Review Article
Plant-Mediated Biosynthesis and Photocatalysis Activities of Zinc Oxide Nanoparticles: A Prospect towards Dyes Mineralization
Table 2
Examples of biosynthesized ZnO NPs and their photodegradation efficiency.
| No. | Plant source | Part extracted | Presource of ZnO NPs | Size | Type of ZnO NPs (catalyst) | Light source | Type of dyes | Degradation efficiency % (time) | Reusability | References |
| 1 | Coriandrum sativum | Leaf | Zinc acetate | 24 nm | ZnO NPs | Direct sun light irradiation | Yellow 186 dye | 93.3–130 min | 3 runs | [2] | 2 | Oak | Fruit hull | Zinc acetate dihydrate | 34 nm | ZnO NPs | Visible light | Basic violet 3 | 93–2:30 h | — | [17] | 3 | Garcinia mangostana | Fruit | Zinc nitrate hexahydrate | 21 nm | ZnO NPs | Solar light | Malachite green dye (MG) | 99–180 min | — | [20] | 4 | Mussaenda frondosa | Leaf/stem | Zinc nitrate | 5–20 nm | ZnO NPs | UV | MB | 80–100 min | — | [33] | 30–100 min | 5 | Moringa oleifera (drumstick) | Leaves | Zinc acetate dihydrate | 52 nm | ZnO NPs | Visible light | Titan yellow dye | 96–60 min | — | [39] | 6 | Sambucus ebulus | Leaf | Zinc acetate dihydrate | 17 nm | ZnO NPs | UV | MB | 80–200 min | — | [40] | 7 | Vitex trifolia L | Leaf | Zinc nitrate hexahydrate crystal | 28 nm | ZnO NPs | UV | MB | 92.13–90 min | — | [41] | 8 | C. sinensis | Peel | Zinc nitrate | 22.6 nm | ZnO NPs | UV | MB | 83–120 min | — | [42] | 9 | Brassica oleracea L. var. italica | Broccoli leaves | Zinc chloride ZnCl2·7H2O | 14–17 nm | ZnO NPs | UV | MB/phenol red (PR) | 74–180 min | — | [43] | 71–180 min | 10 | Tabernaemontana divaricata | Green leaf | Zinc nitrate | 20–50 nm | ZnO NPs | Sunlight | MB | ≈100–90 min | — | [44] | 11 | Coriandrum sativum | Leaf | Zinc acetate dihydrate | 9–18 nm. | ZnO NPs | UV | Anthracene | 89–240 min | — | [45] | 12 | Dolichos lablab L. | Leaf | Zinc acetate dihydrate | 29 nm | ZnO NPs | Visible and near-UV | MB/rhodamine B (RhB), orange II (OII) | 80–210 min | — | [46] | 95–210 min | 66–210 min | 13 | Carica papaya | Latex | Zinc nitrate | 11–26 nm | ZnO NPs | UV | Alizarin red-S dye | 99–120 min | 4 runs | [47] | 14 | Sea buckthorn | Fruit | Zinc nitrate hexahydrate | 17.15 nm | ZnO NPs | UV | Malachite green/Congo red/MB/eosin Y | 100–70 min | 5 runs | [48] | 99–80 min | 99–70 min | 100–90 min | 15 | Cannabis sativa | Leaf | Zinc acetate | 34 nm 38 nm | Ag-ZnO NPs/ZnO NPs | Solar light | Congo red/methyl orange | 96–80 min | — | [49] | 38–80 min | 94–80 min | 35–80 min | 16 | Ferulago angulata | — | Zinc acetate dihydrate | 32–36 nm | ZnO NPs | Visible light | Rhodamine B | 93–3.5 h | — | [50] | 17 | Chlorella | — | Zinc nitrate | 20 ± 2.2 nm | ZnO NPs | UV | Dibenzothiophene (DBT) | 97–3 h | 5 runs | [51] | 18 | Euphorbia prolifera | Leaf | Zinc chloride + ZnO NPs | 5–17 nm | Cu/ZnO NPs | UV | MB/Congo red (CR) | 100≈ 0 min/≈ 100–9 min | 5 runs | [52] | 19 | Azadirachta indica | Leaves | Zinc nitrate | 9–38 | ZnO NPs | Sunlight/UV light | MB | 92–120/85–120 min | — | [53] | 20 | Betel | Leaves | ZnO acetate | 50 nm | ZnO NPs | Solar/UV | MB | 90–210 min | — | [54] | 96–210 min | 21 | Guava | Leaves | AgNO3 | 56.1 nm | Ag-ZnO NPs | Solar light | MB | 98–60 min | 6 runs | [55] |
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