Research Article
Adsorption of Carbon Dioxide, Methane, and Nitrogen Gases onto ZIF Compounds with Zinc, Cobalt, and Zinc/Cobalt Metal Centers
Table 1
The fitting constants of the DSL equation for CH4, N2, and CO2 on ZIF-8, Co-ZIF-8, and Zn/Co-ZIF-8.
| Constants | Specimens | ZIF-8 | Co-ZIF-8 | Zn/Co-ZIF-8 | Gas | Nitrogen | Methane | Carbon dioxide | Nitrogen | Methane | Carbon dioxide | Nitrogen | Methane | Carbon dioxide |
| (mole/kg) | 38359 | 9.58 | 97.28 | 12139 | 7.37 | 21.83 | 13139 | 8.45 | 42.85 | (MPa-1) | | | | | | | | | | (K) | 693.55 | 1582 | 5038 | 881.97 | 1535.11 | 2917.13 | 861.97 | 1649.61 | 1904.60 |
| (mole/kg) | 0 | 0 | 27.89 | 0 | 0 | 0 | 0 | 0 | 0 | (MPa-1) | 0 | 0 | | 0 | 0 | 0 | 0 | 0 | 0 | (K) | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| | 0.020 | 0.0082 | 1.07 | 2.04 | 0.13 | 0.22 | 1.52 | 0.11 | 0.22 | (%) | 8.82 | 3.54 | 7.46 | 34.61 | 12.15 | 27.98 | 45.30 | 9.32 | 18.26 |
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