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Spectroscopy
Volume 18 (2004), Issue 1, Pages 113-119
http://dx.doi.org/10.1155/2004/309130

Solid state NMR study of 1,3imidazolidine-2-thione, 1,3-imidazolidine-2-selenone and some of their N-substituted derivatives

Mohamed I. M. Wazeer, Anvarhusein A. Isab, and Ali El-Rayyes

Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran-31261, Saudi Arabia

Copyright © 2004 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Solid‒state NMR spectra were recorded for 1,3-imidazolidine-2-thione, 1,3-imidazolidine-2-selenone and some of their N-substituted derivatives. Spinning side-bands of thione and selenone carbons were analysed to yield chemical shift anisotropies for these carbons. The NMR spectrum of imidazolidine-2-thione (Imt) showed some evidence for the presence of thiol tautomer. Molecular computations were carried out for Imt and its N-methyl derivative to yield relative energies of various tautomers.