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Journal of Nanomaterials
Volume 2016 (2016), Article ID 5858906, 11 pages
Research Article

Preparation of Graphene/TiO2 Composite Nanomaterials and Its Photocatalytic Performance for the Degradation of 2,4-Dichlorophenoxyacetic Acid

School of Resources Environment and Chemical Engineering, Nanchang University, Nanchang 330031, China

Received 13 May 2016; Accepted 13 July 2016

Academic Editor: Xuping Sun

Copyright © 2016 Donggen Huang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The graphene (GR) was prepared by an improved electrochemical stripping method using a high-purity graphite rod as raw material and high temperature heat reduction in hydrogen atmosphere, and the graphene/TiO2 (GR/TiO2) composite nanomaterials were manufactured by the method of sol-gel and high temperature crystallization in hydrogen atmosphere using butyl titanate and electrolysis graphene as precursors. The physical and chemical properties of the composites had been characterized by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV-Vis spectrophotometer (UV-Vis), scanning electron microscopy (SEM), Transmission Electron Microscope (TEM),  and specific surface area (SSA) by BET method. The photocatalytic properties of GR/TiO2 composites nanomaterials in anoxic water were studied by using 2,4-dichlorophenoxyacetic acid (2,4-D) as probe. The results showed that graphite was well intercalated and peeled by a facile electrolysis method in different electric field environment; a well dispersed and rings structure of graphene was prepared by coupling ultrasound-assisted changing voltage electrochemical stripping technology. The as-prepared GR/TiO2 composites had good performance for the photocatalytic degradation of 2,4-D in anoxic water; the chlorines were removed from benzene ring; the middle products of dichlorophenol, chlorophenol, phloroglucinol, and so forth were produced from the photocatalytic redox reaction of 2,4-D in anoxic water; parts of 2,4-D were decomposed completely, and CO2 and H2O were produced.