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Journal of Nanomaterials
Volume 2016, Article ID 5697672, 7 pages
Research Article

Facile Synthesis of High {001} Facets Dominated BiOCl Nanosheets and Their Selective Dye-Sensitized Photocatalytic Activity Induced by Visible Light

1Materials and Structural Department, Changjiang River Scientific Research Institute, Wuhan 430010, China
2Collaborative Innovation Center for Geo-Hazards and Eco-Environment in Three Gorges Area, Yichang 443002, China

Received 4 October 2015; Revised 16 December 2015; Accepted 20 December 2015

Academic Editor: Takuya Tsuzuki

Copyright © 2016 Da Zhang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Single-crystal BiOCl nanosheets, with high 001 facets exposed, were synthesized through a facile hydrolysis reaction under general atmospheric pressure, without adding any organic surfactant or agent. The thickness of the BiOCl nanosheets is about 20 nm, and the diameter is arranged from 200 to 400 nm. The structure of the BiOCl nanosheets was characterized by X-ray diffraction, energy disperse X-ray spectrum, transmission electron microscopy, and selective area electron diffraction. Moreover, three different dyes were used as model molecules to test the photocatalytic activity of BiOCl nanosheets under visible light. It was found that the BiOCl nanosheets possess selective photocatalytic behavior as their activity over RhB is much higher than that over MO or MB. Based on the analysis of the experimental results, the potential mechanism was discussed.