Research Article
Properties of Silicon Dioxide Amorphous Nanopowder Produced by Pulsed Electron Beam Evaporation
Table 2
The centers of the peaks in the spectrum of pulsed cathodoluminescence NP SiO
2 (Figure
6).
| Peak, number | Peak centres | Association | References | nm | eV |
| 1 | 451.5 | 2.74 | Twofold coordinated silicon centers ≡Si–Si≡ | [30] | Oxygen-deficient centers | [30, 42] |
| 2 | 513 | 2.4 | Self-trapped exciton | [34] | Oxygen vacancy related defect | [24] |
| 3 | 590 | 2.1 | Nonbridging oxygen hole centers (NBOHC) ≡Si–O• | [43] | Hydrogen-related defects (the OH group) | [24] |
| 4 | 618 | 2.00 | Fe3+ (transition (4G) → (6S)) | [31] | Si nanocluster | [25, 35] | The nonbridging oxygen hole centers (NBOHC) ≡Si–O• | [37, 39] | The quantum confinement effect | [38, 39] | Defects in the Si oxide/Si interface | [26, 39–41] |
| 5 | 649 | 1.91 | Nonbridging oxygen hole centers (NBOHC) ≡Si–O• | [24] |
| 6 | 683 | 1.81 | ≡Si–O–O• | [43] | Si nanocluster | [24, 25, 36] |
| 7 | 702 | 1.76 | Si nanocluster | [24, 25, 30, 36] |
| 8 | 743 | 1.67 | Si nanocluster | [24, 25, 30, 36] |
| 9 | 795 | 1.56 | Si nanocluster | [25, 36] |
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