Research Article

Synthesis, Spectroscopy, Theoretical, and Electrochemical Studies of Zn(II), Cd(II), and Hg(II) Azide and Thiocyanate Complexes of a New Symmetric Schiff-Base Ligand

Table 3

Electrochemical data of ligand and complexes.

Compounds ( ), ( ) ( )

L−0.78 (−0.70), −1.54 (−1.47)−0.08−0.07−0.63 (−0.71)
ZnL(NCS)2−0.76 (−0.67), −1.57 (−1.49)−0.09−0.13−0.59 (−0.68)
ZnL(N3)2−0.73 (−0.62), −1.50 (−1.44)−0.09−0.06−0.57 (−0.66)
CdL(SCN)(NCS)−0.86 (−0.75)−0.09−0.61 (−0.74)
CdL(N3)2−0.77 (−0.67)−0.1−0.57 (−0.71)
HgL(SCN)2−0.93 (−0.82)−0.09−0.72 (−0.83)
HgL(N3)2−0.90 (−0.78)−0.12−0.70 (−0.82)

a ; b .