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Journal of Nanomaterials
Volume 2016 (2016), Article ID 7510563, 7 pages
Research Article

UV Treatment of the Stabilizing Shell for Improving the Photostability of Silver Nanoparticles

Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy

Received 21 July 2016; Accepted 9 August 2016

Academic Editor: Giovanni Bongiovanni

Copyright © 2016 Silvia Rinaldi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Silver nanoparticles or nanoclusters are quite sensitive to light exposure. In particular, irradiation in the localized surface plasmon resonance (LSPR) region brings about a drastic modification of their optical properties due to growth and reshaping of the nanoparticles. In order to obtain luminescent colloids, small silver colloidal nanoparticles were prepared in chloroform using vinylpyrrolidone oligomers as capping agent and their luminescence properties were used to control their stability upon prolonged exposure to visible light. The polymeric shell around the metal clusters was hardened through photo-cross-linking by UV light. This process did not alter the morphology and the optical properties of the nanoparticles but greatly improved the particle photostability as confirmed also by confocal laser scanning microscopy measurements. The data clearly show that UV curing of the stabilizing layer could be a simple postsynthetic procedure to obtain materials with stable properties.