scavenger in catalyst layer,” Electrochimica Acta, vol. 109, pp. 775–780, 2013. View at Publisher · View at Google Scholar · View at Scopus
  14. Z. Wang, H. Tang, H. Zhang et al., “Synthesis of Nafion/CeO2 hybrid for chemically durable proton exchange membrane of fuel cell,” Journal of Membrane Science, vol. 421-422, pp. 201–210, 2012. View at Publisher · View at Google Scholar · View at Scopus
  15. V. Prabhakaran, C. G. Arges, and V. Ramani, “Investigation of polymer electrolyte membrane chemical degradation and degradation mitigation using in situ fluorescence spectroscopy,” Proceedings of the National Academy of Sciences of the United States of America, vol. 109, no. 4, pp. 1029–1034, 2012. View at Publisher · View at Google Scholar
  16. H. Hori, M. Murayama, T. Sano, and S. Kutsuna, “Decomposition of perfluorinated ion-exchange membrane to fluoride ions using zerovalent metals in subcritical water,” Industrial & Engineering Chemistry Research, vol. 49, no. 2, pp. 464–471, 2010. View at Publisher · View at Google Scholar
  17. P. X. Huang, F. Wu, B. L. Zhu et al., “CeO2 nanorods and gold nanocrystals supported on CeO2 nanorods as catalyst,” The Journal of Physical Chemistry B, vol. 109, no. 41, pp. 19169–19174, 2005. View at Publisher · View at Google Scholar
  18. S. Babu, A. Velez, K. Wozniak, J. Szydlowska, and S. Seal, “Electron paramagnetic study on radical scavenging properties of ceria nanoparticles,” Chemical Physics Letters, vol. 442, no. 4–6, pp. 405–408, 2007. View at Publisher · View at Google Scholar · View at Scopus
  19. D. Schubert, R. Dargusch, J. Raitano, and S.-W. Chan, “Cerium and yttrium oxide nanoparticles are neuroprotective,” Biochemical and Biophysical Research Communications, vol. 342, no. 1, pp. 86–91, 2006. View at Publisher · View at Google Scholar · View at Scopus
  20. P. Trogadas, J. Parrondo, and V. Ramani, “CeO2 surface oxygen vacancy concentration governs in situ free radical scavenging efficacy in polymer electrolytes,” ACS Applied Materials and Interfaces, vol. 4, no. 10, pp. 5098–5102, 2012. View at Publisher · View at Google Scholar · View at Scopus
  21. S. Xiao, H. Zhang, C. Bi et al., “Membrane degradation mitigation using zirconia as a hydrogen peroxide decomposition catalyst,” Journal of Power Sources, vol. 195, no. 24, pp. 8000–8005, 2010. View at Publisher · View at Google Scholar · View at Scopus
  22. Y. Li, W. Chen, Q. Xu, J. Zhou, Y. Wang, and H. Sun, “Piezoelectric and dielectric properties of CeO2-doped Bi0.5Na0.44K0.06TiO3 lead-free ceramics,” Ceramics International, vol. 33, pp. 95–99, 2007. View at Publisher · View at Google Scholar
  23. L. Wang, S. G. Advani, and A. K. Prasad, “Self-hydrating Pt/CeO2-nafion composite membrane for improved durability and performance,” ECS Electrochemistry Letters, vol. 3, no. 5, pp. F30–F32, 2014. View at Publisher · View at Google Scholar
  24. A. M. Baker, L. Wang, W. B. Johnson, A. K. Prasad, and S. G. Advani, “Nafion membranes reinforced with ceria-coated multiwall carbon nanotubes for improved mechanical and chemical durability in polymer electrolyte membrane fuel cells,” Journal of Physical Chemistry C, vol. 118, no. 46, pp. 26796–26802, 2014. View at Publisher · View at Google Scholar · View at Scopus
  25. J. Parrondo, P. Trogadas, and V. Ramani, “Degradation mitigation in polymer electrolyte membranes using free radical scavengers,” ECS Transactions, vol. 16, no. 2, pp. 1725–1733, 2008. View at Google Scholar
  26. Y. Gu, C. Liu, Y. Li, X. Sui, K. Wang, and Z. Wang, “Ce0.8Sn0.2O2-δ–C composite as a co-catalytic support for Pt catalysts toward methanol electrooxidation,” Journal of Power Sources, vol. 265, pp. 335–344, 2014. View at Publisher · View at Google Scholar · View at Scopus
  27. D. M. Gu, Y. Y. Chu, Z. B. Wang, Z. Z. Jiang, G. P. Yin, and Y. Liu, “Methanol oxidation on Pt/CeO2–C electrocatalyst prepared by microwave-assisted ethylene glycol process,” Applied Catalysis B: Environmental, vol. 102, no. 1-2, pp. 9–18, 2011. View at Publisher · View at Google Scholar
  28. Z.-B. Wang, P.-J. Zuo, Y.-Y. Chu, Y.-Y. Shao, and G.-P. Yin, “Durability studies on performance degradation of Pt/C catalysts of proton exchange membrane fuel cell,” International Journal of Hydrogen Energy, vol. 34, no. 10, pp. 4387–4394, 2009. View at Publisher · View at Google Scholar · View at Scopus
  29. L.-H. Xing, G.-P. Yin, Z.-B. Wang, S. Zhang, Y.-Z. Gao, and C.-Y. Du, “Investigation on the durability of direct dimethyl ether fuel cell. Part I: anode degradation,” Journal of Power Sources, vol. 198, pp. 170–175, 2012. View at Publisher · View at Google Scholar · View at Scopus
  30. Z.-B. Wang, C.-R. Zhao, P.-F. Shi et al., “Effect of a carbon support containing large mesopores on the performance of a Pt−Ru−Ni/C catalyst for direct methanol fuel cells,” The Journal of Physical Chemistry C, vol. 114, no. 1, pp. 672–677, 2010. View at Publisher · View at Google Scholar
  31. F. D. Coms, H. Liu, and J. E. Owejan, “Mitigation of perfluorosulfonic acid membrane chemical degradation using cerium and manganese ions,” ECS Transactions, vol. 16, no. 2, pp. 1735–1747, 2008. View at Publisher · View at Google Scholar