¹H, ¹³C, and ¹⁵N NMR Studies of Au(III) and Pd(II) Chloride Complexes and Organometallics with 2-Acetylpyridine and 2-Benzoylpyridine

Table 3

¹⁵N chemical and coordination/protonation shifts (in parentheses) for Au(III) and Pd(II) chloride complexes, organometallics, and salts with 2apy or 2bz′py.

Compound	N(1)
2apy^DMSO-d6	−62.4
[Au(2apy*)Cl2]^DMSO-d6	−156.5(−94.1)
2bz′py^CDCl3	−61.4
2bz′py^DMSO-d6	−60.3
2bz′py^CD3CN	−60.3
[Au(2bz′py)Cl3]^CDCl3	−148.7(−87.3)
trans- [Pd(2bz′py)2Cl2]^CDCl3	−164.9(−103.5)
[Au(2bz′py*)Cl2]^DMSO-d6	−165.0(−104.7)
(2bz′pyH)[AuCl4]^CD3CN	−171.4(−111.1)