Synthesis, Characterization, and Photochemical Properties of a New Square Mn(I)-Ru(II) Complex Using Pyrazine as Bridge Ligand

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</svg></td><td align="center"><i>ν</i>CO cm<sup>−1</sup></td><td align="center"><svg height="16.424999" id="M24" style="vertical-align:-3.37158pt" version="1.1" viewbox="0 0 30.775 16.424999" width="30.775" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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</svg>)</td></tr><tr><td class="thead-hr" colspan="4"><hr/></td></tr><tr><td align="left" rowspan="2">Complex <b>I</b></td><td align="center">1.10</td><td align="center" rowspan="2">2032, 1938</td><td align="center">394 (11500);</td></tr><tr><td align="center">0.79/0.73</td><td align="center">442 (10400) </td></tr><tr><td align="left" rowspan="2">Complex <b>II</b></td><td align="center" rowspan="2">1.56/1.49</td><td align="center" rowspan="2">—</td><td align="center">394 (9100)</td></tr><tr><td align="center">425 (8000) </td></tr><tr><td align="left" rowspan="2">Complex <b>III</b></td><td align="center">1.10</td><td align="center" rowspan="2">2041, 1953, 1932</td><td align="center" rowspan="2">381 (2900)</td></tr><tr><td align="center">0.87/0.89</td></tr><tr class="table-tr"><td colspan="4"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Electrochemistry properties of complexes <b>I</b>, <b>II,</b> and <b>III</b> in CH<sub>3</sub>CN.

Journal of Spectroscopy

tab2

Table 2

Table 2: Synthesis, Characterization, and Photochemical Properties of a New Square Mn(I)-Ru(II) Complex Using Pyrazine as Bridge Ligand 