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Journal of Spectroscopy
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Journal of Spectroscopy
/
2013
/
Article
/
Tab 3
/
Research Article
Synthesis, Spectroscopy, Theoretical, and Electrochemical Studies of Zn(II), Cd(II), and Hg(II) Azide and Thiocyanate Complexes of a New Symmetric Schiff-Base Ligand
Table 3
Electrochemical data of ligand and complexes.
Compounds
(
),
(
)
(
)
L
−0.78 (−0.70), −1.54 (−1.47)
−0.08
−0.07
−0.63 (−0.71)
ZnL(NCS)
2
−0.76 (−0.67), −1.57 (−1.49)
−0.09
−0.13
−0.59 (−0.68)
ZnL(N
3
)
2
−0.73 (−0.62), −1.50 (−1.44)
−0.09
−0.06
−0.57 (−0.66)
CdL(SCN)(NCS)
−0.86 (−0.75)
−0.09
—
−0.61 (−0.74)
CdL(N
3
)
2
−0.77 (−0.67)
−0.1
—
−0.57 (−0.71)
HgL(SCN)
2
−0.93 (−0.82)
−0.09
—
−0.72 (−0.83)
HgL(N
3
)
2
−0.90 (−0.78)
−0.12
—
−0.70 (−0.82)
a
;
b
.