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Journal of Spectroscopy
Volume 2016, Article ID 8084301, 7 pages
Research Article

Fabrication and Crystallization of ZnO-SLS Glass Derived Willemite Glass-Ceramics as a Potential Material for Optics Applications

1Department of Physics, Faculty of Science, Universiti Putra Malaysia (UPM), 43400 Serdang, Selangor, Malaysia
2Materials Synthesis and Characterization Laboratory, Institute of Advanced Technology, Universiti Putra Malaysia (UPM), 43400 Serdang, Selangor, Malaysia

Received 29 October 2015; Revised 3 January 2016; Accepted 6 January 2016

Academic Editor: Austin Nevin

Copyright © 2016 Mohd Hafiz Mohd Zaid et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Willemite glass-ceramics were successfully derived from conventional melt-quench ZnO-SLS precursor glass by an isothermal heat treatment process. The effect of heat treatment temperatures on the physical properties was investigated by Archimedes principle and linear shrinkage. The generation of willemite crystal phase and morphology with increase in heat treatment temperature was examined by X-ray diffraction (XRD), Fourier transform infrared (FTIR), and field emission scanning electron microscopy (FESEM) techniques. X-ray diffraction revealed that the metastable -Zn2SiO4 and thermodynamically stable zinc orthosilicate α-Zn2SiO4 phases can be observed at temperatures above 700°C. The experimental results indicated that the density and shrinkage of the glass-ceramic vary with increasing the sintering temperature. FTIR studies showed that the structure of glass-ceramic consists of SiO2 and ZnO4 units and exhibits the structural evolution of willemite glass-ceramics. The characteristic of strong vibrational bands can be related to the tetrahedron corresponding to reference spectra of willemite.