Recent Developments in Nanostructured Palladium and Other Metal Catalysts for Organic Transformation

Table 2

Suzuki reaction with various metal nanocatalysts .

Nanocatalyst (amount)	PhI	PhB(OH)2	Base	Solvent	(°C)	Time (h)	Yield (%)	Ref.
Pd-SMU-MNPs (6 mg)	1	1	K2CO3	PEG	50	0.5	97^a	[42]
Cu-C (0.1 mol%)	1	1.2	K2CO3	H2O	50	3	96^a	[53]
Fe3O4NPs/IL/Pd(0) (0.2 mol%)	1	1.1	K2CO3	H2O/EtOH (1 : 1)	RT	0.25	96^a	[54]
Au-graphene (1 mol%)	1	1.2	NaOH	H2O	100	4	85^b	[55]
Pd/TiO2 (0.7 mol%)	1	1.1	Na2CO3	NMP : H2O (2.5 : 1)	120	4	97^a	[56]
Ru/Al2O3 (5 mol%)	1	1.5	NaOH	DME/H2O (1 : 1)	60	1	96^a	[57]
Pd@MWCNTs (1 mmol%)	1	1.2	K2CO3	MeOH : H2O (3 : 1)	Reflux	2.5	84^b	[51]
PVP-stabilized Pd-NPs (0.07 mol%)	0.5	0.75	K3PO4	H2O : EtOH (3 : 1)	90	24	97^b	[58]
Pd/NH2-SiO2 (0.05 mol%)	1	1.2	K2CO3	H2O (2 mL)	60-70	1	96^a	[44]
Fe3O4@CS-Schiff-based Pd catalyst (10 mg)	1	1.2	K2CO3	PEG	80	0.17	98^a	[43]
Pd-Ni@Fe3O4 (0.0026 mol% of Pd and 0.001 mol% of Ni))	0.5	0.75	K2CO3	EtOH	80	0.25	94^a	[59]
Pd/r-GO NP thin film	1	1.2	K2CO3	H2O	80	0.25	>99^a	[60]
LDH-DS-Pd(0) (0.5 mol%)	1	1.2	K2CO3	DMF/H2O 6 mL (5 : 1, /)	80	5	93^a	[61]
Pd@MTiO2 (0.03 g)	1	1.2	K2CO3	H2O	70	3	99^b	[62]
Carbon nanocomposite Pd catalyst (1 mol%)	0.5	0.6	K2CO3	DMF/H2O (2 : 1)	100	1.5	97^b	[63]
Core-shell-like Ni-Pd/CB catalyst (5.5 mg, 0.1 mol% Pd)	2.5	2.75	K2CO3	EtOH/H2O (1 : 1)	30	0.5	90^a	[64]
Au-G nanocomposite (0.05 g)	1	1.5	K2CO3	H2O	RT	4	99^b	[65]
Sr/Alg/CMC/GO/Au (0.005 mol%)	2	2.4	NaOH	H2O	80	4	98^a	[66]
OXDH-Pd-NPs (0.0091 mmol)	5.41	4.92	Na2CO3	1,4 Dioxane/water (1 : 1)	80	1	98^a	[45]
Stabilized Pd-NPs (1 mol%)	0.5	0.75	KF	DMF : H2O (1 : 1)	RT	24	93^a	[41]