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Journal of Spectroscopy
Volume 2015, Article ID 329730, 7 pages
http://dx.doi.org/10.1155/2015/329730
Research Article

Raman Spectroscopy and Electrochemical Investigations of Pt Electrocatalyst Supported on Carbon Prepared through Plasma Pyrolysis of Natural Gas

1Departamento de Química, Centro de Ciências Exatas, UFES, Avenida Fernando Ferrari, 514 Goiabeiras, 29075-910 Vitória, ES, Brazil
2Departamento de Morfologia, Centro de Ciências da Saúde, UFES, Campus de Maruípe, 29049-999 Vitória, ES, Brazil

Received 17 March 2015; Revised 8 July 2015; Accepted 15 July 2015

Academic Editor: Christophe Dujardin

Copyright © 2015 Tereza Cristina Santos Evangelista et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. U.S. Department of Energy. Office of Fossil Energy. National Energy Technology Laboratory, Fuel Cell Handbook, EG&G Technical Services, 7th edition, 2004.
  2. T. Iwasita, “Fuel cells: Spectroscopic studies in the electrocatalysis of alcohol oxidation,” Journal of the Brazilian Chemical Society, vol. 13, no. 4, pp. 401–409, 2002. View at Publisher · View at Google Scholar · View at Scopus
  3. D. Wang, J. Liu, Z. Wu et al., “Electrooxidation of methanol, ethanol and 1-propanol on pd electrode in alkaline medium,” International Journal of Electrochemical Science, vol. 4, no. 12, pp. 1672–1678, 2009. View at Google Scholar · View at Scopus
  4. L. C. Basso, H. V. de Amorim, A. J. de Oliveira, and M. L. Lopes, “Yeast selection for fuel ethanol production in Brazil,” FEMS Yeast Research, vol. 8, no. 7, pp. 1155–1163, 2008. View at Publisher · View at Google Scholar · View at Scopus
  5. S. K. Meher and G. R. Rao, “Morphology-controlled promoting activity of nanostructured MnO2 for methanol and ethanol electrooxidation on Pt/C,” Journal of Physical Chemistry C, vol. 117, no. 10, pp. 4888–4900, 2013. View at Publisher · View at Google Scholar · View at Scopus
  6. X. S. Zhao, W. Z. Li, L. H. Jiang et al., “Multi-wall carbon nanotube supported Pt–Sn nanoparticles as an anode catalyst for the direct ethanol fuel cell,” Carbon, vol. 42, no. 15, pp. 3263–3265, 2004. View at Publisher · View at Google Scholar · View at Scopus
  7. E. J. Yoo, T. Okata, T. Akita, M. Kohyama, J. Nakamura, and I. Honma, “Enhanced electrocatalytic activity of Pt subnanoclusters on graphene nanosheet surface,” Nano Letters, vol. 9, no. 6, pp. 2255–2259, 2009. View at Publisher · View at Google Scholar · View at Scopus
  8. H. Wu, D. Wexler, and H. Liu, “Pt-Ni/C catalysts using different carbon supports for the cathode of the proton exchange membrane fuel cell (PEMFC),” Materials Chemistry and Physics, vol. 136, no. 2-3, pp. 845–849, 2012. View at Publisher · View at Google Scholar · View at Scopus
  9. S. Tang, G. Sun, J. Qi et al., “New carbon materials as catalyst supports in direct alcohol fuel cells,” Chinese Journal of Catalysis, vol. 31, no. 1, pp. 12–17, 2010. View at Publisher · View at Google Scholar · View at Scopus
  10. Y. Wang, C. He, A. Brouzgou et al., “A facile soft-template synthesis of ordered mesoporous carbon/tungsten carbide composites with high surface area for methanol electrooxidation,” Journal of Power Sources, vol. 200, pp. 8–13, 2012. View at Publisher · View at Google Scholar · View at Scopus
  11. J. C. C. Freitas, D. F. Cipriano, C. G. Zucolotto, A. G. Cunha, and F. Emmerich, “Solid-state NMR study of carbon blacks obtained by plasma pyrolysis of natural gas,” in Proceedings of the Annual World Conference on Carbon, Krakow, Poland, 2012.
  12. L. Fulcheri and Y. Schwob, “From methane to hydrogen, carbon black and water,” International Journal of Hydrogen Energy, vol. 20, no. 3, pp. 197–202, 1995. View at Publisher · View at Google Scholar · View at Scopus
  13. J. R. Fincke, R. P. Anderson, T. A. Hyde, and B. A. Detering, “Plasma pyrolysis of methane to hydrogen and carbon black,” Industrial and Engineering Chemistry Research, vol. 41, no. 6, pp. 1425–1435, 2002. View at Publisher · View at Google Scholar · View at Scopus
  14. P. E. Dodds, I. Staffell, A. D. Hawkes et al., “Hydrogen and fuel cell technologies for heating: a review,” International Journal of Hydrogen Energy, vol. 40, no. 5, pp. 2065–2083, 2015. View at Publisher · View at Google Scholar · View at Scopus
  15. E. Antolini and E. R. Gonzalez, “The electro-oxidation of carbon monoxide, hydrogen/carbon monoxide and methanol in acid medium on Pt-Sn catalysts for low-temperature fuel cells: a comparative review of the effect of Pt-Sn structural characteristics,” Electrochimica Acta, vol. 56, no. 1, pp. 1–14, 2010. View at Publisher · View at Google Scholar · View at Scopus
  16. F. L. S. Purgato, L. A. Montoro, J. Ribeiro, K. B. Kokoh, and P. Olivi, “The effect of heat treatment on the preparation of Pt-RuO2/C electrocatalysts,” Electrocatalysis, vol. 1, no. 2-3, pp. 122–128, 2010. View at Publisher · View at Google Scholar · View at Scopus
  17. L. Li and Y. Xing, “Pt-Ru nanoparticles supported on carbon nanotubes as methanol fuel cell catalysts,” Journal of Physical Chemistry C, vol. 111, no. 6, pp. 2803–2808, 2007. View at Publisher · View at Google Scholar · View at Scopus
  18. S. S. Gupta and J. Datta, “A comparative study on ethanol oxidation behavior at Pt and PtRh electrodeposits,” Journal of Electroanalytical Chemistry, vol. 594, no. 1, pp. 65–72, 2006. View at Publisher · View at Google Scholar · View at Scopus
  19. A. Brouzgou, S. Q. Song, and P. Tsiakaras, “Low and non-platinum electrocatalysts for PEMFCs: current status, challenges and prospects,” Applied Catalysis B: Environmental, vol. 127, pp. 371–388, 2012. View at Publisher · View at Google Scholar · View at Scopus
  20. A. Serov and C. Kwak, “Recent achievements in direct ethylene glycol fuel cells (DEGFC),” Applied Catalysis B: Environmental, vol. 97, no. 1-2, pp. 1–12, 2010. View at Publisher · View at Google Scholar · View at Scopus
  21. F. E. Teran, D. M. Santos, J. Ribeiro, and K. B. Kokoh, “Activity of PtSnRh/C nanoparticles for the electrooxidation of C1 and C2 alcohols,” Thin Solid Films, vol. 520, no. 18, pp. 5846–5850, 2012. View at Publisher · View at Google Scholar · View at Scopus
  22. A. Serov and C. Kwak, “Progress in development of direct dimethyl ether fuel cells,” Applied Catalysis B: Environmental, vol. 91, no. 1-2, pp. 1–10, 2009. View at Publisher · View at Google Scholar · View at Scopus
  23. I. Mizutani, Y. Liu, S. Mitsushima, K.-I. Ota, and N. Kamiya, “Anode reaction mechanism and crossover in direct dimethyl ether fuel cell,” Journal of Power Sources, vol. 156, no. 2, pp. 183–189, 2006. View at Publisher · View at Google Scholar · View at Scopus
  24. X. Zhang, H. Zhu, Z. Guo, Y. Wei, and F. Wang, “Design and preparation of CNT@SnO2 core-shell composites with thin shell and its application for ethanol oxidation,” International Journal of Hydrogen Energy, vol. 35, no. 17, pp. 8841–8847, 2010. View at Publisher · View at Google Scholar
  25. W.-P. Zhou, M. Li, C. Koenigsmann, C. Ma, S. S. Wong, and R. R. Adzic, “Morphology-dependent activity of Pt nanocatalysts for ethanol oxidation in acidic media: nanowires versus nanoparticles,” Electrochimica Acta, vol. 56, no. 27, pp. 9824–9830, 2011. View at Publisher · View at Google Scholar · View at Scopus
  26. A. R. Bonesi, M. S. Moreno, W. E. Triaca, and A. M. C. Luna, “Modified catalytic materials for ethanol oxidation,” International Journal of Hydrogen Energy, vol. 35, no. 11, pp. 5999–6004, 2010. View at Publisher · View at Google Scholar · View at Scopus
  27. F. Kadirgan, S. Beyhan, and T. Atilan, “Preparation and characterization of nano-sized Pt-Pd/C catalysts and comparison of their electro-activity toward methanol and ethanol oxidation,” International Journal of Hydrogen Energy, vol. 34, no. 10, pp. 4312–4320, 2009. View at Publisher · View at Google Scholar · View at Scopus
  28. D. Cullity and S. R. Stock, Elements of X-Ray Diffraction, Prentice Hall, Upper Saddle River, NJ, USA, 3rd edition, 2001.
  29. Powder Diffraction File: 01-087-0646, vol. PDF-2, Joint Committee on Powder Diffraction Standards, International Center for Diffraction Data, Newtown Square, Pa, USA, 2011.
  30. R. Escribano, J. J. Sloan, N. Siddique, N. Sze, and T. Dudev, “Raman spectroscopy of carbon-containing particles,” Vibrational Spectroscopy, vol. 26, no. 2, pp. 179–186, 2001. View at Publisher · View at Google Scholar · View at Scopus
  31. F. Tunistra and J. L. Koenig, “Raman spectrum of graphite,” The Journal of Chemical Physics, vol. 53, no. 3, pp. 1126–1130, 1970. View at Publisher · View at Google Scholar
  32. R. S. Das and Y. K. Agrawal, “Raman spectroscopy: recent advancements, techniques and applications,” Vibrational Spectroscopy, vol. 57, no. 2, pp. 163–176, 2011. View at Publisher · View at Google Scholar · View at Scopus
  33. A. C. Ferrari and J. Robertson, “Interpretation of Raman spectra of disordered and amorphous carbon,” Physical Review B, vol. 61, no. 20, pp. 14095–14107, 2000. View at Publisher · View at Google Scholar · View at Scopus
  34. A. C. Ferrari, J. C. Meyer, V. Scardaci et al., “Raman spectrum of graphene and graphene layers,” Physical Review Letters, vol. 97, no. 18, Article ID 187401, 2006. View at Publisher · View at Google Scholar · View at Scopus
  35. J. Ribeiro, D. M. dos Anjos, K. B. Kokoh et al., “Carbon-supported ternary PtSnIr catalysts for direct ethanol fuel cell,” Electrochimica Acta, vol. 52, no. 24, pp. 6997–7006, 2007. View at Publisher · View at Google Scholar · View at Scopus
  36. D. J. Tarnowski and C. Korzeniewski, “Effects of surface step density on the electrochemical oxidation of ethanol to acetic acid,” Journal of Physical Chemistry B, vol. 101, no. 2, pp. 253–258, 1997. View at Publisher · View at Google Scholar · View at Scopus
  37. A. A. Abd-El-Latif, E. Mostafa, S. Huxter, G. Attard, and H. Baltruschat, “Electrooxidation of ethanol at polycrystalline and platinum stepped single crystals: a study by differential electrochemical mass spectrometry,” Electrochimica Acta, vol. 55, no. 27, pp. 7951–7960, 2010. View at Publisher · View at Google Scholar · View at Scopus
  38. Z.-Y. Zhou, Z.-Z. Huang, D.-J. Chen, Q. Wang, N. Tian, and S.-G. Sun, “High-index faceted platinum nanocrystals supported on carbon black as highly efficient catalysts for ethanol electrooxidation,” Angewandte Chemie—International Edition, vol. 49, no. 2, pp. 411–414, 2010. View at Publisher · View at Google Scholar · View at Scopus
  39. S. Singh and J. Datta, “Kinetic investigations and product analysis for optimizing platinum loading in direct ethanol fuel cell (DEFC) electrodes,” Ionics, vol. 17, no. 9, pp. 785–798, 2011. View at Publisher · View at Google Scholar · View at Scopus
  40. M. L. Calegaro, H. B. Suffredini, S. A. S. Machado, and L. A. Avaca, “Preparation, characterization and utilization of a new electrocatalyst for ethanol oxidation obtained by the sol-gel method,” Journal of Power Sources, vol. 156, no. 2, pp. 300–305, 2006. View at Publisher · View at Google Scholar · View at Scopus