Research Article

Properties of Silicon Dioxide Amorphous Nanopowder Produced by Pulsed Electron Beam Evaporation

Table 2

The centers of the peaks in the spectrum of pulsed cathodoluminescence NP SiO2 (Figure 6).

Peak, numberPeak centres AssociationReferences
nmeV

1451.52.74Twofold coordinated silicon centers ≡Si–Si≡[30]
Oxygen-deficient centers[30, 42]

2 5132.4Self-trapped exciton[34]
Oxygen vacancy related defect[24]

35902.1Nonbridging oxygen hole centers (NBOHC) ≡Si–O[43]
Hydrogen-related defects (the OH group)[24]

46182.00Fe3+ (transition (4G) → (6S)) [31]
Si nanocluster[25, 35]
The nonbridging oxygen hole centers (NBOHC) ≡Si–O[37, 39]
The quantum confinement effect[38, 39]
Defects in the Si oxide/Si interface[26, 3941]

56491.91Nonbridging oxygen hole centers (NBOHC) ≡Si–O[24]

66831.81≡Si–O–O•[43]
Si nanocluster [24, 25, 36]

77021.76Si nanocluster [24, 25, 30, 36]

87431.67Si nanocluster [24, 25, 30, 36]

97951.56Si nanocluster [25, 36]