Research Article

EIS Evaluation of Fe, Cr, and Ni in NaVO3 at 700°C

Table 2

Chemical reactions and equilibrium constants for the Cr-Na-V-O system at 700°C.

NumberReaction K

14 = 2 V2O4(s) + 2 Na2O(s) + O2−39.7131
2 = + Na2O(s)−10.1885
32 = V2O3(s) + 3 Na2O(s) + O2−47.6241
42 = V2O3(s) + Na2O(s) + O2−27.2471
52 V2O3(s) + O2 = 2 V2O4(s)14.7810
62 + Na2O(s) = Cr2O3(s) + 2 16.7790
72 + 2 V2O4(s) + O2 = 4 6.15498