Research Article

Thermodynamics of Silicon Nanowire Growth under Unintended Oxidation of Catalytic Particles

Table 1

Values of the logarithm of the equilibrium partial pressure of O2 (dissociation pressure) for some synthesis reactions of the oxides of the metal catalysts for Si NW growth (per 1 mol of O2) [8].


Metals with Keq> 1, see equation (11), are shown above of the shadowed Si row, while metals with Keq<1 are shown below of the shadowed Si row.