Morphological Study and Dielectric Behavior of Nonisothermally Crystallized Poly(ethylene naphthalate) Nanocomposites as a Function of Graphene Content

Espinoza-Martinez, Adriana B.; Avalos-Belmontes, Felipe; Valle, Luis F. Ramos-de; Espinoza-Martinez, Pedro A.; Avila-Orta, Carlos A.; Soriano-Corral, Florentino; Mata-Padilla, José M.; Tellez-Rosas, María M.

doi:https://doi.org/10.1155/2016/9846102

Journal of Nanomaterials

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Abstract Introduction Experimental Results and Discussion Conclusions Acknowledgments Supplementary Materials References Copyright Related Articles

Research Article | Open Access

Volume 2016 | Article ID 9846102 | https://doi.org/10.1155/2016/9846102

Morphological Study and Dielectric Behavior of Nonisothermally Crystallized Poly(ethylene naphthalate) Nanocomposites as a Function of Graphene Content

Adriana B. Espinoza-Martinez,¹Felipe Avalos-Belmontes,²Luis F. Ramos-de Valle,¹Pedro A. Espinoza-Martinez,¹Carlos A. Avila-Orta,¹Florentino Soriano-Corral,¹José M. Mata-Padilla,¹and María M. Tellez-Rosas²

Academic Editor: Yasuhiko Hayashi

Received21 Apr 2016

Accepted26 Sept 2016

Published23 Oct 2016

Abstract

Morphological evolution and dielectric properties of poly(ethylene naphthalate)- (PEN-) graphene nanocomposites nonisothermally crystallized have been investigated. PEN-graphene nanocomposites containing 0.01, 0.025, 0.05, 0.075, and 0.1 wt% of graphene were prepared by melt blending in a mini twin screw extruder. The results showed that graphene exhibited a superior influence on morphological and conformational structure of PEN during nonisothermal crystallization at low graphene contents. Crystallization temperature () was found to be increased up to 18°C supporting the high nucleating activity of graphene layers. Wide angle X-ray diffraction (WAXD) and Fourier Transform Infrared Spectroscopy (FTIR) indicated that graphene modifies the conformation of PEN chains promoting crystallinity and favoring the evolution from to crystalline form with homogeneous lamellar thickness. It may be attributed to the structural similarity between naphthalene rings and graphene structure and to - interactions during nucleation. Dielectric behavior was found to be a function of graphene content where the nanocomposites changed from dielectric to low conducting material when passing from 0.075 to 0.1 wt% of graphene content. This phenomenon permits having a wide range of properties to fit a wide variety of applications required to store electrical energy of low voltage.

1. Introduction

Graphene has become one of the most important carbon materials due to its unique electronic, mechanical, and thermal properties [1]. In the last five years, graphene has been used to fabricate polymer nanocomposites, and they have shown very high performance for a wide variety of applications such as automotive, packaging, and electronics [2–4]. Due to its two-dimensional structure, the percolation threshold can be achieved at very low contents (<0.1 vol%) that makes graphene a suitable carbon filler for electrostatic discharge and electromagnetic devices [5]. However, the use of polymeric nanocomposites in electronics is limited to a few plastics in combination with some conductive fillers. The characteristics sought in plastics intended for this use are gas barrier and corrosion and thermal and chemical resistance, as well as easy processing. Conductive nanocomposites based on engineering thermoplastics fulfill some of these features and could offer a wide range of advantages in electronic applications. Among these thermoplastics, semicrystalline polyesters such as poly(ethylene terephthalate) (PET) [6, 7] and poly(butylene terephthalate) (PBT) [8] have been widely used as structural materials in electrical, automotive, and electronic applications, and it has been reported that their use as matrix for electrical conductive nanocomposites is of great industrial relevance. Another engineering polyester is poly(ethylene naphthalate) (PEN) which is used as high-performance polymer with better mechanical, thermal, chemical, and barrier properties than PET [9, 10]. Resulting from the increased chain stiffness PEN can be used as stable substrate in electronic and optoelectronic devices, particularly electroluminescent display devices, such as organic light emitting diode displays (OLED displays) [11]. Another interesting characteristic of PEN is its ability to crystallize and gain certain properties absent in its amorphous state [12, 13]. It has been reported that PEN has three different crystal morphologies know as , , and [14], which can be obtained depending of the crystallization conditions, for example, crystallization temperature, cooling rate, premelting temperature, and mechanical orientation. Recently, it was reported that carbon nanotubes induce crystals in PEN nanocomposites under isothermal [15] and nonisothermal conditions [16] at low nanotubes content. It was proposed that nanotubes act as templates and induce an aromatic self-assembly due to the interactions between the naphthalene units of PEN and the aromatic surface of the nanotubes [16]. For graphene, there have been some reports dealing with its good nucleating effect and its improvement of the electrical properties, upon adding very small quantities of graphene, in semicrystalline polymers such as polypropylene, polyethylene, nylon poly(vinylidene fluoride) (PVDF), and so forth [17–19].

PEN nanocomposites were prepared by melt blending with low wt% of graphene and crystallized nonisothermally. Although electrical conductivity of graphene-based PEN composites has been reported [20], no research has been done on the crystalline morphology and its influence on the properties of graphene-based PEN nanocomposites. Therefore, morphological changes and thermal and dielectric properties of PEN nanocomposites were investigated in detail in the present study at very low graphene content.

2. Experimental

2.1. Materials

Poly(ethylene naphthalate) homopolymer TEONEX® TN8085S with = 42,921 g/gmol from Teijin Chemicals LTD and graphene Nano Platelets HDPlas™ from Cheap Tubes Inc. were used in the experiments as received. The graphene platelets had an approximate diameter of 1-2 μm, surface area >700 m²/g, >99 wt% of purity, a number of layers higher than 4, and low degree of defects according to the information obtained from RAMAN analysis of pristine graphene (see Supplementary Material available online at http://dx.doi.org/10.1155/2016/9846102).

2.2. Preparation of PEN-Graphene Nanocomposites

PEN and graphene were dried in a vacuum oven at 80°C overnight before preparing the nanocomposites. In order to increase the surface area of PEN pellets, they were pulverized down to a particle size of 100 μm. PEN was then mixed with different amounts of graphene: 0.01, 0.025, 0.05, 0.075, and 0.10 wt%. The nanocomposites were obtained in a laboratory mini extruder model LME-120, from Polymer Testing, Ithaca, NY, USA. Samples were passed twice through the extruder at 300°C and 120 rpm.

After melt compounding, nanocomposites were compression molded at 300°C and 10 MPa of pressure for 3 minutes, to obtain 1 mm thick samples, in order to eliminate any previous thermomechanical history. Finally, the samples were cooled down at −10°C/min. These samples were used for further characterization.

2.3. Characterization

2.3.1. Differential Scanning Calorimetry (DSC)

Crystallization and melting behavior of PEN-graphene nanocomposites was studied in a Perkin Elmer DSC 8500, from Perkin Elmer, Waltham, MA, USA, over the temperature range of 30–300°C under a nitrogen atmosphere. Samples were heated to 300°C at 10°C/min and held there for 3 min to erase previous thermal history and then cooled to 30°C at −10°C/min.

2.3.2. Wide Angle X-Ray Diffraction (WAXD) and Small Angle X-Ray Scattering Measurements (SAXS)

Simultaneous WAXD and SAXS measurements of pure polymer and nanocomposites were measured at room temperature using an Anton Paar X-ray scattering equipment SAXSess mc² from Anton Paar, Graz, Austria.

2.3.3. Fourier Transform Infrared Spectroscopy (FTIR)

FTIR spectra of PEN and nanocomposites were obtained using a NICOLET 500 spectrometer, from Thermo Fisher, MA, USA, equipped with ATR unit. FTIR spectra were acquired (50 scans and 4 cm⁻¹ resolution) from 4000–500 cm⁻¹.

2.3.4. Optical Microscopy

Distribution of graphene platelets in the polymer matrix at the micrometric scale was analyzed in an Olympus BX60 microscope, from Olympus of the Americas, Center Valley, PA, USA, at 200x. The particle size analysis was performed by using the ImagePro software.

2.3.5. Transmission Electron Microscopy (TEM)

The detailed morphology of nanocomposites was observed using a FEI-TITAN field emission microscope, from FEI North America, Hillsboro, OR, USA, with a voltage of 300 KV.

2.3.6. Capacitance Test

Dielectric properties were measured with a Keysight Precision LCR Meter model E4980A, from Keysight, Englewood, CO, USA, coupled with Keysight 16451B dielectric test accessory at room temperature. Frequencies used were, of 0.1, 1, 10, and 100 kHz. Each measurement was taken in quadruplicate and the average is reported as a result. The capacitance was determined by the parallel plate method according to ASTM D150-81.

3. Results and Discussion

3.1. Nonisothermal Crystallization

The presence of foreign particles in semicrystalline polymers during either isothermal or nonisothermal crystallization can modify the kinetics of the process. Depending on the characteristics of the particles such as the surface chemistry, morphology, size, and crystalline structure, these particles can act as nucleating agents [21, 22]. For PEN there is a nonextensive research on this topic compared to PET. However, there have been reported some substances that serve as heterogeneous nuclei and they initiate primary nucleation of PEN, or chemical nucleating agents, but all of them at higher contents to 0.1 wt% [23–26]. There have been a series of studies on the morphology, crystallization, and properties of PEN-carbon nanotubes composites. It has been found that higher nanotubes contents to 0.1 wt% accelerate crystallization and increase the crystallization temperature () [15, 16, 27, 28]. Figure 1 shows the cooling and heating thermograms of DSC at a rate of 10°C/min. It can be seen in Figure 1(a) that increases as a function of graphene content. In addition, it can be observed in Table 1 that the magnitude of increase of , with increasing graphene content, decreases constantly and reaches a plateau at a graphene content of 0.1 wt%, producing a of ~204.5 ± 0.5°C. At this point the graphene nuclei may have reached the saturation point. The melting endotherms of Figure 1(b) show the appearance of a shoulder in nanocomposites with 0.075 and 0.1 wt% of graphene, corresponding to a second melting endotherm indicating a second crystal population. It may suggest that graphene as well as carbon nanotubes transmutes the crystallization of PEN, from the form to the form [16].

(a)

(b)

Sorrentino et al. [29] studied the effect of expanded graphite (EG) on the crystallization and mechanical behavior of foamed PEN nanocomposites. During cooling from the molten state, they found an increase in of approximately 12°C at a maximum content of EG of 2.5 wt%. In our case an increase of around 18°C in was observed, with graphene contents as low as 0.01 wt%.

3.2. Crystalline Structure

The influence of graphene sheets on the PEN crystalline structure development was analyzed by means of WAXD. The relative crystallinity () was calculated by means of the Murthy and Minor method [30]. It can be seen in Figure 2 that with very low graphene content PEN passes from an almost completely amorphous state to a semicrystalline polymer with around 29% (Table 2). This phenomena indicates that graphene sheets act as effective nucleating particles for the crystallization of PEN. In this case, it is assumed that it is due to the structural similarity and the - interactions between naphthalene rings and the hexagonal structure of graphene promoting conformational changes at the unit cell level. PEN typically develops two crystalline forms called and [14]. The form of PEN, which typically occurs as the polymer, is cooled down from the melt to the and the chain configuration is totally extended; form is developed when PEN is crystallized under some orientation process, in which case the unit cell contains not one but four chains of PEN in a kind of sinusoidal configuration. All PEN-graphene nanocomposites showed a mixture of and crystalline forms. However, as shown in Figure 2, the form tends to dominate at the lower graphene contents, but as the graphene content increases up to 0.10 wt%, there is a transition and the form eventually dominates, as inferred from the disappearance of the (010), (100), and (10) diffraction peaks. This behavior has also been found in nonisothermally crystallized PEN-carbon nanotubes nanocomposites but at different filler contents [16, 31]. The fraction of crystals was calculated according to the standard procedure described by Jones et al. [32] with the following equation:where is relative content of -crystal form, , , , and are intensities of the strongest diffraction peaks of the triclinic form of PEN, and , , and are intensities of the strongest peaks of -form of PEN.

From the quantitative point of view, as can be observed in Table 2, at very low graphene contents (0.01 wt%), almost 50% of crystals are related to the -form crystals at very low graphene contents (0.01 wt%) and they eventually dominate the crystalline phase at graphene contents from 0.05 to 0.1 wt%.

According to the results, it can be suggested that the presence of a large amount of -form crystals formed by the simple incorporation of graphene layers allows the easy preparation of nanocomposites with higher density and then with a marked increase in the mechanical properties according to the experimental correlations between the presence of these carbon nanostructures and the packaging characteristics, and the tensile strength reported by other authors [33, 34].

3.3. Lamellar Structure

SAXS studies were carried out in order to analyze the influence of graphene in the lamellar thickness of PEN crystals. It can be seen in Figure 3 that the pure PEN pattern does not show any characteristic signal of the presence of lamellar structures. With the incorporation of low quantities of graphene, however, the ordering of PEN molecules is induced and lamellar crystals are formed, as indicated by the increasing shoulder at (1/nm). As can be observed, the crystal size () of PEN in nanocomposites remains quite unchanged even when there is a transition in crystals type from to . However, a narrower crystal size distribution can be seen in nanocomposites with 0.1 wt% of graphene. This may be assumed to be because at 0.1 wt% of graphene the surface area of particles is the adequate to induce almost a total to change in crystalline morphology of PEN.

3.4. Conformational Changes

As observed in WAXD results, graphene induces changes at the unit cell level in PEN molecules. These changes are promoted by means of conformational changes during crystallization, and the final arrangement of the PEN chains can be verified by infrared spectroscopy. The phenomenon of clay-induced polymorphism in PEN-clay nanocomposites has been reported [35]. In this case, the authors found that the type of crystal phase that forms during PEN crystallization depends on the surfactant molecules and their degradation products at the polymer/organoclay interface. In the case of PEN-graphene nanocomposites the hexagonal structure of graphene particles and aromaticity of PEN may play an important role during nucleation due to some aspects such as the lack of functional groups in the surface of graphene that avoid a steric hindrance for the adsorption of PEN molecules, the semiplanarity of PEN molecules, and - interactions between PEN and graphene surface. Figure 4 shows representative FTIR spectra of PEN and PEN nanocomposites nonisothermally crystallized. The region between 1000 and 800 cm⁻¹ was particularly analyzed. For pure PEN some peaks characteristic of the amorphous phase appear at 825 and 965 cm⁻¹ [36]. The appearance of new peaks in PEN nanocomposites is assumed to be due to the conformational changes induced by the interactions between PEN molecules and graphene surface during the nonisothermal crystallization process.

It can be seen that the FTIR spectra of nanocomposites show the signals of both, the and crystalline forms. Also, as the graphene content increases, the crystalline form becomes amply dominant, as indicated by the marked and well defined signals at 835, 920, and 978 cm⁻¹. This coincides with the data in Table 2, where the crystalline form passes from being 40% of the whole crystalline phase, at 0.010 wt% graphene content, to 90% at 0.10 wt% graphene content.

Due to the mixture of and crystals, the FTIR spectra of nanocomposites show the signals of both crystalline forms. However, due to the increase in graphenic nuclei, the -peaks are well defined at 835, 920, and 978 1/cm. It indicates important changes in the conformation of PEN molecules, from all-trans conformation to both trans and gauche conformations where the crystals population dominates.

3.5. Distribution and Dispersion of Graphene Particles in PEN Nanocomposites

In order to analyze the distribution of graphene particles in PEN nanocomposites at microscopic level samples were studied in an optical microscope. Figure 5 shows the distribution of graphene in the different nanocomposites. It can be seen in all cases that graphene particles are very well distributed and the average particle size was found to be around 1.5–2 μm. Continuing with this analysis, the morphology of graphene at a minor scale was carried out by means of TEM. Figure 6 shows a homogeneous dispersion in all nanocomposites. Also, it can be seen that graphene layers are partially exfoliated which can explain the good nucleating activity of graphene for PEN crystallization without the use of compatibilizers, ultrasound, or chemical modification of graphene as reported by other authors [20].

(a)

(b)

(c)

(d)

(e)

(a)

(b)

(c)

(d)

(e)

3.6. Dielectric Properties

Figure 7 shows the values of permittivity or dielectric constants of PEN and PEN-graphene nanocomposites at different frequencies. It is observed that the dielectric constant of processed PEN is around 1.9 at different frequencies. When graphene is added to PEN, the dielectric constants tend to increase up to 3.0 at 0.075 wt% of graphene, which is approximately twice that of the PEN dielectric constant. But as graphene content was increased to 0.1 wt%, however, the dielectric constant decreased. In this case, it has been reported [37] that some polymers tend to store some mobile charges such as phonons and electrons at low graphene contents, which produces an increase in the dielectric constant of polymer nanocomposites. As the graphene content increases, the dielectric constant decreases due to the accumulation of charge in the graphene-PEN interphase. At this point the charges start to present an increasing mobility, which eventually gives rise to the percolation phenomenon. In a few words by varying the graphene concentration it is possible to control dielectric constant of polymeric nanocomposites and they may serve as charge storing devices of low electric charge, for example, in microbial fuel cells or other organic bioelectricity sources [38].

4. Conclusions

The crystalline morphology changes and the dielectric properties of nonisothermally crystallized PEN-graphene nanocomposites were investigated. Results indicate that graphene induces PEN crystallization at very low graphene contents, from 0.01 to 0.1 wt%. According to the DSC analyses, showed a marked increase of up to 18°C supporting the high nucleating activity of graphene particles due to the structural similarity between the naphthalene rings of PEN and the graphene surface and - interactions. WAXD, SAXS, and FTIR clearly indicated that graphene modifies the conformation of PEN molecules during crystallization promoting the evolution from to crystalline form with a homogeneous thickness distribution in crystals population, which is preferred at 0.1 wt% of graphene. Distribution and dispersion of graphene were homogeneous in all nanocomposites and intercalation-exfoliation of graphene layers without the use of compatibilizers, ultrasound, or chemical modification of graphene was reasonably good. Finally, the dielectric behavior of PEN-graphene nanocomposites changes as a function of graphene content, changing from dielectric to a low conducting material when passing from 0.075 to 0.1 wt% of graphene.

Competing Interests

The authors declare that they have no competing interests.

Acknowledgments

One of the authors (Pedro A. Espinoza-Martinez) thanks CONACYT for granting him scholarship to carry his M.S. studies. Also, the authors gratefully acknowledge the financial support through Projects CIQA-6162 and CONACYT-CB-222805 and CONACYT-LN-232753. Also the authors wish to thank Marcelina Sánchez, Silvia Torres, Julieta Sánchez, Gilberto Hurtado, Josefina Zamora, Adán Herrera, Jesús Cepeda, Myriam Lozano, and Enrique Barriga for their technical support.

Supplementary Materials

Analysis of the structure of pristine graphene by micro-raman spectroscopy. RAMAN spectrum indicates (ID/IG ratio) that the pristine graphene has a low degree of defects. Also, it indicates the possibility that this graphene has approximately a number of layers higher than 4.

Supplementary Material

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Copyright © 2016 Adriana B. Espinoza-Martinez et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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