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Research Article | Open Access
T. Krishnakumar, R. Jayaprakash, N. Pinna, A. Donato, N. Donato, G. Micali, G. Neri, "Sb-SnO2-Nanosized-Based Resistive Sensors for NO2 Detection", Journal of Sensors, vol. 2009, Article ID 980965, 7 pages, 2009. https://doi.org/10.1155/2009/980965
Sb-SnO2-Nanosized-Based Resistive Sensors for NO2 Detection
A study over Sb-promoted tin oxide nanopowders for sensing applications is reported. nanopowders pure and promoted with 5 wt% of antimony were prepared by wet chemical methods and widely characterized by TEM, XRD, and XPS techniques. Thick film resistive sensors were fabricated by depositing the synthesized nanopowders by drop-coating on interdigited alumina substrates. The sensing characteristics of the pure and Sb-promoted sensors for the monitoring of trace level of were studied. The response of the sensors to water vapor was also investigated, revealing that Sb acts favorably eliminating the interference of humidity.
Metal oxide semiconductors (MOSs) in the form of highly porous films are widely used in resistive chemical sensors for the monitoring of gaseous species in several applications of technological interest . Tin oxide () is the most used sensing material in commercially sensor devices for toxic gases detection . It is well known that the sensing properties of -based material depend on its chemical and physical characteristics, which are strongly dependent on the preparation conditions, dopant and grain size. This implies that the synthesis of the sensing material is a key step in the preparation of high-performance MOS gas sensors.
powders and films can be prepared by a variety of synthesis methods [3–8]. Furthermore, the electrical and sensing properties of the undoped tin oxide can be modulated by addition of proper amounts of suitable dopants. For example, promoting with antimony, the electrical properties can be enhanced in order to greatly reduce the resistivity of the sensing film [9, 10]. This is particularly advantageous specially at low temperature, because in this temperature interval the electrical resistance of films is generally high and complicates the measurements with conventional instruments.
Grain size reduction is another of the main factors for enhancing the gas sensing properties of semiconducting oxides [11–13]. It is believed that improved sensing technologies can be configured and developed by taking advantage of recent advances in nanosized materials. They are currently receiving a great deal of attention due to their unique physical properties, which derive from their nanometer-scaled sizes. In such materials, for example, the surface-to-bulk ratio is much greater than coarse materials, so that the surface properties become paramount, which makes them particularly appealing in applications, such as gas sensors, where nanosized properties can be exploited. In this regards, pure and promoted nanocrystalline powders have attracted much attention because of their promising applications in practical sensor devices [14, 15].
Aim of this work is to develop a nitrogen dioxide () sensor device based on nanopowders with particularly low cross-sensitivity to humidity. is a major atmospheric pollutants causing acid rains and photochemical smog. Therefore, nowadays the more and more strict regulations on the emission of this toxic gas require fast and accurate detection of at sub-ppm concentration. The development of semiconductor sensors for detecting in air is then strongly demanding. Previous sensor devices based on tin oxide have been described in literature [16–18]. However, humidity effects on these sensors are relevant and can significantly affect performance and cause false alarms.
For this scope here we focused our attention on Sb- nanopowders, with aim to develop a sensor sensitive to nitrogen dioxide at low concentrations and with a humidity-independent character. Results of previous detailed characterizations by XRD, TEM, and XPS of the synthesized nanopowders [19, 20] were taken into account in order to correlate the microstructural properties with the sensing characteristics. Performances of the Sb- sensor were also compared with that of a reference sensor based on nanosized pure powders.
2.1. Nanopowders Synthesis
Reference pure nanopowders were synthesized as follows. A 0.1 M solution of tin(II) chloride in deionized water was prepared. Then pH of the solution was maintained between 7 and 9 using liquid ammonia diluted with water. The resulting precipitate was washed with water until no chlorine ions are detected and further washed with ethanol to remove ions. The resulting precipitate was irradiated at a frequency of 2.45 GHz and power up to 1 kW in a microwave oven for 10 minutes.
The Sb- nanopowders were synthesized by a chemical precipitation technique. The appropriate amount of SbC in order to have a nominal 5 wt% in the Sb- powder was dissolved first in fuming HCl. The resulting clear solution was added dropwise into 0.1 mol SnC·2 (98%, Merck chemicals) of solution using water as solvent. The total solution was stirred for 30 minutes, and aqueous phase ammonia (25%) was added dropwise until the pH of the solution adjusted to 4. Within few seconds a white precipitate was obtained. It was washed with water and ethanol until no chlorine ions were detected and refluxed for 12 hours. The refluxed precipitate was filtered and dried at 120°C in air, and the residue was ground to fine powder in a mortar and pestle.
In order to characterize the thermal behavior of the as prepared and Sb- nanopowders, they were sintered at different temperatures (up to 600°C) in air for 5 hours at a rate of 5°C/minutes. Main characteristics of the nanopowders are reported in Table 1.
2.2. Nanopowders Characterization
XRD measurements were performed on a Bruker AXS D8 Advance instrument using the CuK with wavelength of 1.541 Å. The average crystalline size of the nanoparticle was evaluated using the Scherrer formula where is the mean crystalline size, is a grain shape dependent constant (0.9), is the wavelength of the incident beam, is a Bragg reflection angle, and is the full width half maximum. Transmission Electron Microscopy (TEM), Selected-Area Electron Diffraction (SAED), and Energy Dispersive Spectroscopy (EDS) were recorded on a Technai G20-stwin Higher Resolution Electron Microscope (HRTEM) using an accelerating voltage of 200 kV. The X-Ray Photoelectron Spectroscopy (XPS) analyses have been performed using the PHI ESCA system equipped with an Mg X-ray source ( eV) with a hemispherical analyzer.
2.3. Sensing Tests
Sensors were made by depositing by drop coating films (1–10 m thick) of the nanopowders dispersed in water on alumina substrates ( m) with Pt interdigitated electrodes and a Pt heater located on the backside. A schematic picture of the sensor structure and a photo of one fabricated sensor device are reported in Figure 1. The sensors were then introduced in a stainless-steel test chamber for the sensing tests. The experimental bench for the electrical characterization of the sensors (Figure 2) allows to carry out measurements in controlled atmosphere. Gases coming from certified bottles can be further diluted in air at a given concentration by mass flow controllers. Electrical measurements were carried out in the temperature range from 50 to 250°C, with steps of 50°C, under a dry air total stream of 200 sccm, collecting the sensors resistance data in the four-point mode. A multimeter data acquisition unit Agilent 34970A was used for this purpose, while a dual-channel power supplier instrument Agilent E3632A was employed to bias the built-in heater of the sensor to perform measurements at superambient temperatures.
The gas response, , is defined as where is the electrical resistance of the sensor at different concentrations in dry air and the resistance in dry air.
Humidity tests were carried out in the range of 0%–100% RH. The different RH values were obtained by mixing dry and wet air (coming from a bubbler maintained at 20°C) into opportune volumetric ratios.
3. Results and Discussion
3.1. Microstructural Characterization
A detailed characterization of the nanopowders under study has been reported elsewhere [19, 20]. Here we recall briefly some data important for the present application. The analyses carried out on the “as prepared” materials showed that the main crystalline phase is SnO. Increasing the calcination temperature, the microstructure evolved stably up to . The pure sample sintered at 600°C showed typical tetragonal Cassiterite reflections, with the calculated lattice parameters of tin oxide nanoparticles ( nm, nm) in good agreement with the standard values ( nm, nm). The average particle size, as estimated from XRD measurements, increases slightly with the treatment temperature (from 26 to 30 nm after calcination at 600°C).
Similar findings have been found on the Sb-promoted tin oxide nanopowders. On the sample sintered at 600°C, XRD analysis (Figure 3) indicated the existence of tetragonal Cassiterite type of Sb-substituted crystals, implying that all antimony ions came into the crystal lattice of bulk to substitute for tin ions. Calculation through the Scherrer formula indicated that the average particle size of 5 wt% antimony promoted tin oxide powder sintered at 600°C is in the range of 20 nm.
Typical morphology of the Sb-promoted tin oxide nanopowders treated at high temperature (600°C) is shown in the TEM micrograph in Figure 4. The corresponding SAED pattern is also reported in the insert. The particle size estimated from TEM measurements corresponds to the average size (20 nm) evaluatedfrom XRD measurements, suggesting that they should be monocrystalline.
In order to investigate the stoichiometry of the 5 wt% Sb- nanopowders, a detailed XPS analysis has been carried out. At this concentration of antimony, the component was found to be dominant with only a small amount of content . Due to the substitution of ion by replacing ion, the donor center was appeared very close to the conduction band of ; that is, donor level was merging with conduction band. This has reflected a decrease in the resistance of the sample.
From characterization data above reported and summarized in Table 1, it can be deduced that crystalline characteristics of were not affected by promoter addition. On the contrary, the grain size was largely dependent on the addition of Sb. Thus, the Sb-promoted powders have presented lower grain size with respect to the unpromoted one. This is in agreement with results reported by other authors . Even if an absolute comparison cannot be made because the samples derive from different preparation methods, this behavior can be explained by the blocking effect of the Sb atoms on the grains growth.
3.2. Sensing Tests
To perform sensing tests, sensor devices were fabricated depositing by drop coating the synthesized nanopowders on interdigited alumina substrates, as described in the experimental section. The as synthesized and Sb- nanopowders resulted particularly suitable for deposition without the use of any further additive. After the sensing layer was deposited on the ceramic substrate, a high-temperature treatment was performed in order to stabilize the film microstructure.
Electrical measurements have shown, as expected, that the baseline resistance of Sb-promoted sensor in air is lower than measured for the pure -based sensor. A low resistance of the sensing layer is a favorable factor implying a low noise in the measurement of the resistance and consequently a high signal/noise ratio. The low resistance of the Sb- film can be explained considering that is a metal oxide with -type semiconducting behavior. In the presence of , the conductivity increase can be due to the formation of holes.
Figure 5 shows a typical transient response to different concentrations obtained with the Sb- sensor operated at 200°C. The sensing layer was in this case pretreated at 300°C. The responses are fast and reversible. The response time, , defined here as the time it takes for the resistance of the gas sensor to decrease to 90% of the minimum resistance when is introduced into air, is fast ( seconds). The recovery time, , the time required for 90% increment in resistance when is turned off and air is reintroduced into the chamber, is instead longer. The response of the sensor correlate linearly with the concentration of the gas target (Figure 6). The good response to 0.8 ppm of indicates the promising performance of the sensor for the detection of sub-ppm concentrations of nitrogen dioxide in air.
Tests carried out with sensing layer treated at higher temperatures have shown that the response slightly decreases. This can be attributed to a loss of surface area consequently to grain size increment. However, treatment temperature at least up to 400°C is necessary in order to stabilize the microstructure of the sensing layer, its grain size, and the adhesion to the substrate. Indeed, after thermal treatment, the adhesion of the sensing layer to the alumina substrate was found to be very tight and durable to stretch. Therefore, further sensing tests have been carried out with pretreatment temperature of 400°C.
Tests aimed to find the optimal operating temperature of the sensors for monitoring are reported in Figure 7. The operative range investigated was between 200 and 400°C. The lower limit was related to the necessity to provide an adequate fast response/recovery time. At all operating temperatures, the pure sensor showed a larger response compared to Sb-promoted sensor. It was also observed that at operating temperature higher than 300°C the sensor response is lower than 1 (i.e., the resistance in nitrogen dioxide is lower that registered in air). This can be explained on the basis of a transition from - to -type response, as observed for different metal oxide semiconductors exposed to various gases , leading in our case to an inverse response above 300°C. A more detailed investigation is however necessary in order to better understand the above observed behavior.
Taking into account all sensing characteristics (sensitivity, response/recovery time) and power consumption, the working temperature of 200°C provides the better opportunity for the sensor operation. Despite antimony addition worsens the response toward , it acts favorably eliminating the interference of humidity. In this regard, analyzing the response to different mixtures of and RH, no influence of the water vapor on the sensor response was observed.
3.3. Humidity Tests
It is well known that tin dioxide sensors are generally sensitive to humidity . In order to understand the effects of water on the sensing characteristics of Sb- nanopowders, it is necessary to recall in brief the behavior of molecules adsorbed on the surface of metal oxide semiconductors. Water is a donor type molecule and giving one electron to the bulk becomes positively charged, and this leads to the formation of a negative space charge region; moreover, the adsorbed water molecules can dissociate into hydroxyl groups . At low temperature this latter mechanism is slower than previous, but it gains importance increasing the temperature. In any case, humidity interferes with sensor operation because these mechanisms can lead to remarkable temporary or irreversible change in the sensor resistance with time (drift), complicating the detection of the gas target .
For accurate and reliable detection with our devices, it is then necessary to observe what effects relative humidity has upon the selective detection of gas. Therefore, an experimentation with various RH concentrations was carried out to examine the effects of relative humidity on pure and Sb-promoted devices. Results collected in all ranges of temperature investigated have shown that the sensor resistance decreases as RH increases. As an example, the dynamic response of the sensors at the operating temperature of 200°C to step changes in relative humidity levels is reported in Figure 8. The magnitude of signal increases with increasing RH, as reported in Figure 9 for both sensors investigated. It can be observed that the response to humidity is higher for the -based sensor. This could be due to a different texture (in terms of surface area, pore size distribution, etc.) between the two sensing layers. Interestingly, this leads on the Sb-promoted device to a water response almost negligible. Therefore, it can be concluded that water vapor affects less the Sb-doped sensor, and this is advantageous because of the consequent stability of the sensor against ambient humidity fluctuations under practical working conditions for monitoring.
nanopowders pure and promoted with 5 wt% of antimony were prepared by wet chemical methods and widely characterized by SEM, TEM, XRD, and XPS techniques.
The sensing characteristics of thick film resistive sensors fabricated by the pure - and Sb-promoted sensors for the monitoring of trace level of were studied. The attention was focused on the Sb-promoted tin oxide film, which has shown interesting properties as sensor. Indeed, besides it resulted less sensitive to gas target with respect to the sensor, its sensing properties are not influenced by humidity. By optimizing the operating conditions, an sensor with good sensitivity and negligible water influence has been developed.
- N. Yamazoe, “Toward innovations of gas sensor technology,” Sensors and Actuators B, vol. 108, no. 1-2, pp. 2–14, 2005.
- K. Takahata, Tin Dioxide Sensors—Development and Applications. Chemical Sensor Technology, vol. 1, Elsevier, Amsterdam, The Netherlands, 1988.
- N. S. Baik, G. Sakai, N. Miura, and N. Yamozoe, “Hydrothermally treated sol solution of tin oxide for thin-film gas sensor,” Sensors and Actuators B, vol. 63, pp. 74–79, 2000.
- Z. Han, N. Guo, F. Li, W. Zhang, H. Zhao, and Y. Qian, “Solvothermal preparation and morphological evolution of stannous oxide powders,” Materials Letters, vol. 48, no. 2, pp. 99–103, 2001.
- K. C. Song and J. H. Kim, “Synthesis of high surface area tin oxide powders via water-in-oil microemulsions,” Powder Technology, vol. 107, no. 3, pp. 268–272, 2000.
- C. H. Shek, J. K. L. Lai, and G. M. Lin, “Grain growth in nanocrystalline prepared by sol-gel route,” Nanostructured Materials, vol. 11, no. 7, pp. 887–893, 1999.
- D. Briand, M. Labeau, J. F. Currie, and G. Delabouglise, “Pd-doped thin films deposited by assisted ultrasonic spraying CVD for gas sensing: selectivity and effect of annealing,” Sensors and Actuators B, vol. 48, no. 1–3, pp. 395–402, 1998.
- N. Pinna and M. Niederberger, “Surfactant-free nonaqueous synthesis of metal oxide nanostructures,” Angewandte Chemie International Edition, vol. 47, no. 29, pp. 5292–5304, 2008.
- D. Zhang, Z. Deng, J. Zhang, and L. Chen, “Microstructure and electrical properties of antimony-doped tin oxide thin film deposited by sol-gel process,” Materials Chemistry and Physics, vol. 98, no. 2-3, pp. 353–357, 2006.
- S.-Y. Lee and B.-O. Park, “Structural, electrical and optical characteristics of :Sb thin films by ultrasonic spray pyrolysis,” Thin Solid Films, vol. 510, no. 1-2, pp. 154–158, 2006.
- C. Xu, J. Tamaki, N. Miura, and N. Yamazoe, “Grain size effects on gas sensitivity of porous -based elements,” Sensors and Actuators B, vol. 3, no. 2, pp. 147–155, 1991.
- S. G. Ansari, P. Boroojerdian, S. R. Sainkar, R. N. Karekar, R. C. Aiyer, and S. K. Kulkarni, “Grain size effects on gas sensitivity of thick film resistor using nanoparticles,” Thin Solid Films, vol. 295, no. 1-2, pp. 271–276, 1997.
- G. Korotcenkov, “Gas response control through structural and chemical modification of metal oxide films: state of the art and approaches,” Sensors and Actuators B, vol. 107, no. 1, pp. 209–232, 2005.
- N. Pinna, G. Neri, M. Antonietti, and M. Niederberger, “Nonaqueous synthesis of nanocrystalline semiconducting metal oxides for gas sensing,” Angewandte Chemie International Edition, vol. 43, no. 33, pp. 4345–4349, 2004.
- G. Neri, A. Bonavita, G. Rizzo et al., “Towards enhanced performances in gas sensing: based nanocrystalline oxides application,” Sensors and Actuators B, vol. 122, no. 2, pp. 564–571, 2007.
- M. M. H. Bhuiyan, S. Katsuki, T. Ueda, and T. Ikegami, “Improvement in the sensitivity of thin film based gas sensor by loading with single-walled carbon nanotube prepared by pulsed laser deposition process,” Sensor Letters, vol. 6, no. 4, pp. 635–640, 2008.
- F. J. Gutierrez, L. Ares, J. I. Robla et al., “ tin dioxide sensors activities, as a function of doped materials and temperature,” Sensors and Actuators B, vol. 16, no. 1–3, pp. 354–356, 1993.
- G. Williams and G. S. V. Coles, “ response of tin dioxide based gas sensors,” Sensors and Actuators B, vol. 16, no. 1–3, pp. 349–353, 1993.
- T. Krishnakumar, N. Pinna, K. P. Kumari, K. Perumal, and R. Jayaprakash, “Microwave-assisted synthesis and characterization of tin oxide nanoparticles,” Materials Letters, vol. 62, no. 19, pp. 3437–3440, 2008.
- T. Krishnakumar, R. Jayaprakash, N. Pinna, A. R. Phani, M. Passacantando, and S. Santucci, “Structural, optical and electrical characterization of antimony-substituted tin oxide nanoparticles,” Journal of Physics and Chemistry of Solids, vol. 70, pp. 993–999, 2009.
- E. C. P. E. Rodrigues and P. Olivi, “Preparation and characterization of Sb-doped films with controlled stoichiometry from polymeric precursors,” Journal of Physics and Chemistry of Solids, vol. 64, no. 7, pp. 1105–1112, 2003.
- T. Siciliano, A. Tepore, G. Micocci, A. Genga, M. Siciliano, and E. Filippo, “Transition from n- to p-type electrical conductivity induced by ethanol adsorption on α-tellurium dioxide nanowires,” Sensors and Actuators B, vol. 138, no. 1, pp. 207–213, 2009.
- M. Batzill and U. Diebold, “The surface and materials science of tin oxide,” Progress in Surface Science, vol. 79, no. 2–4, pp. 47–154, 2005.
- F. Réti, M. Fleischer, J. Gerblinger et al., “Comparison of the water effect on the resistance of different semiconducting metal oxides,” Sensors and Actuators B, vol. 26, no. 1–3, pp. 103–107, 1995.
- N. Bârsan and R. Ionescu, “The mechanism of the interaction between CO and an surface: the role of water vapour,” Sensors and Actuators B, vol. 12, no. 1, pp. 71–75, 1993.
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