Recent Development of Catalytic Materials for Ethylbenzene Oxidation

Table 2

Recently used heterogeneous catalysts in oxidation reactions.

Year	Catalysts	Method of catalysts synthesis	Application	Ref.
2019	Mn catalysts on various supports	Coprecipitation	Carbon monoxide oxidation	[50]
	Copper promoted ceria	Hydrothermal	Carbon monoxide oxidation	[51]
	Copper on titania aerogel	Wet impregnation	Carbon monoxide oxidation	[52]
	Pd supported on CeO2(100) and CeO2(111) facets	Hydrothermal	Carbon monoxide oxidation	[53]
	Copper on titania hollow sphere	Wet chemical	Methanol oxidation	[54]
	Pt-based catalysts	Chemical reduction	Glycerol	[55]
	RuO2/TiO2 catalyst	—	Hg° oxidation	[56]
	MnO2 hollow sphere	Precipitation	Formaldehyde oxidation	[57]
2018	Ruthenium catalyst	—	Water oxidation	[58]
	Solid catalyst on various supports	Impregnation	1-Octonol oxidation	[59]
	Bioinspired manganese catalysts	—	Enantioselective oxidation of spirocyclic compounds	[60]
	Pt catalyst on carbon	—	Xylose	[61]
	α-ZrP. Mn(II)	Ion exchange	Cyclohexane oxidation	[62]
2017	Pt-Sn on carbon support	Formic acid reduction	Ethanol and carbon monoxide oxidation	[63]
	Pt-Ru/C	Colloidal method	Glycerol oxidation	[64]
	Porphyrinic metal-organic framework	Postsynthetic modification	Cyclohexane	[65]
	MnOx-CeO2 supported on Co-N-C	Coprecipitation	Ethylbenzene oxidation	[66]
2016	Pd-Pt nanocubes	Wet impregnation	Carbon monoxide oxidation	[67]
	Pt3Ni alloy nanoparticles	Impregnation	Carbon monoxide oxidation	[68]
	Boron-doped crystalline diamond	—	Aliphatic polyamine oxidation	[69]
	Pd/graphene	Sonoelectrochemical and chemical-reduction	Glucose oxidation	[70]
	PdO/graphene	Cyclic voltammetry (CV) and chronoamperometry (CA)	Ethanol oxidation	[71]
	Graphene-supported palladium	—	Formaldehyde oxidation	[72]
2015	PtAg bimetallic alloy	Coreduction	Methanol oxidation	[73]
	Pt/carbon xerogel and Vulcan carbon	Impregnation, microemulsion	Methanol oxidation	[74]
	Nickel supported on nitrogen-doped carbon nanotubes	Hydrothermal	Hydrogen oxidation	[27]
	Lanthanum-based perovskite supports for AuPt nanoparticles	SAS precipitation	Glycerol oxidation	[75]
2014	Au/MnO	Photochemical, electrochemical	Water oxidation	[76]
	Pd-Cu nanoalloy	Soft chemical method	Methanol oxidation	[77]
	Cu (II) functionalized Fe3O4	—	Sulfides and thiols	[78]
	Pd-Cu bimetal	Coreduction	Ethanol oxidation	[79]
	Pd nanohollow/Pt nanorod core/shell composite	Multistep crystalline growth	Methanol oxidation	[80]
2013	Au/Mg(OH)2	Deposition	Carbon monoxide	[81]
	Au/Al2O3, Au/C	Dispersion	Glucose oxidation	[82]
	Au/Pt bimetallic nanoparticles	Dispersion, reduction	Glucose oxidation	[83]
	Au/CuO	Coprecipitation	Carbon monoxide	[84]
2012	Au/C	Incipient wet impregnation	Glucose oxidation	[85]
	Au/SiO2	Stöber method	Cyclohexene and d-glucose oxidation	[86]
	Au-Cu/SiO2	Two-step method	Alcohol	[87]
	Au-Pd/MgO	Sol immobilization, adsorption-reduction	Benzyl alcohol oxidation	[88]
2011	Pd-Ni electrocatalysts	Nanocapsule	Ethanol oxidation	[89]
2010	PtBi/C electrocatalysts	Borohydride reduction	Ethanol electrooxidation	[90]
	PdIr/C	Simultaneous reduction	Ethanol oxidation	[91]
	PtSn/C-Rh, PtSn/C-CeO	Alcohol reduction, polymeric precursor	Ethanol oxidation	[92]
2009	Gold nanoparticles	Reduction	Glucose and 1-phenyl ethanol	[93]
	Supported gold nanoparticles	—	Silanol oxidation	[94]
2008	Metalloporphyrin and cobalt acetate	Condensation	p-Xylene oxidation	[95]
	Au/TiO2	Deposition precipitation	Alcohol oxidation	[96]
2007	Gold catalysts	—	Alcohol oxidation	[97]
	CuO/mesoporous silica	Impregnation	Benzene oxidation	[98]
	Supported gold catalysts	Deposition precipitation	Alcohol oxidation	[99]
2005	Gold with anionic ligand	Precipitation	Alcohol oxidation	[100]