Highly Sensitive Detection of Dopamine at Ionic Liquid Functionalized RGO/ZIF-8 Nanocomposite-Modified Electrode

<div>(a) Nyquist plots of the bare GCE, ZIF-8/GCE, IL-RGO/GCE, and IL-RGO/ZIF-8 with different contents of IL-RGO-modified GCEs in the presence of 0.1 M PBS solution (pH 7.0) containing <svg height="11.9413pt" id="M20" style="vertical-align:-0.3499002pt" version="1.1" viewbox="-0.0498162 -11.5914 65.928 11.9413" width="65.928pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M384 0V27C293 34 287 42 287 114V635C232 613 172 594 109 583V559L157 557C201 555 205 550 205 499V114C205 42 199 34 109 27V0H384Z"></path></g><g transform="matrix(.013,0,0,-0.013,6.24,0)"><path d="M113 -12C146 -12 170 11 170 46C170 78 146 103 114 103S58 78 58 46C58 11 82 -12 113 -12Z"></path></g><g transform="matrix(.013,0,0,-0.013,9.204,0)"><path d="M241 635C89 635 35 457 35 312C35 153 89 -12 240 -12C390 -12 443 166 443 312C443 466 390 635 241 635ZM238 602C329 602 354 454 354 312C354 172 330 22 240 22C152 22 124 173 124 313S148 602 238 602Z"></path></g><g transform="matrix(.013,0,0,-0.013,18.35,0)"><path d="M528 54L331 254L528 455L492 493L294 291L96 493L60 455L257 254L60 54L96 16L294 217L492 16L528 54Z"></path></g><g transform="matrix(.013,0,0,-0.013,28.886,0)"><path d="M384 0V27C293 34 287 42 287 114V635C232 613 172 594 109 583V559L157 557C201 555 205 550 205 499V114C205 42 199 34 109 27V0H384Z"></path></g><g transform="matrix(.013,0,0,-0.013,35.126,0)"><path d="M241 635C89 635 35 457 35 312C35 153 89 -12 240 -12C390 -12 443 166 443 312C443 466 390 635 241 635ZM238 602C329 602 354 454 354 312C354 172 330 22 240 22C152 22 124 173 124 313S148 602 238 602Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,41.413,-5.741)"><path d="M556 236V289H56V236H556Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,46.973,-5.741)"><path d="M462 177V227H365V632H320C217 496 116 350 21 208V177H284V109C284 43 280 38 190 31V0H451V31C369 38 365 43 365 108V177H462ZM284 227H88C155 336 218 430 282 519H284V227Z"></path></g><g transform="matrix(.013,0,0,-0.013,54.115,0)"><path d="M861 0V28C774 35 771 41 768 147L759 509C756 612 762 614 851 622V650H681L449 149L221 650H57V622C148 613 153 609 144 479L130 271C123 166 117 123 111 88C104 46 85 34 26 28V0H259V28C192 35 169 42 167 90C166 130 166 173 170 256L185 541H187L411 7H431L675 555H679L683 147C683 41 680 35 598 28V0H861Z"></path></g></svg> DA; inset: semicircles at high frequency. (b) Frequency as a function of the real part and imaginary part of impedance of IL-RGO(2)/ZIF-8/GCE (the diamond is the real part of the impedance and the pink circle is the imaginary part of the impedance). Inset: the equivalent circuit of the IL-RGO/ZIF-8/GCE electrode in PBS solid solution. The red solid lines were fitted by the inset equivalent circuit.</div>

Journal of Nanomaterials

fig5

Figure 5

Figure 5: Highly Sensitive Detection of Dopamine at Ionic Liquid Functionalized RGO/ZIF-8 Nanocomposite-Modified Electrode 