Review Article

Spectroscopic Characterization of Poly(ortho-Aminophenol) Film Electrodes: A Review Article

Table 1

Electropolymerization of o-aminophenol on different electrode materials and in different electrolyte media.

Electrode materialsElectrolyte mediumElectrosynthesis methodReference

Pt, Au and glassy carbon0.1 M HClO4 + 0.4 M NaClO4 +  M o-AP (1 < pH < 7)Potentiodynamic cycling
−0.25 V and 0.70 V (SCE)
[1]

Pt electrode0.4 mol cm−3 of NaClO4 + 10−2 mol dm−3 of o-AP Potentiodynamic cycling
−0.25 V and 0.75 V (SCE)
[2]

Carbon paste electrode5 mM o-AP + 0.5 M HClO4
In the presence and in the absence of sodium dodecyl sulfate
Potentiodynamic cycling
−0.1 V and 0.7 V (Ag/AgCl/KCl 3 M)
[3]

Platinum and glassy carbon electrodes 0.2 M NaClO4 + 0.1 M HClO4 + 5 10−3 M o-AP solutionPotentiodynamic cycling
0.2 V and 1.3 V (RHE)
[4]

Glassy carbon electrodes chemically (nitric acid (67% wt/wt) and sulfuric acid (98% wt./wt) for 10 min) and electrochemically (1.85 V (SCE) for 5 min) pretreated before electropolymerization of o-AP 0.1 M H2SO4 + 0.05 M o-APPotentiodynamic method (−0.2 V and 0.7 V versus SCE)
[5]

Basal-plane pyrolytic graphite and In-Sn oxide conducting glass 0.5 M Na2SO4 solution (pH 1) + 50 mM o-AP Potentiodynamic cycling (−0.4 and 1.0 V versus sodium chloride saturated calomel electrode )[6]

Glassy carbon1 M SO4H2 + 0.5 M Na2SO4 + 50 mM o-AP solution Potentiodynamic cycling (−0.2 V and 1.0 V versus SCE)[7]

Glassy carbon and Pt electrodes0.05 M o-AP in a mixture of 1 M H2SO4 and 0.5 M Na2SO4Potentiodynamic cycling (−0.2 V to 0.8 V versus SCE)[8]

Pt and Au electrodes0.05 M o-AP + 0.5 M H2SO4 solutionPotentiostatic method (  V; 0.8 V and 0.9 V versus SCE[9]

Pt and GC electrodes0.05 M o-aminophenol solution in 0.5 M HClO4 + 10 mM sulfonated nickel phtalocyaninePotentiodynamic cycling (–0.25 and 0.7 V versus SCE)[10]

GC electrodes
0.10 M HClO4 + 0.10 M o-APPotentiodynamic (−0.10 V and 1.00 V versus SCE) and potentiostatic (  V for a given time) methods [11]

Vitreous carbon, platinum, and copper
0.3 M NaOH hydroalcoholic solution (70 vol% H2O, 30 vol% CH3OH) + 0.1 M o-APPotentiodynamic cycling[12]

Glassy carbon electrode or on a glass plate covered with semiconducting indium thin oxide 1 M phosphate buffer solution (pH 5.55) containing 25  g/mL of laccase and 10 mM o-APPotentiodynamic cycling (−0.1 V and 0.9 V versus Ag/AgCl)[13]