Interaction of Fullerenes with Organosilanes in the Ionization Chamber of a Mass Spectrometer under Electron Impact and the Reaction of C₆₀ with Tetraphenylsilane in Solution under UV Irradiation

Table 1

Ions of the main products formed in the reactions of fullerenes with organosilanes in the IC of a mass spectrometer under EI.

Number	Fullerene	Silane	Method	Ions detected
1	C60	Tetramethyl	A	[HkC60(CH3) (-mH)]^+, = 1–8
	C70	The same	A	[C70CH2], [HC70CH3], [CH2C70CH2], [C70(CH3)2], [HC70(CH2)CH3]^+
2	C60	Diphenyl	A	[C60C6H4], [C60Ph]^+, [HC60Ph]
3	C60	Diphenylmethyl	A	[C60CH2], [HC60CH3], [C60(CH3)2], HC60(CH2), [H2C60(CH3)2], [C60C3H10], [C60(CH2)4], [CH2C60(CH2)(CH3)2], [H2C60(CH3)4], [C60C6H4], [HC60Ph], [CH2C60C6H4], [CH3C60Ph]
4	C60	Tetraphenyl	B	[C60C6H4], [HC60Ph], [C60Ph2], [H2C60Ph2]
5	C60	-Naphthylphenylmethyl	C	[C60CH2], [HC60CH3], [C60(CH2)2], [C60(CH3)2], HC60(CH2), [H2C60(CH3)2], [C60C3H10], [C60C6H4], [HC60Ph], [CH2C60C6H4], [C60C10H6], [HC60(-Naphthyl)]