Relative Humidity Dependent Resistance Switching of Bi<sub>2</sub>S<sub>3</sub> Nanowires

<div>Electrical characterization of individual Bi<sub>2</sub>S<sub>3</sub> nanowires: (a) SEM image of connected Bi<sub>2</sub>S<sub>3</sub> nanowire (<svg height="12.5155pt" id="M5" style="vertical-align:-3.22717pt" version="1.1" viewbox="-0.0498162 -9.28833 23.6862 12.5155" width="23.6862pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M530 686C535 705 530 712 521 712C504 712 448 684 359 674L358 648H393C437 648 439 646 429 593L400 435C372 447 345 448 332 448C286 448 194 414 144 373C68 311 23 203 23 111C23 26 57 -12 91 -12C120 -12 147 3 188 29C227 54 290 102 341 170H343L322 71C308 6 320 -12 341 -12C373 -12 442 27 501 96L485 120C455 91 422 67 408 67C401 67 401 76 404 91C440 294 479 473 530 686ZM387 375L355 241C326 187 200 53 142 53C126 53 109 73 109 130C109 217 154 337 218 381C240 396 265 404 297 404S372 390 387 375Z" id="g113-101"></path></g><g transform="matrix(.0091,0,0,-0.0091,7.15,3.132)"><path d="M731 650H485V618C556 614 580 601 585 558C588 530 592 485 592 390V153H589L173 650H22V618C69 614 92 606 112 582C131 558 132 555 132 483V266C132 175 129 128 125 96C120 49 95 36 36 33V0H281V33C212 36 188 50 183 98C180 129 177 175 177 266V510H179L603 -9H638V390C638 483 640 530 644 561C649 602 674 615 731 618V650Z" id="g58-76"></path></g><g transform="matrix(.0091,0,0,-0.0091,14.011,3.132)"><path d="M969 650H746V617C823 609 825 598 814 540C798 470 743 278 700 144H698C638 319 581 476 525 641H491C440 478 384 317 329 145H327C283 286 245 418 205 553C192 601 192 609 267 617V650H20V617C80 609 98 602 122 522C177 343 233 172 285 -9H321C372 152 428 309 485 485H487C542 330 604 151 660 -9H696C779 269 841 460 862 521C891 599 900 609 969 617V650Z" id="g58-85"></path></g></svg>–80 nm); (b) IVC of Bi<sub>2</sub>S<sub>3</sub> nanowire with nonlinear dependence; solid fit corresponds to simulated IVC with two reverse Schottky barriers; extracted Schottky barrier height <svg height="12.3916pt" id="M6" style="vertical-align:-3.42948pt" version="1.1" viewbox="-0.0498162 -8.96212 69.4337 12.3916" width="69.4337pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M542 242C542 369 469 429 379 468C370 472 372 496 376 513L416 681L400 691L344 648L219 51C167 69 113 128 113 217C113 324 166 387 266 428L252 459C124 418 23 336 23 202C23 95 90 13 205 -8L182 -132C165 -222 191 -254 209 -261L215 -258L270 -7C415 -4 542 98 542 242ZM469 232C469 126 403 33 279 39L355 409C399 394 469 331 469 232Z" id="g113-243"></path></g><g transform="matrix(.0091,0,0,-0.0091,7.02,3.132)"><path d="M389 0V32C297 38 291 46 291 118V635C234 613 175 595 109 583V556L161 554C203 552 207 547 207 497V118C207 46 201 38 110 32V0H389Z" id="g50-50"></path></g><g transform="matrix(.013,0,0,-0.013,15.598,0)"><path d="M537 353L508 390C487 357 455 333 417 333C389 333 344 353 309 370C265 391 212 414 172 414C122 414 79 382 50 340L81 307C101 339 134 364 172 364C198 364 245 343 280 326C324 305 375 283 417 283C466 283 507 314 537 353ZM537 168L508 205C487 172 455 148 417 148C389 148 344 168 309 185C265 206 212 229 172 229C122 229 79 197 50 155L81 122C101 154 134 179 172 179C198 179 245 158 280 141C324 120 375 98 417 98C466 98 507 129 537 168Z" id="g117-132"></path></g><g transform="matrix(.013,0,0,-0.013,26.861,0)"><path d="M542 242C542 369 469 429 379 468C370 472 372 496 376 513L416 681L400 691L344 648L219 51C167 69 113 128 113 217C113 324 166 387 266 428L252 459C124 418 23 336 23 202C23 95 90 13 205 -8L182 -132C165 -222 191 -254 209 -261L215 -258L270 -7C415 -4 542 98 542 242ZM469 232C469 126 403 33 279 39L355 409C399 394 469 331 469 232Z" id="g113-243"></path></g><g transform="matrix(.0091,0,0,-0.0091,33.881,3.132)"><path d="M414 144C384 79 371 75 317 75H135L276 221C367 316 408 376 408 465C408 570 327 635 237 635C179 635 131 609 100 575L42 494L67 471C94 510 138 565 205 565C277 565 321 517 321 435C321 348 258 270 195 195C146 137 88 81 33 26V0H411C423 44 433 88 446 135L414 144Z" id="g50-51"></path></g><g transform="matrix(.013,0,0,-0.013,42.46,0)"><path d="M535 323V373H52V323H535ZM535 138V188H52V138H535Z" id="g117-34"></path></g><g transform="matrix(.013,0,0,-0.013,53.722,0)"><path d="M241 635C89 635 35 457 35 312C35 153 89 -12 240 -12C390 -12 443 166 443 312C443 466 390 635 241 635ZM238 602C329 602 354 454 354 312C354 172 330 22 240 22C152 22 124 173 124 313S148 602 238 602Z" id="g113-49"></path></g><g transform="matrix(.013,0,0,-0.013,59.962,0)"><path d="M113 -12C146 -12 170 11 170 46C170 78 146 103 114 103S58 78 58 46C58 11 82 -12 113 -12Z" id="g113-47"></path></g><g transform="matrix(.013,0,0,-0.013,62.926,0)"><path d="M137 343C167 482 260 545 321 574C357 591 397 603 429 609L423 641C382 634 335 622 295 608C189 570 37 457 37 238C37 84 125 -12 242 -12C362 -12 447 89 447 209C447 311 374 393 267 393C247 393 226 386 204 376L137 343ZM227 337C318 337 361 256 361 173C361 105 336 22 258 22C176 22 126 120 126 240C126 266 127 291 132 310C155 323 189 337 227 337Z" id="g113-55"></path></g></svg> eV; relative humidity level = 5%.</div>

Journal of Nanomaterials

fig1

Figure 1

Figure 1: Relative Humidity Dependent Resistance Switching of Bi<sub>2</sub>S<sub>3</sub> Nanowires 

Journal of Nanomaterials

Relative Humidity Dependent Resistance Switching of Bi2S3 Nanowires

Figure 1

Relative Humidity Dependent Resistance Switching of Bi₂S₃ Nanowires