Journal of Spectroscopy

Journal of Spectroscopy / 2003 / Article

Open Access

Volume 17 |Article ID 209713 | https://doi.org/10.1155/2003/209713

Christopher K. Jankowski, Antoun Bou Laouz, Denis Lesage, Eduardo Diaz T., "Unusual Rearrangement of Dihalocyclopropanes", Journal of Spectroscopy, vol. 17, Article ID 209713, 11 pages, 2003. https://doi.org/10.1155/2003/209713

Unusual Rearrangement of Dihalocyclopropanes

Abstract

Dihalocyclopropanation of the double bond of some olefins, leading to dihalocyclopropanes, offered an opportunity to perform their rearrangement to dihalomethylvinyl with Hiyama type reagents, in presence of cationic system such as Cr2+/Cr3+. The chain elongation of alkenes via the gem‒dihalocyclopropanes produced α,β–unsaturated aldehydes and acids.

Copyright © 2003 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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