Research Article
Compatibilizer Polarity Parameters as Tools for Predicting Organoclay Dispersion in Polyolefin Nanocomposites
Table 1
Characteristics of the polyolefin-montmorillonite nanocomposite samples included in the analysis.
| | Sample number | Compatibilizer | Polymer | Organoclay | Nanocomposite | References | | Type (Trade name. Supplier) | Acid value (mg KOH/g) | Molar weight (MW) | Type | Extrusion temperature (°C) | Type (Trade name) | Clay basal spacing d001 (nm) | Organoclay/polymer ratio (wt./wt.) | Clay basal spacing d001 (nm) |
| | 1 | PP-g-MA (PB3200. Crompton) | 11 | 120 000 | PP | 165 | OCT (nanomer I.30 P) | 2.36 | 80/15 | 2.89 | [47] | | 2 | PP-g-MA (PB3000. Crompton) | 14 | 61 000 | PP | 165 | OCT (nanomer I.30 P) | 2.36 | 80/15 | 2.99 | [47] | | 3 | PP-g-MA (PB3150. Crompton) | 6 | 330 000 | PP | 165 | OCT (nanomer I.30 P) | 2.36 | 80/15 | 2.67 | [47] | | 4 | PP-g-MA (PP-MA-1010. Sanyo) | 52 | 30 000 | PP-MA-1010a | 190 | OCT (own synthesis) | 2.20 | 75/25 | 5.88 | [48] | | 5 | PP-g-MA (PP-MA-1010. Sanyo) | 52 | 30 000 | PP-MA-1010a | 200 | OCT (own synthesis) | 2.10 | 75/25 | 6.30 | [49] | | 6 | PP-g-MA (PP-MA-1001. Sanyo) | 26 | 40 000 | PP-MA-1001a | 190 | OCT (own synthesis) | 2.20 | 75/25 | 7.37 | [48] | | 7 | PP-g-MA (CA100. Arkema Orevac) | 11 | 88 000 | PP | 180–200 | DMDHTA (Cloisite 20A) | 2.51 | 80/15 | 3.11 | [50] | | 8 | PP-g-MA (Polybond 3200. Crompton) | 11 | 95 804 | PP | 190–210 | DMDHTA (Cloisite 20A) | 2.42 | 84/12 | 3.49 | [54] | | 9 | SEBS-g-MA (Kraton FG 1901X. Shell) | 20 | 97 700 | PP | 200 | DMDHTA (Cloisite 15A) | 3.34 | 85/15 | 3.71 | [57] | | 10 | LLDPE-g-MA (18302 N. Arkema Orevac) | 9 | 125 000 | LLDPE | 200 | DMDHTA (Cloisite 20A) | 2.59 | 92/6 | No dc001 pic | [30] | | 11 | LLDPE-g-MA (Bondyram 4001. Polyram) | 9 | 69 000 | LLDPE | 200 | DMDHTA (Cloisite 20A) | 2.59 | 92/6 | 4.42 | [30] | | 12 | LLDPE-g-MA (Bondyram 4001A. Polyram) | 9 | 200 000 | LLDPE | 200 | DMDHTA (Cloisite 20A) | 2.59 | 92/6 | 4.34 | [30] | | 13 | PP-g-AA (polybond 1002. Crompton) | 46 | 162 504 | PP | 190–210 | DMDHTA (Cloisite 20A) | 2.42 | 84/12 | 3.20 | [54] | | 14 | PP-g-GMA (PP-g-GMA. own synthesis) | 7 | 190 409 | PP | 190–210 | DMDHTA (Cloisite 20A) | 2.42 | 84/12 | 3.65 | [54] | | 15 | OxPE (AC 316. Honeywell) | 16 | 12 928 | LLDPE | 160–180 | DMDHTA (Cloisite 20A) | 2.28 | 85/15 | 3.16 | [23] | | 16 | OxPE (AC 330. Honeywell) | 30 | 8 850 | LLDPE | 160–180 | DMDHTA (Cloisite 20A) | 2.28 | 85/15 | 3.43 | [23] | | 17 | OxPE (AC 395. Honeywell) | 42 | 8 400 | LLDPE | 160–180 | DMDHTA (Cloisite 20A) | 2.28 | 85/15 | 3.22 | [23] |
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aNo additional polymer; only includes compatibilizer and nanoclay.
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