Review Article

Fundamentals, Thermophysical Properties, and Heat Transfer Characteristics of Nanorefrigerants: A Review

Table 1

Studies on stability of various nano-based refrigerants.

AuthorsNanoparticles and
refrigerants
ParametersCharacterizationMethod of stabilizationInferences

Liu et al. [40]AuR141b1 vol%TEM, dynamic light scattering analysisNo discussion on stability
Xiao-Min et al. and Park et al. [29, 41]CNT’sR22, R123, and R134a1 vol%No discussion on stability
Bartelt et al. [42]CuOR134a+oil RL68H4 vol% in oil,
0.5, 1, and 2 mass% of suspension in R134a,
avg size: 30 nm
Ultrasonic agitation of nanolubricant for 24 hFlow boiling study
Bi et al. [9]TiO2 and Al2O3R134a+mineral oil1 mass%,
50 nm
Light transmission ratio indexUltrasonic agitationStable suspension
Ding et al. [43]CuOR113+RB68EP oil40 nmTEMNo surfactantsConsidered to be stable
Kedzierski et al. [25]CuOR134a (with polyolester)1 vol% in polyolester,
size: 30 nm
Light scattering techniqueSurfactant and ultrasonication for 24 hParticles will dispersed after weeks with avg size 35 nm
Trisaksri et al. [31]TiO2R141b0.01, 0.03, and 0.05 vol%TEMUltrasonication for 6 hStable dispersion was found
Peng et al. [33]CuOR1130.1, 0.2, and 0.5 wt%,
avg size: 40 nm
TEMUltrasonic processing for 30 minStable dispersion was found
Jiang et al. [44]CNT’sR113Size: 15-80 nm
0.2, 0.4, 0.6, 0.8, and 1 vol%
TEMUltrasonic process for 30 minNo discussion
on stability
Henderson et al. [34]SiO2 and CuOR134a+polyolester0.05 and 0.5 vol% of SiO2,
0.02, 0.04, and 0.08 vol% of CuO,
Not mentionedHexamethyl-disilazane coated on SiO2, and CuO mixture is ultrasonic agitated for several minSiO2
is stable with coating.
CuO needs ultrasonic mixing for stable dispersion
Peng et al. [26]DiamondR113 (oil VG68)3 wt% in oil,
5, 10, and 15 wt% of suspension in R113,
size: 10 nm
SEMUltrasonication for 12 hObserved the stable suspension after 12 h
Peng et al. [45]CNT’sR113+oil VG68 mixture1, 3 and 5 wt% of CNT nanolubricant mixed with R113TEMUltrasonication for 120 minStable dispersion was found
Bobbo et al. [46]SWCNH’s and TiO2R134a+POE oilSWCNH’s–100 nm and TiO2–21 nm
0.5 g/L
TEM for SWCNH’sUltrasonic vibration for 45 minNo discussion
On stability
Kedzierski [47]Al2O3R134a (with polyolester)5.6% in polyolester,
0.5, 1, and 2 mass% of suspension with R134a,
size: 20 nm
Light scattering techniqueSurfactant and ultrasonication for 24 hParticles dispersed properly with avg size 10 nm
Peng et al. [32]CuR113+oil VG68Size: 20, 50, and 80 nm,
0-5 wt% of suspension
TEMUltrasonication for 1 hStable dispersion was ensured
Peng et al. [48]CuR1130.1, 0.5, and 1.0 wt% in R113,
avg size: 20 nm.
TEM, Spectro-photometerSurfactants: SDS, CTAB, and Span-80 and ultrasonication for 1 hFound stable for 24 h
Peng et al. [49]Cu, Al, Al2O3, and CuOR113, R141b, and n-pentane+RB68EP oil0.2–1.37 vol%,
size: 20 nm
TEMNo surfactantsNo discussion on stability
Bi et al. [10]TiO2R600a0.1 and 0.5 g/LLight transmission ratio indexStable suspension
Abdel-Hadi et al. [50]CuOR134aSize: 15-70 nm
0.1–1%
Mixed by gravity effectFlow boiling study
Mahbubul et al. [51]TiO2R123Up to 5 vol%
avg size: 21 nm
Not mentionedNo surfactantsFlow analysis
Subramani et al. [52]Al2O3R134a0.06 mass% of nanolubricant
avg size: 50 nm
Not mentionedUltrasonic agitation for 24 hStable dispersion for 3 days
Kumar et al. [53]Al2O3R134a+PAG oil0.2%
concentration,
size: 40-50 nm
Not mentionedMagnetic stirrer for mixing and ultrasonic shake for 30 minEnsured stable dispersion
Hu et al. [54]CuR113+oil VG68Nanolubricant; 1,3, and 5 wt%,
surfactant; 0-10,000 ppm
TEMSurfactants: SDS, CTAB, and Span-80 and ultrasonication for 1 hStable for 24 h
Mahbubul et al. [16, 22]Al2O3R141bSize: 13 nm
0.5, 1, 1.5, and 2 vol%
TEMOrbital incubator shaking for 24 h at 240 rpmStable suspension was ensured
Sun et al. [55, 56]Cu, Al, Al2O3, and CuOR141b0.1, 0.2, and 0.3 wt% in R141b,
avg size: 40 nm
Visible spectro-photometerSurfactant: Span-80 and
ultrasonic shaking for 30 min
Dispersion was stable
Tang et al. [57]δ-Al2O3R141b0.001, 0.01, and 0.1 vol%SEMSurfactant: SDBS and ultrasonication for 10 hPredicted to be stable for 54 days
Nephon et al. [30]TiO2R141b0.01, 0.025, 0.05, and 0.075 vol%,
avg. size: 21 nm
Not mentionedUltrasonication for 3 hSynthesized just before experiments and found stable
Baqeri et al. [58]CuOR600a/POE0.5, 1, 1.5, 2, and 5 wt%Ultrasonic shakingFound stable for 12 h
Mahbubul et al. [59]Al2O3R141bSize: 13 nm
0.05–0.15 vol%
SEM, TEMMechanical shaking for 24 h at 240 rpmProper dispersion of particles
Akhavan-Behabadi et al. [60, 61]CuOR600a+(oil RL68H)0.5, 1, and 1.5 wt%,
avg size: 50 nm
Not mentionedUltrasonic shaking for 1 hVisually ensured stable dispersion
Diao, et al. [27]CuR141b0.008, 0.015, and 0.05 vol%
avg size: 30 nm
SEMSDBS and ultrasonic shaking for 8 hObtained stabilized suspension
Yang et al. [62]MWCNT’sR141b0.1, 0.2, and 0.3 wt%Visible spectro-photometerSurfactant: Span-80 and ultrasonic shaking for 30 minStable dispersion was found
Kedzierski et al. [63]Al2O3R134a (with polyolester)1.6, 2.3, and 5.1 vol% in polyolester,
0.5 and 1 mass% in R134a
Dynamic light scattering techniqueSurfactant and ultrasonication for 24 hParticles dispersed properly with avg size 10 nm
Alawi et al. [64]TiO2R1230.5-2 vol%
size: 20 nm
Flow boiling study