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Journal of Nanomaterials
Volume 2016 (2016), Article ID 3502310, 8 pages
http://dx.doi.org/10.1155/2016/3502310
Research Article

Breath Figure-Assisted Fabrication of Nanostructured Coating on Silicon Surface and Evaluation of Its Antireflection Power

1CNR-Istituto per lo Studio delle Macromolecole (ISMAC), Via A. Corti 12, 20133 Milano, Italy
2Ricerca sul Sistema Energetico (RSE), Strada Torre della Razza, Località Le Mose, 29122 Piacenza, Italy

Received 29 December 2015; Revised 16 March 2016; Accepted 27 March 2016

Academic Editor: Shu Seki

Copyright © 2016 Francesco Galeotti et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. P. B. Clapham and M. C. Hutley, “Reduction of lens reflexion by the ‘moth eye’ principle,” Nature, vol. 244, no. 5414, pp. 281–282, 1973. View at Publisher · View at Google Scholar · View at Scopus
  2. Y.-A. Dai, H.-C. Chang, K.-Y. Lai et al., “Subwavelength Si nanowire arrays for self-cleaning antireflection coatings,” Journal of Materials Chemistry, vol. 20, no. 48, pp. 10924–10930, 2010. View at Publisher · View at Google Scholar · View at Scopus
  3. H. K. Raut, V. A. Ganesh, A. S. Nair, and S. Ramakrishna, “Anti-reflective coatings: a critical, in-depth review,” Energy & Environmental Science, vol. 4, no. 10, pp. 3779–3804, 2011. View at Publisher · View at Google Scholar · View at Scopus
  4. K. Sakakibara, J. P. Hill, and K. Ariga, “Thin-film-based nanoarchitectures for soft matter: controlled assemblies into two-dimensional worlds,” Small, vol. 7, no. 10, pp. 1288–1308, 2011. View at Publisher · View at Google Scholar · View at Scopus
  5. J. H. Zhang, Y. F. Li, X. M. Zhang, and B. Yang, “Colloidal self-assembly meets nanofabrication: from two-dimensional colloidal crystals to nanostructure arrays,” Advanced Materials, vol. 22, no. 38, pp. 4249–4269, 2010. View at Publisher · View at Google Scholar · View at Scopus
  6. G. M. Whitesides and B. Grzybowski, “Self-assembly at all scales,” Science, vol. 295, no. 5564, pp. 2418–2421, 2002. View at Publisher · View at Google Scholar · View at Scopus
  7. D. M. Sim, M.-J. Choi, Y. H. Hur et al., “Ultra-high optical transparency of robust, graded-index, and anti-fogging silica coating derived from si-containing block copolymers,” Advanced Optical Materials, vol. 1, no. 6, pp. 428–433, 2013. View at Publisher · View at Google Scholar · View at Scopus
  8. D. Gentili, G. Foschi, F. Valle, M. Cavallini, and F. Biscarini, “Applications of dewetting in micro and nanotechnology,” Chemical Society Reviews, vol. 41, no. 12, pp. 4430–4443, 2012. View at Publisher · View at Google Scholar · View at Scopus
  9. H. G. Yang, M. Su, K. Y. Li et al., “Preparation of patterned ultrathin polymer films,” Langmuir, vol. 30, no. 31, pp. 9436–9441, 2014. View at Publisher · View at Google Scholar · View at Scopus
  10. M. Pisco, F. Galeotti, G. Grisci, G. Quero, and A. Cusano, “Self-assembled periodic patterns on the optical fiber tip by microsphere arrays,” in Proceedings of the 24th International Conference on Optical Fibre Sensors, vol. 9634 of Proceedings of SPIE, Curitiba, Brazil, September 2015. View at Publisher · View at Google Scholar
  11. A. Muñoz-Bonilla, M. Fernández-García, and J. Rodríguez-Hernández, “Towards hierarchically ordered functional porous polymeric surfaces prepared by the breath figures approach,” Progress in Polymer Science, vol. 39, no. 3, pp. 510–554, 2014. View at Publisher · View at Google Scholar · View at Scopus
  12. F. Galeotti, V. Calabrese, M. Cavazzini et al., “Self-functionalizing polymer film surfaces assisted by specific polystyrene end-tagging,” Chemistry of Materials, vol. 22, no. 9, pp. 2764–2769, 2010. View at Publisher · View at Google Scholar · View at Scopus
  13. F. Galeotti, W. Mróz, G. Scavia, and C. Botta, “Microlens arrays for light extraction enhancement in organic light-emitting diodes: a facile approach,” Organic Electronics, vol. 14, no. 1, pp. 212–218, 2013. View at Publisher · View at Google Scholar · View at Scopus
  14. M. Hernández-Guerrero and M. H. Stenzel, “Honeycomb structured polymer films via breath figures,” Polymer Chemistry, vol. 3, no. 3, pp. 563–577, 2012. View at Publisher · View at Google Scholar · View at Scopus
  15. M. Pisco, F. Galeotti, G. Quero, A. Iadicicco, M. Giordano, and A. Cusano, “Miniaturized sensing probes based on metallic dielectric crystals self-assembled on optical fiber tips,” ACS Photonics, vol. 1, pp. 917–927, 2014. View at Google Scholar
  16. F. Galeotti, A. Andicsova, S. Yunus, and C. Botta, “Precise surface patterning of silk fibroin films by breath figures,” Soft Matter, vol. 8, no. 17, pp. 4815–4821, 2012. View at Publisher · View at Google Scholar · View at Scopus
  17. V. Vohra, A. Bolognesi, G. Calzaferri, and C. Botta, “Multilevel organization in hybrid thin films for optoelectronic applications,” Langmuir, vol. 25, no. 20, pp. 12019–12023, 2009. View at Publisher · View at Google Scholar · View at Scopus
  18. A. Böker, Y. Lin, K. Chiapperini et al., “Hierarchical nanoparticle assemblies formed by decorating breath figures,” Nature Materials, vol. 3, no. 5, pp. 302–306, 2004. View at Publisher · View at Google Scholar · View at Scopus
  19. L.-S. Wan, L.-W. Zhu, Y. Ou, and Z.-K. Xu, “Multiple interfaces in self-assembled breath figures,” Chemical Communications, vol. 50, no. 31, pp. 4024–4039, 2014. View at Publisher · View at Google Scholar · View at Scopus
  20. E. Ferrari, P. Fabbri, and F. Pilati, “Solvent and substrate contributions to the formation of breath figure patterns in polystyrene films,” Langmuir, vol. 27, no. 5, pp. 1874–1881, 2011. View at Publisher · View at Google Scholar · View at Scopus
  21. M. Du, P. Zhu, X. Yan, Y. Su, W. Song, and J. Li, “Honeycomb self-assembled peptide scaffolds by the breath figure method,” Chemistry—A European Journal, vol. 17, no. 15, pp. 4238–4245, 2011. View at Publisher · View at Google Scholar · View at Scopus
  22. H. L. Cong, J. L. Wang, B. Yu, and J. G. Tang, “Preparation of a highly permeable ordered porous microfiltration membrane of brominated poly(phenylene oxide) on an ice substrate by the breath figure method,” Soft Matter, vol. 8, no. 34, pp. 8835–8839, 2012. View at Publisher · View at Google Scholar · View at Scopus
  23. H. Bai, C. Du, A. Zhang, and L. Li, “Breath figure arrays: unconventional fabrications, functionalizations, and applications,” Angewandte Chemie—International Edition, vol. 52, no. 47, pp. 12240–12255, 2013. View at Publisher · View at Google Scholar · View at Scopus
  24. F. Trespidi, G. Timò, F. Galeotti, and M. Pasini, “PDMS antireflection nano-coating for glass substrates,” Microelectronic Engineering, vol. 126, pp. 13–18, 2014. View at Publisher · View at Google Scholar · View at Scopus
  25. F. Galeotti, F. Trespidi, G. Timò, and M. Pasini, “Broadband and crack-free antireflection coatings by self-assembled moth eye patterns,” ACS Applied Materials and Interfaces, vol. 6, no. 8, pp. 5827–5834, 2014. View at Publisher · View at Google Scholar · View at Scopus
  26. A. Bolognesi, F. Galeotti, J. Moreau et al., “Unsoluble ordered polymeric pattern by breath figure approach,” Journal of Materials Chemistry, vol. 20, no. 8, pp. 1483–1488, 2010. View at Publisher · View at Google Scholar · View at Scopus
  27. D. K. Cai, A. Neyer, R. Kuckuk, and H. M. Heise, “Optical absorption in transparent PDMS materials applied for multimode waveguides fabrication,” Optical Materials, vol. 30, no. 7, pp. 1157–1161, 2008. View at Publisher · View at Google Scholar · View at Scopus
  28. A. Perevedentsev, Y. Sonnefraud, C. R. Belton et al., “Dip-pen patterning of poly(9,9-dioctylfluorene) chain-conformation-based nano-photonic elements,” Nature Communications, vol. 6, article 5977, 2015. View at Publisher · View at Google Scholar · View at Scopus
  29. M. H. Stenzel, C. Barner-Kowollik, and T. P. Davis, “Formation of honeycomb-structured, porous films via breath figures with different polymer architectures,” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 44, no. 8, pp. 2363–2375, 2006. View at Publisher · View at Google Scholar · View at Scopus
  30. A. J. Zhang, H. Bai, and L. Li, “Breath figure: a nature-inspired preparation method for ordered porous films,” Chemical Reviews, vol. 115, no. 18, pp. 9801–9868, 2015. View at Publisher · View at Google Scholar · View at Scopus
  31. R. Daly, J. E. Sader, and J. J. Boland, “Taming self-organization dynamics to dramatically control porous architectures,” ACS Nano, vol. 10, no. 3, pp. 3087–3092, 2016. View at Publisher · View at Google Scholar
  32. E. Servoli, G. A. Ruffo, and C. Migliaresi, “Interplay of kinetics and interfacial interactions in breath figure templating—a phenomenological interpretation,” Polymer, vol. 51, no. 11, pp. 2337–2344, 2010. View at Publisher · View at Google Scholar · View at Scopus
  33. W. Madej, A. Budkowski, J. Raczkowska, and J. Rysz, “Breath figures in polymer and polymer blend films spin-coated in dry and humid ambience,” Langmuir, vol. 24, no. 7, pp. 3517–3524, 2008. View at Publisher · View at Google Scholar · View at Scopus
  34. F. Pilati, M. Montecchi, P. Fabbri et al., “Design of surface properties of PET films: effect of fluorinated block copolymers,” Journal of Colloid and Interface Science, vol. 315, no. 1, pp. 210–222, 2007. View at Publisher · View at Google Scholar · View at Scopus
  35. B. W. Lim and M. C. Suh, “Simple fabrication of a three-dimensional porous polymer film as a diffuser for organic light emitting diodes,” Nanoscale, vol. 6, no. 23, pp. 14446–14452, 2014. View at Publisher · View at Google Scholar · View at Scopus
  36. Y. Xia and G. M. Whitesides, “Soft lithography,” Angewandte Chemie—International Edition, vol. 37, no. 5, pp. 550–575, 1998. View at Publisher · View at Google Scholar · View at Scopus
  37. B. D. Gates, “Nanofabrication with molds & stamps,” Materials Today, vol. 8, no. 2, pp. 44–49, 2005. View at Publisher · View at Google Scholar · View at Scopus
  38. P. O. Morawska, Y. Wang, A. Ruseckas et al., “Side-chain influence on the mass density and refractive index of polyfluorenes and star-shaped oligofluorene truxenes,” Journal of Physical Chemistry C, vol. 119, no. 38, pp. 22102–22107, 2015. View at Publisher · View at Google Scholar · View at Scopus
  39. M. Campoy-Quiles, G. Heliotis, R. Xia et al., “Ellipsometric characterization of the optical constants of polyfluorene gain media,” Advanced Functional Materials, vol. 15, no. 6, pp. 925–933, 2005. View at Publisher · View at Google Scholar · View at Scopus
  40. T. Higashihara and M. Ueda, “Recent progress in high refractive index polymers,” Macromolecules, vol. 48, no. 7, pp. 1915–1929, 2015. View at Publisher · View at Google Scholar · View at Scopus
  41. M. Born and E. Wolf, Principles of Optics: Electromagnetic Theory of Propagation, Interference and Diffraction of Light, Cambridge University Press, 1999.
  42. R. Dong, J. Yan, H. Ma, Y. Fang, and J. Hao, “Dimensional architecture of ferrocenyl-based oligomer honeycomb-patterned films: from monolayer to multilayer,” Langmuir, vol. 27, no. 14, pp. 9052–9056, 2011. View at Publisher · View at Google Scholar · View at Scopus
  43. M. S. Park and J. K. Kim, “Broad-band antireflection coating at near-infrared wavelengths by a breath figure,” Langmuir, vol. 21, no. 24, pp. 11404–11408, 2005. View at Publisher · View at Google Scholar · View at Scopus
  44. L. A. Connal, P. A. Gurr, G. G. Qiao, and D. H. Solomon, “From well defined star-microgels to highly ordered honeycomb films,” Journal of Materials Chemistry, vol. 15, no. 12, pp. 1286–1292, 2005. View at Publisher · View at Google Scholar · View at Scopus