Review Article

Recent Progress in the Fabrication of Low Dimensional Nanostructures via Surface-Assisted Transforming and Coupling

Table 1

Dehalogenation of brominated versus iodinated precursors and occurrence of organometallic intermediates for different metal surface.

metalBromine cleavageIodine cleavage

Cu(111)  
organometallic → disordered
Full @ RTFull @ RT
Ag(111)  
organometallic → ordered
Partial @ RT
Full @ ~150°C
Full @ RT
Au(111)  
rarely organometallic intermediates
None @ RT
Full @ ~180°C
Full @ RT